Zhaofeng Chang's research while affiliated with Kunming University of Science and Technology and other places

Publications (29)

Article
Full-text available
Biochar modification has received significant research attention due to its attractive and fruitful rewards in improving biochar performances. However, the determinants of modified biochars’ stability and the ability of aged modified biochars to remove heavy metals have not been comprehensively evaluated. Therefore, three commonly used functional g...
Article
Biochar-immobilized bacteria have been widely used to remove organic pollutants; however, the enhanced effect of biochar-immobilized bacteria on tetrabromobisphenol A (TBBPA) removal has not been fully investigated and the removal mechanism remains unclear. In this study, a bacterial strain with high TBBPA degradation ability, Burkholderia cepacian...
Article
Full-text available
Arsenic (As) contamination is a major threat to drinking water quality throughout the world, and the development of appropriate remediation methods is critical. Adsorption is considered the most effective method for remediation of As-contaminated water. Biochar is a promising adsorbent and widely discussed for As removal due to its potential low co...
Article
In this study, the biochar–goethite composites ([email protected]) were synthesized through co–ball milling and the degradation of triphenyl phosphate (TPhP) was compared in persulfate (PDS) alone system and [email protected]&PDS systems. The results showed that TPhP can be effectively degraded in PDS alone system and degradation efficiency reached...
Article
Undesirable solar energy absorption, poor charge transfer efficiency, and sluggish metallic ions redox cycle are three pressing problems, restricting the application of photocatalysis and peroxymonosulfate (PMS) techniques. Herein, an interface engineering of g-C3N4 quantum dots anchoring on the CuFe2O4/Cu⁰ hollow microspheres ([email protected]) w...
Article
In this study, pristine biochar (BC), ball milling biochar (MBC), Fe3O4 modified BC (Fe3O4@BC), and Fe3O4 modified MBC (Fe3O4@MBC) were prepared to compare the Bisphenol A (BPA) removal efficiency by activating persulfate (PDS). All catalysts exhibited excellent degradation rather than adsorption in the PDS system, and Fe3O4@MBC800 had the best BPA...
Article
Investigators are debating on the positive and negative priming effects of biochar on native soil organic carbon (SOC), which is largely attributed to the technical barrier of identifying biochar contribution to the apparently measured SOC or mineralized CO2. We combined benzene polycarboxylic acids (BPCAs) molecular biomarkers and soil particle de...
Article
Many studies have elucidated health concerns of informal e-waste recycling activities, yet few has evaluated the effectiveness of the regulations as well as the human exposure risks to adjacent residents. Herein, legacy polybrominated diphenyl ethers (PBDEs), hexabromocyclododecane (HBCDs), and alternative organophosphate esters (OPEs) were investi...
Article
Dissolved organic matter (DOM), which exists widely in the environment, coming from different sources, may greatly affect the adsorption of antibiotics. However, the adsorption mechanisms of antibiotics in a sandy soil and the effects of DOM from different sources on the adsorption remain poorly understood. This study systematically investigated th...
Article
Aromatic moieties of biochar are considered as key components for immobilizing hydrophobic organic contaminants in the environment. However, the relative importance of different aromatic moieties such as low-/high-condensation components in sorption has not been comprehensively investigated. In this study, biochar was produced from flue-cured tobac...
Article
Biochar inevitably goes through long-term aging under biotic and abiotic processes in the environment, which results in various changes in its physicochemical properties. However, the traditional characterization methods based on particle separation cannot effectively monitor biochar in complex matrixes. Molecular markers, especially benzene polyca...
Article
Thallium contamination has raised global concern due to its high toxicity and treatment difficulties. In this study, the magnetic adsorbent rGO-Fe3O4@TiO2 was synthesized for the effective removal of thallium(I) from water. The stable magnetism of the adsorbent before and after the adsorption ensured the facile magnetic separation from treated stre...
Article
Microplastics are ubiquitous in all environments and exert toxic effects in various organisms. However, the neurotoxicity and underlying mechanisms of long-term exposure to MPs aged under UV radiation remain largely unclear. In this study, Caenorhabditis elegans was treated with 0.1-100 μg/L virgin and aged polystyrene microplastics (PS-MPs) for 10...
Article
In this study, Fe3O4@TiO2 decorated reduced graphene oxide (RGO) nanosheets were synthesized by loading iron oxide on the surface of RGO nanosheets and subsequently coating by titanium oxide, which can be employed as the persulfate (PS) activator and high-performance adsorbent toward thallium (Tl). PS could be effectively activated by the Fe3O4@TiO...
Article
Full-text available
生物炭因其具有多孔、比表面积较大、含氧官能团较为丰富且芳香性较强等优点而在农业面源污染控制方面具有良好的应用前景。然而,生物炭应用于土壤后难以从土壤颗粒中分离出来,从而制约了其对农业面源污染物吸附行为的预测。分子标志物技术在表征有机碳行为领域做出了重要的贡献,苯多羧酸(Benzene polycarboxylic acids,BPCAs)分子标志物方法的引入,可为表征生物炭与磷之间相互作用提供新的视角。因此,本研究采用批量吸附实验,考察了烟秆和松木及其制备的生物炭对磷的吸附行为。结果表明,随热解温度的升高,生物质及其生物炭中各BPCAs含量及苯六甲酸(Benzene hexacarboxylic acid,B6CA)对BPCA的贡献率随热解温度的升高而增加,生物炭的芳香缩合度不断增强;两类生...
Article
Condensed organic matters (COM) with black carbon-like structures are considered as long-term carbon sinks because of their high stability. It is difficult to distinguish COM from general organic matter by conventional chemical analysis, thus the contribution by and interaction mechanisms of organo-mineral complexes in COM stabilization are unclear...
Article
The physicochemical properties of biochar determined its sorption of organic contaminations, and the environmental aging process changed the biochar properties. However, the correlation between biochar heterogeneous properties and their sorption characteristics is unclear. In this study, peanut shell biochars were produced at 200–700 °C, and HNO 3...
Article
Understanding formation of organo-mineral association is crucial for soil organic matter (SOM) stabilization. To remove reactive minerals from un-disturbed natural soil (NS) and two cultivated soils (dry-farming soil, TD, and terrace paddy soil, TP), a 10% HF/1M HCl treatment was applied. The mineral protection of different molecular SOM structures...
Article
Full-text available
The formation of organo-mineral complexes is essential in organic matter (OM) stabilization. However, limited studies have been conducted to systematically examine the mineral influence on the decomposition of plant residuals at a molecular level. In this study, pine needles and chestnut leaves were mixed with kaolinite at the weight ratio of 5:1....
Article
Benzene polycarboxylic acid (BPCA)molecules are a widely used marker method for the qualitative and quantitative analysis of pyrogenic black carbons (BC). Based on an overview of the development and chemical reaction mechanismof the BPCA method,we propose that the commonly used BPCAmarkers may not be solely indicative of BC but more generally of co...
Article
Biochar function in soil is based on properties such as sorption characteristics, and these are expected to change throughout the life cycle of the biochar. Because biochar particles cannot easily be separated from soil particles, this change is seldom investigated. Biochar-related molecular markers, such as benzene polycarboxylic acids (BPCAs) are...
Article
Soil organic matter (SOM) is generally treated as a static compartment of soil in pollutant fate studies. However, SOM might be altered or fractionated in soil systems, and the details of SOM property/composition changes when coupled with contaminant behavior are unknown. In this study, a mild acid treatment was adopted to remove reactive minerals...

Citations

... The exposure of TCS to UV-C and solar light induces its photodegradation, resulting in the formation of various degradation byproducts. Several studies have indicated that, under an UV-C irradiation wavelength of 254 nm, three primary byproducts are typically generated: 2,4-DCP, a quinone, and a hydroquinone [33,34]. ...
... However, only NASMX significantly reduced xanthosine levels by 24 % relative to the control. Nucleotide metabolism is vulnerable to exposure to organic contaminants in plants (Hao et al., 2023). Under oxidative stress, DNA damage is a frequent occurrence, and DNA repair mechanisms are activated to alleviate this damage in plants (Li et al., 2020b). ...
... Previous research [46][47][48] has found a strong relationship between the O/C molar ratio and biochar half-life, demonstrating that different O/C ratio ranges correspond to varied half-life durations. According to the International Biochar Initiative (IBI), biochars with O/C ratios less than 0.2 are thought to be extremely stable and have a half-life of more than 1000 years [48][49][50]. With half-life ranging from 100 to 1000 years, biochars with O/C ratios between 0.2 and 0.6 are thought to be moderately stable. ...
... Considering this, biochar has emerged as a carbonbased material for successful Cr(VI) removal, because of its low-cost and presence of numerous functional groups on the surface [20,21]. Biochar has been widely applied as a potential biosorbent to eradicate poisonous heavy metal ions (arsenic, lead or cadmium) from contaminated water [22,23]. The heavy metals removal mechanism by biochar usually includes complexation with functional groups, physical sorption, ion exchange and surface precipitation [24]. ...
... The catechol 2,3dioxygenase pathway converts catechol into 2oxo-3-hexenedioate and succinate (Han et al., 2023). Lastly, some bacteria can use the phenol hydroxylase pathway, which converts phenol into phenol-2-monooxygenase and then into catechol (Yu et al., 2023). ...
... The corresponding TEM and HRTEM images further confirmed that Cu was reduced to Cu 0 by the derived carbon, and the catalyst particles were grown in situ and dispersed on the surface of the framework (Fig. 2e-h). The lattice fringes (Fig. 2f, h) with d-spacing of 0.208 nm corresponded to the (1 1 1) plane of Cu 0 , and the lattice fringes with dspacing of 0.252 nm, 0.296 nm and 0.483 nm corresponded to the (3 1 1), (2 2 0) and (1 1 1) faces of CuFe 2 O 4 [29], respectively. ...
... The low WEOM concentration in Lake Baiyangdian (0.47-5.62 g/kg, 1.61%-9.35%) may be related to the abundance of microorganisms in the water and in the shoreline soil ( Yuan et al., 2014 ;Wang et al., 2022b ;Zhang et al., 2023a ). This change may be caused by the annual water transfer projects implemented in Lake Baiyangdian, which further accelerate the growth and reproduction of microorganisms. ...
... Further, our observed PBDE and bis (2-ethyl hexyl) tetrabromophthalate (BEH-TEBP) concentrations were one to two orders of magnitude lower than those found in floor dust (no e-waste recycling or dismantling activities were conducted in the areas where floor dust was collected) of a Canadian e-waste facility . When comparing with other facilities where e-waste was dismantled or recycled, indoor dust concentrations of PBDEs observed in this study were also considerably lower than those reported inside both regulated and unregulated e-waste recycling facilities in China Zheng et al., 2015;Zhou et al., 2022), Vietnam (Wannomai et al., 2020), and Canada . Moreover, concentrations of 1,2-bis (2,4,6-tribromophenoxy) ethane (BTBPE), BEH-TEBP, and DBDPE in indoor dust inside Facility #1 were at the lower end of those observed in regulated e-waste recycling facilities in Canada and in unregulated e-waste recycling facilities in China Zheng et al., 2015) and Vietnam (Wannomai et al., 2020). ...
... The Co-based bimetallic catalysts with spinel structure have shown great potential in PMS activation owing to their favorable electron transfer properties promoted by self-redox cycle [7][8][9]. Especially, ZnCo 2 O 4 revealed low flat band potential and high position of Fermi level, leading to superior catalytic activity for PMS. ...
... Moreover, the magnetic biochar-Fe 3 O 4 composite material achieved an impressive 96.73% degradation rate for Bisphenol A in the reaction system by employing both free radical and non-free radical pathways, surpassing the removal rates of single biochar (6.98%) or Fe 3 O 4 (21.59%) 71 . Similarly, another magnetic biochar-FeS composite fabricated via ball milling employed biochar as an electron transport medium and utilized surfbonded Fe(II) and S(II) to achieve tetracycline degradation within just 30 min 72 , yielding comparable results as reported by ref. 72 . ...