Wenbo Shen's research while affiliated with Government of the People's Republic of China and other places

Publications (22)

Article
Full-text available
Inspired by nature, humidity-responsive materials and devices have attracted significant interest from scientists in multiple disciplines, ranging from chemistry, physics and materials science to biomimetics. Owing to their superiorities, including harmless stimulus and untethered control, humidity-driven materials have been widely investigated for...
Article
Full-text available
As a typical representative of dopants, organic functional dyes have demonstrated their significant roles in novel smart liquid crystal (LC) devices, and dye‐doped LCs have also been a source of inspiration for scientists to design and fabricate stimuli‐gated materials or devices for envisioned applications in a wide range of areas. In this review,...
Article
Polymer-dispersed liquid crystals (PDLCs), comprised of submicron-sized LC droplets embedded in a continuous polymer matrix, have been the subject of interest for scientists and manufacturers owing to their promise for optoelectronic applications. Recently, many research works have made significant progress in improving performance, developing new...
Article
In this work, a facile approach to fabricating multifunctional smart windows by employing an ionic liquid-doped liquid crystal (LC)/polymer composite was reported. The composite was prepared via an established method of polymerization-induced phase separation while a commercial ionic liquid was doped into the composite as a supporting electrolyte....
Article
Accelerators are usually used to promote the thermal curing of epoxy/thiol mixtures and help to improve the preparation efficiency of epoxy-based polymer-dispersed liquid crystals (PDLCs). However, some accelerators may cause serious yellowing of the resultant products and their catalytic effect is also limited. In this work, a commercial compound...
Article
Polymer-dispersed and polymer-stabilized liquid crystals (PD&PSLCs) are the coexistent systems of PDLCs and PSLCs, in which a mesogenic polymer network forms in the LC droplets to construct the PSLC system and the combination of the LC domains and the isotropic polymer matrix makes up the PDLC system. In this work, a PD&PS cholesteric LC (PD&PSCLC)...
Article
In this work, a novel approach to realizing the electrically induced coloration of polymer-stabilized cholesteric liquid crystal (LC) films with broadband reflection capability for smart windows was reported. Only starting common materials and an established preparation method were used. The polymer-stabilized cholesteric LC films with broadband re...
Article
In this work, the effect of two different KH570 modified silicon-based nanofillers on the electric-optical performance of PDLC samples was studied. The two nanomaterials not only were as the nanofillers but also acted as the crosslinkers in the PDLC system because of the acrylate groups grafting on the surfaces. The results indicated that both the...
Article
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In this work, two silicon nanostructures were doped into polymer/nematic liquid crystal composites to regulate the electric-optical performance. Commercial SiO2 nanoparticles and synthesized thiol polyhedral oligomeric silsesquioxane (POSS-SH) were chosen as the dopants to afford the silicon nanostructures. SiO2 nanoparticles were physically disper...
Article
In this study, a new method to prepare the chiral polymer/cholesteric liquid crystals composite films with broadband reflective capability was reported. A negative dielectric anisotropy liquid crystal material was utilized as the mesogenic solvents and a chiral mesogenic monomer was employed as the chiral dopant. The chiral mesogenic monomer not on...
Article
In this paper, we report a simple and effective technique to improve the electro-optical performance of polymer-dispersed liquid crystal (PDLC) films via the implantation of polyhedral oligomeric silsesquioxane (POSS) microstructure into the polymer matrix. The measurement results of the electro-optical properties indicated that the electro-optical...
Article
In this paper, the viewing-angle-switching (VAS) films based on polymer dispersed liquid crystals (PDLCs) were fabricated and the optical properties of the VAS films were studied. The VAS films based on PDLC films can exhibit electrically switchable viewing-angle properties, and the films showed a narrow viewing angle under no electric field and pr...
Article
Full-text available
Optical diffusers with high transmission, high haze and excellent diffusing ability are widely needed in backlight unit (BLU) of liquid crystal displays (LCDs). However, there are still drawbacks in the particles-doped optical diffusers, including the distribution of the scattered particles due to agglomeration of particles and complex coating proc...
Article
In this paper, by utilising the photoinitiated cationic polymerisation of liquid crystalline epoxide in LC solvents, the epoxy-based polymer stabilised liquid crystals (EPSLCs) were fabricated. The effects of the liquid crystalline epoxide content, UV intensity, polymerisation temperature, and initiator content on the network morphology of liquid c...
Article
As a typical class of electrically light-transmittance-switchable (ELTS) composites materials, polymer dispersed liquid crystal (PDLC) films have been widely used in displays, smart windows, light shutters, etc. However, the commercialised PDLC film still requires a comparatively high voltage to maintain its transparent state, leading to huge power...
Article
In this paper, polymer dispersed liquid crystal (PDLC) films based on epoxy-mercaptan system were prepared by thermal-initiated polymerization. The effects of the liquid crystal (LC) content, the proportion and the functionality of epoxy monomers on the polymer structures and electro-optical properties of the as-made PDLC films were investigated sy...
Article
A novel approach to fabricate epoxy-based polymer-stabilized liquid crystals (EPSLCs) via the cationic photopolymerization of liquid crystalline epoxide in mesogenic solvents was presented. The photoinitiated cationic polymerization of liquid crystalline epoxide in different mesogenic solvents was compared and the liquid crystalline epoxy polymer (...
Article
A liquid crystalline epoxide was synthesized and its curing reactivity was compared with that of the conventional epoxy monomers. By utilizing the difference in curing reactivity between the liquid crystalline epoxide and non-liquid crystalline epoxy monomers, a coexistent system of polymer-dispersed and polymer-stabilized liquid crystal (LC) in th...
Article
In this paper, we report the design, preparation and properties of epoxy-mercaptan polymer/nematic liquid crystal (LC) composites with electrically switchable optical transmittance. It is found that the polymer microstructure can be regulated from porous structure to microspheres or beads by appropriately modulating the curing temperature, the mole...
Article
Polymer-dispersed liquid crystal (PDLC) films have been successfully applied in the field of smart windows, building partitions and projection screens. However, the high-driving voltage of the state-of-the-art PDLC films not only results in serious security problems but also leads to huge energy consumptions. Although studied for decades, however,...

Citations

... Another solution to incorporate liquid crystal epoxy into mixtures with cholesteric compounds is to implant mesogenic epoxy microspheres into the CLC matrix. Research carried out in the article [46] by Zhang et al. proves that such systems are characterized by high bistability, i.e., the ability to be in one of two stable states and remain in it for a long time without the need for continuous external energy supply. This offers prospects for the production of promising materials that can be used as intelligent windows or shading elements with low energy consumption. ...
... LCEs are a combination of liquid crystal mesogens and polymer networks, possessing anisotropy of mesogens and elasticity of polymer networks [16][17][18]. When subjected to external stimuli (e.g., temperature, light, non-polar solvents), LCEs undergo the nematic-isotropic phase transition, causing an anisotropic contraction ( Figure 1E) [19][20][21]. By spatially patterning the mesogens, they can produce versatile in-plane or out-of-plane actuation modes, including bending, twisting, curling, and extension [22][23][24]. ...
... Among the various types of low-molar-mass liquid crystals (LCs) and polymeric liquid crystals, the cholesteric type of LCs, which are characterized by an unusual helical structure (Fig. 1a), is of greatest interest from the point of view of their possible applications [1,2]. This type of structural organization predetermines remarkable optical properties including a selective light reflection (SLR) band with a center wavelength λ max proportional to the pitch P of the helix ...
... Thus, significant changes have been observed in the physical properties of the produced composites [10][11][12][13][14][15]. Liquid crystal/Polymer composites, which are formed by combining NLCs with polymers, are preferred as potential materials for switchable smart windows applications [16][17][18]. The combination of NLCs with a low proportion of polymer forms a polymer stabilized liquid crystal (PSLC), and the combination of NLCs with a high proportion of polymer forms a polymer dispersed liquid crystal (PDLC) [19,20]. ...
... 39,40 MoO 3 microrods, which are larger than nanorods, aid in better dispersion within liquid crystal matrices, preventing agglomeration, ensuring uniform distribution, and enhancing stability in the liquid crystal matrix. 41,42 Figure 5b shows the EDX spectra analysis which confirms the successful incorporation of vanadium, titanium, molybdenum, selenium, and oxygen as per the stoichiometry ratio. ...
... Smartphones, laptops, and other products for electronic information displays have developed rapidly and become an essential part of our work and life [1]. To pursue a better display effect, the wide viewing angle, high luminance, and high reliability are used in electronic displays, bringing visual feast and enjoyment to users [2]. ...
... Particularly, recent investigation indicates that doping polyhedral oligomeric silsesquioxane (POSS) can attenuate the surface free energy and diminish the driving voltages, which works similarly to the fluorinated polymer [21][22][23]. The intuitive way to ameliorate the properties is by tuning the molecular structure of each component, and tremendous efforts have been devoted to this purpose, such as the research on fluorinated, alkene-terminated and cyano-terminated tolane liquid crystals; acrylate and thiol monomers with different chain lengths, functionality and terminal groups; and low-molar-mass, oligomeric and polymeric photoinitiators [4,[24][25][26][27][28][29][30][31]. These methods can alleviate the obstacles to some extent. ...
... At present, PDLCs demonstrate tremendous potential for a variety of applications including physical and chemical sensors [20][21][22], displays [23,24], time temperature indicators [25], smart windows [26], etc. The electro-optical performance of PDLCs has been improved in various strategies, such as doping guests (e.g., dyes [27] and nanoparticles [14,28]), utilizing LC elastomers [29], and innovating novel modes [30][31][32]. However, the singleness of the function and color of common PDLCs largely limits their application scope. ...
... Electrochromic LCD (EC-LCD) utilizes the rotation of liquid crystal molecules to effect color change. [108] When an electric field is applied, the liquid crystal molecules are rearranged, causing a color change. Therefore, EC-LCD can be utilized to display various graphics, texts, and images for applications in watches, calculators, and smartphones, among others. ...
... Doping NLC with nanoparticles (NPs) of varied dimensions and characteristics to form LC-NP nanocomposites with improved electro-optic and dielectric properties has recently been a muchexplored field of work. These nanocomposites with tailored physical properties can be used for the development of modern displays [4][5][6], smart windows [7,8], and biosensors [9,10], while also helping in answering physically significant questions regarding chirality transfer between molecules [11,12] and phase stabilisation based on symmetry breaking of director field [13]. ...