Wuliji Hasi's research while affiliated with Harbin Institute of Technology and other places

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Publications (65)


Automated Identification of Pesticide Mixtures via Machine Learning Analysis of TLC-SERS Spectra
  • Article

June 2024

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18 Reads

Journal of Hazardous Materials

Guoqiang Fang

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Wuliji Hasi

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Siqingaowa Han
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High sensitivity I-beam shaped polarization related vector curvature sensor with optical intensity modulation
  • Article
  • Full-text available

May 2024

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29 Reads

Infrared Physics & Technology

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Interfacial Self-Assembly of Surfactant-Free Au Nanoparticles as a Clean Surface-Enhanced Raman Scattering Substrate for Quantitative Detection of As5+ in Combination with Convolutional Neural Networks

August 2023

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55 Reads

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9 Citations

The Journal of Physical Chemistry Letters

Surface-enhanced Raman scattering (SERS) is a highly sensitive tool in the field of environmental testing. However, the detection and accurate quantification of weakly adsorbed molecules (such as heavy metal ions) remain a challenge. Herein, we combine clean SERS substrates capable of capturing heavy metal ions with convolutional neural network (CNN) algorithm models for quantitative detection of heavy metal ions in solution. The SERS substrate consists of surfactant-free Au nanoparticles (NPs) and l-cysteine molecules. As plasmonic nanobuilt blocks, surfactant-free Au NPs without physical or chemical barriers are more accessible to target molecules. The amino and carboxyl groups in the l-cysteine molecule can chelate As5+ ions. The CNN algorithm model is applied to quantify and predict the concentration of As5+ ions in samples. The results demonstrated that this strategy allows for fast and accurate prediction of As5+ ion concentrations, and the determination coefficient between the predicted and actual values is as high as 0.991.


Schematic diagram of EPT based on MZI.
(a)Enlarged schematic of EDT zone;(b)-(c) Theoretical simulation of coupling efficiency and loss of EDT.
The simulation spectral characterization of EDT-MZI Structures with different ellipticity.
Image of the transmitted light field and normalized power of the adiabatic taper: (a) without the intensity modulation zone; (b) With spherical modulation zone formed by SMF;(c) With spherical modulation zone formed by SMF and MMF.
(a) The mechanical simulation characterization for: the double down taper MZI;(b)-(e) The EDT-MZI in different ellipticity.

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Simultaneous sensing of strain and temperature based on the inline-MZI embedded point-shaped taper structure with low crosstalk

August 2023

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17 Reads

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1 Citation

Optics Express

Optics Express

An embedded spherical dot taper structure (EDT) based on the MZI principle is proposed in this paper, which is mainly fabricated by using two special arc discharges in the preparation process. The proposed structure involves two specialized arc discharge techniques. First, an oversaturated discharge fusion process creates a micro-arc spherical area on the fiber end face to form the first link type. Second, an unsaturated discharge-pulling taper fusion joint creates a local micro-extrusion operation on this micro-arc fiber end face to form the second link. The thermal stress from instantaneous discharge causes a reverse spherical expansion zone to form in the end face structure, similar to the micromachining of long-period fiber gratings that use local CO2 laser etching to create modulated zones. The study involves a mathematical and theoretical analysis of how geometric parameters in the spherical modulation zone impact the structure's characteristic spectrum. The research demonstrates the potential for this structure to function as a light-intensity modulated strain sensor device through both theoretical and experimental means. As per the experimental findings, the optimized structure displays a high level of strain sensing sensitivity at 0.03 dB/µε and temperature sensing sensitivity of 73 pm/°C (20°C-75°C) and 169 pm/°C (75°C-120°C). Additionally, it possesses excellent cross-sensitivity at only ∼0.0015 µε/°C. Therefore, this sensor presents a favorable option for strain and temperature synchronization sensing and monitoring components, and exhibits notable application prospects in precision engineering, which encompasses mechanical manufacturing, the power and electrical industry, healthcare domain, and certain specialized areas of small-scale precision engineering.




Self-Assembling Vectorial Curvature Sensing System Based on a Single Helix of Polarization-Maintaining Fiber

January 2023

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23 Reads

IEEE Transactions on Instrumentation and Measurement

This paper presents a novel composite vector bending sensing system capable of switching freely between wavelength and intensity modulation. The fundamental sensing unit of the system depends on an offset rotation twisted Mach-Zehnder Interferometer (TW-MZI) with unique refractive index (RI) distribution characteristics proven through experiments. The sensing unit delivers remarkable performance in intensity modulation, reaching a maximum of 18.74 ± 0.01 dB/m <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-1</sup> . The sensing unit features a non-uniform geometric distribution and utilizes polarization-maintaining optical fibers as its structural material, enabling it to detect the correlation of polarized light and recognize the bending direction. With these advantages, a quasi-parallel distributed curvature sensing system is constructed, integrating a Sagnac interferometer (SI) as the sensing reference arm combined with the TW-MZI sensing unit. Adjusting the interference length and optical power can obtain a first-order harmonic vernier spectrum. Additionally, the envelope differencing technique enhances the interference fringe contrast, reducing the reliance on the monitoring wavelength domain. This combination highlights the composite system’s wavelength modulation-based vector curvature sensing capability, achieving a maximum value of 15.59 ± 0.01 nm/m <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-1</sup> . Moreover, this system exhibits characteristics such as low-temperature crosstalk, high stability, and rapid responsiveness, making it well-suited for applications in medical device diagnostics, oil and gas pipeline inspection, and structural safety monitoring within the construction industry.


Citations (49)


... In this equation, ԑ represents the shear strain experienced by the device due to bending. Consequently, there exists the following relationship between the characteristic wavelength λ ki and the curvature [49]: ...

Reference:

High sensitivity I-beam shaped polarization related vector curvature sensor with optical intensity modulation
Research and assessment of high sensitivity intensity modulation vector curvature sensor based on cascaded bamboo-joint microcavity structure
  • Citing Article
  • October 2023

... Gold and silver nanoparticles have been largely utilized as agents to enhance the Raman scattering in SERS mainly because of their stability and excellent enhancement properties [27,28]. Metal nanoparticles can be fabricated via self-assembly [29], ink-jet printing [25], the deposition of presynthesized colloidal metal nanoparticles [30], surfactant-free synthesis [31], silver-complex ink [32], etc. Nevertheless, any alternative approach that would entail a more facile yet still efficient procedure devoid of disadvantages such as the cost and operating time remains attractive and worthy of investigation. ...

Interfacial Self-Assembly of Surfactant-Free Au Nanoparticles as a Clean Surface-Enhanced Raman Scattering Substrate for Quantitative Detection of As5+ in Combination with Convolutional Neural Networks
  • Citing Article
  • August 2023

The Journal of Physical Chemistry Letters

... The accuracy of each algorithm was evaluated by measuring the percentage of correctly classified compounds out of the total number of test compounds. The algorithms compared in this study were the Fuzzy KNN (F-KNN) method [40], Learning Vector Quantization (LVQ) [41], C4.5 method [42], K-Means clustering method [43], momentum backpropagation (MK) method [44], PCA-SVM [45], and hybrid CMA-ES (GA-C-E) algorithm. ...

Study on the classification and identification of various carbonate and sulfate mineral medicines based on Raman spectroscopy combined with PCA-SVM algorithm
  • Citing Article
  • December 2022

Analytical Sciences

... Li [44] combined SERS with a deep learning convolutional neural network (CNN) algorithm to detect the thiram and pymetrozine in tea, with correlation values of 0.995 and 0.977. The method proposed by Sha [45] is to identify midazolam and diazepam by combining SERS with CNN. The coefficient of detection reaches up to 0.966. ...

Qualitative and quantitative detection and identification of two benzodiazepines based on SERS and convolutional neural network technology
  • Citing Article
  • November 2022

The Analyst

... This method involved dissecting the SERS spectrum of the mixture and providing a schematic representation, which indicated the proportion of each antibiotic. Applying SERS sensors directly to real-world samples like human milk presents challenges due to interfering compounds (Fang et al., 2022). It should be noted that, in this experiment, human milk underwent centrifugation with acid to eliminate fat and protein, and the resulting supernatant was collected for SERS spectral detection. ...

Machine Learning-Driven 3D Plasmonic Cavity-in-Cavity Surface-Enhanced Raman Scattering Platform with Triple Synergistic Enhancement Toward Label-Free Detection of Antibiotics in Milk
  • Citing Article
  • September 2022

Small

... 23,24 More common are TLC-surface enhanced Raman spectroscopy (SERS) methods, which use metal nanostructures to increase Raman signals for detection of molecules at low concentrations. TLC-SERS has been employed to separate and quantify analytes in a variety of applications, such as reaction progress monitoring, food safety analysis, etc. [25][26][27][28] Quantitative TLC-Raman remains a relatively unexplored technique for plant pigment analysis. ...

A novel suitable TLC-SERS assembly strategy for detection of Rhodamine B and Sudan I in chili oil
  • Citing Article
  • April 2022

Food Control

... At present, various metal nanoparticles with different morphologies have been successfully synthesized, such as nanocubes (NCs) [14], nanowires (NWs) [15], nanorods (NRs) [16], nanostars (NSs) [17], and nano triangles (NT) [18]. Among them, silver NCs exhibit strong and unique LSPR performance, providing powerful SERS property by the sharp edges and angles [19]. ...

Plasmonic Nanosensor Based on Ag Nanocubes of High Purification by Extraction Filtration Strategy for SERS Determination of Malachite Green in Aquaculture Water
  • Citing Article
  • February 2022

Sensors and Actuators B Chemical

... These structures are suitable for studying the fundamental properties of plasmon coupling, but their application as SERS platforms that utilize the strong electromagnetic field spaces is challenging. Therefore, research focusing on utilizing this distinctive plasmon coupling in high-density two-dimensional assemblies of metal nanoparticles, which have demonstrated utility as SERS sensing platforms [27][28][29], has recently attracted particular attention [30,31]. For example, the SERS activity of two-dimensional assemblies composed of two components, AuNPs and Au@Ag nanocubes, has been reported to be significantly stronger compared to the two-dimensional assemblies consisting of single-component Au nanoparticles or Au@Ag nanocubes alone, attributed to strong plasmon coupling in heterodimers [30]. ...

Binary Plasmonic Assembly Films with Hotspot-Type-Dependent Surface-Enhanced Raman Scattering Properties
  • Citing Article
  • October 2021

ACS Applied Materials & Interfaces

... According to different experimental methods, SERS can enhance the signal by 10 4 -10 15 times compared with ordinary Raman spectroscopy [21], which greatly improves the detection sensitivity and can reach the level of single virus [22]. Based on its advantages of high sensitivity, speed, nondestructive and good biocompatibility, it has been widely used in many fields such as biomedicine, food and environmental safety [23,24]. The Raman nanospheres (RNPs) used in this study are a new type of nanomaterials with core-shell structure formed by the fusion of a variety of metals, small molecular substances, polymers, etc. ...

Fabrication of an AAO-Based Surface-Enhanced Raman Scattering Substrate for the Identification of Levofloxacin in Milk
  • Citing Article
  • January 2021

New Journal of Chemistry

... By self-assembling a monolayer of AuSph onto FP, the strong affinity of chloride ion with the gold surface was adapted to greatly enhance the SERS signals. Fentanyl citrate in urine samples were detected with the LOD of 0.59 g mL −1 [165]. ...

Sensitive and reliable identification of fentanyl citrate in urine and serum using chloride ion-treated paper-based SERS substrate
  • Citing Article
  • January 2021

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy