Zhifeng Wang's research while affiliated with Hebei University of Technology and other places

Publications (18)

Article
Full-text available
The conversion of NO3⁻‐to‐NH3 by electrolysis is an appealing approach for wastewater treatment; however, such a process is hindered by the lack of efficient catalysts. Herein, taking the nanoporous Al11Ce3 intermetallic phase as an example, its electrocatalytic NO3⁻ reduction reaction capability is first demonstrated. Benefiting from the unique st...
Article
In this study, we prepared amorphous iron-cobalt oxide through the dealloying of trimetallic FeCoAl, showing excellent performance in both urea oxidation and hydrogen evolution reactions (UOR and HER) in alkaline seawater. The catalyst demonstrated stable UOR and HER activity during long-term operations due to the abundant active sites and oxygen v...
Article
Full-text available
The unique bicontinuous porous structure and superior electrical conductivity of nanoporous gold (NPG) make it a highly promising material for energy storage and conversion. Although the number of articles on the study of NPG-based materials in energy fields has increased significantly in recent years, the collation and review of these articles are...
Article
Full-text available
In this study, we investigated the high strain rate response of Mg-6wt%Er alloys with 1wt%Zn addition by split Hopkinson pressure bar (SHPB) tests in a range of 900–2500 s−1. Their related microstructures were also characterized by optical microscopy (OM), scanning electron microscopy (SEM), electron back-scattering diffraction (EBSD), and transmis...
Article
Full-text available
Biodegradable Mg–Zn–Ca-based metallic glasses (MGs) present improved strength and superior corrosion resistance, compared to crystalline Mg. In particular, in vivo and in vitro attempts reveal that biodegradable Mg–Zn–Ca-based MGs possess excellent biocompatibility, suggesting that they are ideal candidates for temporary implant materials. However,...
Article
Full-text available
Benefiting from ultra-high theoretical capacity, silicon (Si) is popular for use in energy storage fields as a Li–ion battery anode material because of its high-performance. However, a serious volume variation happens towards Si anodes in the lithiation/delithiation process, triggering the pulverization of Si and a fast decay in its capacity, which...
Article
Nanoporous Pd1Ag1 nanoleaves with merits of an appropriate atomic ratio, abundant low-coordinated surface atoms, efficient reactant accessibility and fast interfacial electron transfer kinetics exhibit superior catalytic activity towards electrochemical nitrogen...
Article
Lithium sulfur batteries have been recognized as a promising on-board energy-storage technology. One of the challenges in this system is the efficient inhibition of polysulfides shuttle with the low-cost sulfur hosts. In this work, we report the fabrication of nanoporous CeO2 and TiO2 by a novel chemical dealloying approach as a thin nonconductive...
Article
The unexhausted solar energy has been considered as one of the most promising alternative to traditional fossil energy. The solar energy can be captured by solar cell, converted into electrical power and then stored by supercapacitor or batteries. Toward higher energy utilization efficiency, how to realize conversing and storing solar energy in a c...
Article
Full-text available
We present here for the first time the electrochemical behavior of germanium anodes in potassium-ion batteries (KIBs). Nanoporous germanium (np-Ge) samples were fabricated by the chemical-dealloying method using Al as the sacrificial metal. Galvanostatic tests identified the reversible potassiation of the np-Ge anodes and the optimal sample with tu...
Article
Electrocatalytic nitrogen reduction reaction (NRR) under ambient temperature and pressure holds a great promise for NH 3 production while it is still impeded by the low active site density and sluggish kinetics, leading to a low product yield rate. In this work, bimodal nanoporous PdCu alloys that have three-dimensional hierarchical interconnected...
Article
Seeking for an efficient and stable electrocatalyst in a wide potential range is vital for the electrocatalytic reduction of CO2 into high-value added liquid fuels. Herein, the nanoporous Sn/SnO2 (np-Sn/SnO2) composites with high mesoporosity are fabricated through a two-step dealloying strategy. At all the applied potentials, the as-prepared np-Sn...
Article
Full-text available
A facile and industry-accepted dealloying method was used to synthesize Mn3O4 particles, which were then employed to prepare sulfur/Mn3O4 (S/Mn3O4) composites as cathode materials for lithium-sulfur batteries. The composites delivered initial discharge capacity reaching up 1184 mAh·g−1 at 0.1 C with capacity retention of 679 mAh·g−1 after 150 cycle...
Article
Sodium ion batteries (SIBs) have been considered as the promising substitution for the lithium ion batteries (LIBs) due to the abundant resource of sodium. Metal sulfides have been demonstrated as a prospective anode materials for SIBs based on a conversion mechanism. However, the insufficient ionic transportation and low conductivity in discharge...
Article
Huge volume expansion of Sn-based anode during Li-insertion leads to instability of the electrodes and degrades the electrochemical performances and thus prohibited their practical applications. Herein we propose a new “digging holes” approach to develop a three dimensional CuSn electrode, in which the active Sn adhere to conductive Cu framework. T...
Article
Full-text available
Tin-based materials have been considered as promising anodes for sodium-ion batteries because of their high theoretical capacity and low-cost. However, their significant volume expansion and low conductivity prohibit their practical applications. A novel CuSn alloy composite with three-dimensional nanoporous structure was prepared by the dealloying...
Article
Metal-silicides have demonstrated bright prospects as advanced anodes for lithium-ion batteries (LIBs). However, their roles in volume change accommodations are still unclear to us. Here, we design and fabricate a nanoporous Si/Cu0.83Si0.17/Cu composite, supported with a highly crystalline Cu-silicide/Cu rigid framework, which demonstrates a high r...

Citations

... While technologies like ion exchange, reverse osmosis, and electrodialysis, have been developed for NO 3 − remediation and clean water production [18,19], they often result in wastewater with high NO 3 − levels, requiring further treatment. Given the lower dissociation energy of the N-O bond in NO 3 − (204 kJ mol −1 ) and the ease of recovering NH 3 from its aqueous solution, using NO 3 − pollution as a nitrogen source for the electrochemical synthesis of NH 3 is highly appealing [20][21][22][23][24][25][26][27][28]. However, the intricate eight-electron reduction process and the competing HER limit the efficiency and selectivity of NH 3 production in the electrocatalytic NO 3 − reduction reaction (NO 3 − RR) [29][30][31]. ...
... On the one hand, urea can be used as a nitrogenous fertilizer to soil and a feed stock to synthesize high-valueadded chemicals [1][2][3][4][5]. On the other hand, the waste urea discharged into the environments results in water eutrophication and air pollution [1,[6][7][8][9][10]. It is urgent to find a solution to weaken and even prevent the detrimental effects from the urea applications. ...
... During the dealloying process, the active metallic elements in alloy precursor are selectively removed by chemical or electrochemical methods based on the different chemical activities [57]. Simultaneously, the remaining metallic elements form a unique nano-scale porous structure through migration and diffusion process [58,59]. By changing the element composition and subsequent treatment, the morphology, structure and space arrangement can be controlled [60]. ...
... As cardiovascular and orthopedic implants require high hardness and strength, the development of Zn mechanical characteristics is one of the most important approaches by which to expand its application in medical implants [49][50][51][52]. Alloying elements are used as a good tool to significantly improve the performance of Zn [53][54][55][56][57]. A number of the mechanical characteristics of Zn-based alloys are compared in Table 2. ...
... Due to their high strength and plastic properties, magnesium-zinc alloys are used in many areas [1,2]. Additionally, due to their biocompatibility with the human body, they seem to be an ideal candidate for biomedical materials [1][2][3]. ...
... The half-cell exhibits nearly stable discharge capacity in the examined cycles at each C-rate tested. This stable discharge capacity at such a high C-rate shows the prepared SiO 2 @Fe 2 O 3 nanocomposite anode is favourable for Li + storage and release [27,[36][37][38]. When the half-cell is tested again at 0.2C-rate after subjecting the half-cell to different C-rates, the SiO 2 @Fe 2 O 3 electrode retains almost its original discharge capacity of 400 mAh g −1 . ...
... Wence Xu et al. [59] reported the two-step synthesis of nano porous PdH 0.43 . Fangjie Pang and coworkers successfully obtained PdAg alloys with controllable Pd/Ag atomic ratios and hierarchical porous structures via two-step dealloying of the Pd 1 Ag 2 Al 97 precursor alloy [143]. The disadvantage of dealloying process is the inability to control the porosity beyond the surface of the nanomaterial owing to the lack of precise control of the pore size. ...
... First, the poor electronic conductivity of element sulfur limits the specific capacity value [7,8]. Second, the discharge products of polysulfide could migrate from the cathode to the anode, called "shuttle effect," leading to the rapid capacity fading [9][10][11][12]. Finally, the big volume change of sulfur during the cycling causes the destruction of the cathode structure [13,14]. ...
... Compared with the integration of a solar cell and supercapacitor, the coupling of a photoelectrode and supercapacitor can efficiently convert and store the solar energy as electric or chemical energy with a simpler device configuration. Different structures of integrated photocapacitive electrodes such as Cu/Cu 2 O, TiO 2 /Ni(OH) 2 , Fe 2 O 3 /Ni(OH) 2 and BiVO 4 -PbO x have been investigated [9][10][11][12]. Currently, the photo-rechargeable performance of photocapacitive electrodes is still far from being commercialized. ...
... Moreover, it was known that the redox potential of K + /K (−2.93 V vs. standard hydrogen electrode [SHE]) is similar to that of Li + /Li (−3.04 V vs. SHE), which implies that KIBs can have the merits of not only low production cost but also high energy density. [10][11][12][13] Thus, many research have focused on the development of novel and outstanding electrode materials for KIBs, and various cathode materials for KIBs have been reported, such as polyanion compounds, Prussian blue analogs, and layered-type oxides. [14][15][16][17][18][19][20][21][22][23] In particular, layered-type transition metal (TM) oxide materials "K x [TM]O 2 " have great attention because of their large gravimetric capacities. ...