Shuwang Wu's research while affiliated with University of California, Los Angeles and other places

Publications (37)

Article
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Soft electronic circuits are crucial for wearable electronics, biomedical technologies and soft robotics, requiring soft conductive materials with high conductivity, high strain limit and stable electrical performance under deformation. Liquid metals (LMs) have become an attractive candidate with high conductivity and fluidic compliance, while effe...
Article
Full-text available
As the soaring demand for energy storage continues to grow, batteries that can cope with extreme conditions are highly desired. Yet, existing battery materials are limited by weak mechanical properties and freeze-vulnerability, prohibiting safe energy storage in devices that are exposed to low temperature and unusual mechanical impacts. Herein, a f...
Article
Hydrogels are cross-linked networks containing water and are widely used in multiple fields due to their intrinsic softness and diffusive properties. One field of particular interest is in medical devices and tissue and organ engineering. Poly(vinyl alcohol) (PVA) is one common hydrogel where its mechanical properties can be changed by using differ...
Article
Electron-ion transduction is the cornerstone for promoting emerging ionotronic devices, ranging from basic electronic elements to bioelectronics. However, with commonly used metal electrodes, the electron-ion transduction suffers from high impedance, signal distortion, and poor voltage tolerance. Conductive porous electrodes could partially remedy...
Article
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With rapid advances in soft electronic devices, the demand for soft conductive materials, including hydrogels, with superior mechanical properties, high conductivity and functionality under extreme environmental conditions are increasing at an unprecedented rate. Although hydrogels have favorable properties such as softness and broad tunability ran...
Article
Hydrogel materials are widely applicable due to their high water content, biocompatibility, and broad tunability. While the overall mechanical performance of hydrogels can be tuned by methods such as altering the recipe, introducing a secondary network, and adding a post-treatment step, anisotropic mechanical properties with specific anisotropic ra...
Article
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Metal patterning via additive manufacturing has been phasing‐in to broad applications in many medical, electronics, aerospace, and automotive industries. While previous efforts have produced various promising metal patterning strategies, their complexity and high cost limited their practical application in rapid production and prototyping. Herein,...
Article
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Polydimethylsiloxane (PDMS) is one of the most popular materials to protect infrastructures from the complicated environment due to its chemical stability, nontoxicity, low cost, high durability, and chain flexibility. Herein, a series of organic–inorganic hybrid coatings are prepared by simply grafting loop‐like PDMS on a solid surface. Owning to...
Article
This article reviews recent progress in the use of stimuli-responsive polymers for soft robotics. First, we introduce different types of representative stimuli-responsive polymers, which include liquid crystal polymers and elastomers, hydrogels, shape memory polymers, magnetic elastomers, electroactive polymers, and thermal expansion actuators. We...
Article
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Icing and frosting on transparent surfaces compromise visibility on various optical equipment and transparent infrastructures. It remains challenging to fabricate energy‐saving coatings for harvesting solar energy while maintaining high transparency. Here, transparent, photothermic, and icephobic composite surfaces composed of photothermal nanomate...
Article
Compared to conventional rigid electronics, polymer-based soft electronics conformal to organisms of irregular shapes have emerged as the next-generation devices, especially benefiting long-term bio-interface interactions that avoid mechanical mismatch and consequent adverse immune responses. Highly conductive poly(3,4-ethylenedioxythiophene):poly(...
Preprint
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Electron-ion transduction is the cornerstone for electronic devices interfacing with biological organisms and promoting emerging ionotronic devices, ranging from basic electronic elements to wearable electronics and energy harvesting devices. However, with commonly used metal electrodes, the electron-ion transduction suffers from high impedance, si...
Article
Many natural tissues feature layered structures for multi-functionality as each layer consists of different cell types and therefore exhibits unique physicochemical properties. Creating such complex multi-layered structures in human-made soft materials is hardly achievable with common gelation methods, lacking spatiotemporal control, and thus deman...
Article
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Ionotronics, emerging devices that couple gel ionic conductors and electronic circuits, have shown great promise as stretchable alternatives with multi-functionalities to conventional rigid devices, ranging from energy harvesting to sensing, displaying, and actuation. However, current hydrogel ionotronics’ performances are still unsatisfactory: i)...
Article
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Artificial Phototropic Systems In article number 2000234, Ximin He and co-workers present a versatile, low-cost mechanically strong artificial phototropic system able to autonomously track sunlight. The double-leg bimorph design allows the system to achieve large-angle reorientation and device load-bearing simultaneously. Using this sunlighttrackin...
Article
Inspired by the biological self-recovery mechanism of superhydrophobicity, a new class of waxgel material with sustainable hierarchical surface micro-structures has been reported. After being damaged or removed, the waxgel material can self-reconstruct its surface layer both chemically and structurally, as well as successfully recovers its superhyd...
Article
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Hydrogels have gained tremendous attention due to their versatility in soft electronics, actuators, biomedical sensors, etc. Due to the high water content, hydrogels are usually soft, weak, and freeze below 0°C, which brings severe limitations to applications such as soft robotics and flexible electronics in harsh environments. Most existing anti-f...
Article
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All-solid-state supercapacitors are seeing emerging applications in flexible and stretchable electronics. Supercapacitors with high capacitance, high power density, simple form factor, and good mechanical robustness are highly desired, which demands electrode materials with high surface area, high mass loading, good conductivity, larger thickness,...
Article
Significance Among various anti-icing conditions, cold and humid environments are the most difficult to tackle. Although photothermal materials have been used to increase surface temperature for delaying freezing, severe condensation under cold and humid environments causes increased reflection, resulting in lower temperature rise and eventually co...
Article
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Oblique‐incidence‐induced energy‐density loss (OEL) is a universal problem which affects nearly all processes involving electromagnetic waves, especially sunlight harvesting. Technologies (solar concentrating plants, large scale systems, etc.) are developed to address this issue, albeit with limitations such as complex design, large size, and high...
Article
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Crosslinked polymers and gels are important in soft robotics, solar vapor generation, energy storage, drug delivery, catalysis, and biosensing. However, their attractive mass transport and volume‐changing abilities are diffusion‐limited, requiring miniaturization to avoid slow response. Typical approaches to improving diffusion in hydrogels sacrifi...
Article
In the field of skin-attachable electronics, debonding-on-demand (DoD) adhesives triggered by mild, efficient, and accessible stimuli can facilitate repeated usage with negligible damage to the skin. Here, a simple and versatile method has been developed to fabricate biocompatible bonding/debonding bistable adhesive polymers (BAPs) with skin temper...
Article
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Natural load-bearing materials such as tendons have a high water content of about 70 per cent but are still strong and tough, even when used for over one million cycles per year, owing to the hierarchical assembly of anisotropic structures across multiple length scales1. Synthetic hydrogels have been created using methods such as electro-spinning2,...
Article
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With the emergence of soft electronic devices, the requirements for conductive soft materials are unprecedentedly high. Among various soft materials, hydrogels are gaining tremendous attention for their superior softness, wetness, responsiveness, and biocompatibility. However, hydrogels inevitably lose elasticity and ionic conductivity at subzero t...
Article
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Hydrogels, exhibiting wide applications in soft robotics, tissue engineering, implantable electronics, etc., often require sophisticately tailoring of the hydrogel mechanical properties to meet specific demands. For examples, soft robotics necessitates tough hydrogels; stem cell culturing demands various tissue-matching modulus; and neuron probes d...
Chapter
Various active soft materials have been developed for sensors and actuators inspired by the powerful, dexterous, and adaptive biological muscles found in octopus arms and elephant trunks. Stimuli-responsive hydrogels, a class of water-loaded polymers, exhibit large volume change and actuation strain upon environmental cues, enabling them to absorb...
Article
Hydrogels with attractive stimuli-responsive volume changing abilities are seeing emerging applications as soft actuators and robots. However, many hydrogels are intrinsically soft and fragile for tolerating mechanical damage in real world applications and could not deliver high actuation force because of the mechanical weakness of the porous polym...
Article
Full-text available
Stimuli-responsive hydrogels have large deformability but - when applied as actuators, smart switch, and artificial muscles - suffer from low work density due to low deliverable forces (~2 kPa) and speed through the osmotic pressure-driven actuation. Inspired by the energy conversion mechanism of many creatures during jumping, we designed an elasti...
Chapter
Anti‐icing coatings as a scientific and engineering topic have been studied for decades, since the undesired ice accumulation on surfaces leads to serious economic, traffic, energy, and safety issues. Inspired by nature, researchers have provided different effective strategies to build anti‐icing surfaces such as superhydrophobic surfaces, slippery...
Article
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Photonic microspheres offer building units with unique topological structures and specific optical functions for diverse applications. Here, a new class of inorganic photonic microspheres with superior robustness, optical and electrical properties is reported by introducing a unique localized concentric ordering architecture and chemical interactio...
Article
Significance Here cheap candle soot is utilized to make superhydrophobic photothermal icephobic surfaces. The candle soot provides the hierarchical structure for superhydrophobicity; meanwhile, sunlight can be trapped in the hierarchical structure to enhance the light absorption leading to a high photothermal efficiency. The superhydrophobicity can...
Article
The ice formation processes on solid surfaces are complex and diverse, which makes it a daunting challenge to design an icephobic material that is functional under different icing conditions in a complex varying real-life environment. Here, inspired by anti-freeze proteins, a multifunctional anti-icing platform based on polydimethylsiloxane (PDMS)-...
Article
Full-text available
Oriented microstructures are widely found in various biological systems for multiple functions. Such anisotropic structures provide low tortuosity and sufficient surface area, desirable for the design of high‐performance energy storage devices. Despite significant efforts to develop supercapacitors with aligned morphology, challenges remain due to...
Article
The design and fabrication of interfacial materials for anti-icing are of great importance, since undesired ice accumulation leads to serious issues in economic, energy and safety. Substantial progresses on interfacial materials for the passive removal of ice have been achieved in the past three years. The present focus review critically summarizes...
Data
Supplementary Figures, Supplementary Tables, Supplementary Methods and Supplementary References

Citations

... He's group developed a tough and antifreezing hydrogel electrolyte for zinc-ion batteries (Figure 8b). [142] On one hand, the introduced inorganic salt (K + ) ions in PVA hydrogels inhibited ice nucleation. On another hand, the open-cell porous structures with strongly aggregated polymer chains provided interpermeating nanoconfinements to prevent ice propagation. ...
... Bioelectronic devices that track cardiac function in real time and provide targeted feedback therapy are urgently required to control disease deterioration and minimize fatal complications [3][4][5] . Recently, epicardium patches achieved synchronized electrical recording and stimulation to regulate arrhythmias through sophisticated component design [6][7][8] . Nevertheless, in vivo electrophysiological detection is susceptible to electromagnetic interference, causing signal artifacts that misinterpret cardiac function 9 . ...
... In addition, the incorporation of a salt solution might improve the mechanical performance of hydrogels. An example of this technique is given in the work by Wu et al. [39], who successfully balanced the anti-freezing and mechanical properties of hydrogels and advanced their application in sub-zero-temperature environments. As shown in Figure 1d, the authors used a salt solution replacement Scheme 1. Schematic of the functionalized ETCHs and their applications. ...
... Jomary et al. [88] applied experimental and molecular simulation methods to investigate the structural characteristics of poly (ethylene glycol) diacrylate (PEGDA) hydrogels, revealing the existence of a link between chain-chain interactions, hydrogel structure, and the equilibrium swelling behavior of this hydrogel polymer solution. Duan et al. [89] prepared poly(vinyl alcohol) (PVA) hydrogels with tunable anisotropy ratios by the bidirectional ice template method and investigated their structural and mechanical properties. Narges et al. [90] employed molecular dynamics simulations to examine the impact of three distinct types of crosslinked hydrogels (polyacrylamide (PAM), polyvinyl alcohol (PVA), and polyethylene glycol (PEG) hydrogels), as well as the volume fraction of PAM hydrogels (ranging from 5% to 15%), on the swelling and thermal characteristics of simulated samples. ...
... In the anion-assisted method, salicylic acid anion (Sal − ) is used to form large pores, and the amount required is significantly reduced, indicating that Sal − has superior micellar penetration compared to the oil phase. 31,32 The strong interaction between Sal − and CTA + micelles, including high miscibility and strong electrostatic attraction, drives Sal − to migrate into the micelles, and its hydrophobic part is embedded in the hydrophobic region of the micelles. 33−36 Therefore, the anion-assisted method is highly reproducible and the effect of the stirring rate on the particle structure is negligible. ...
... Ice accretion on surfaces bring safety hazards for a range of fields including transportation, aviation, power transmission and offshore petroleum extraction etc [1][2][3][4][5]. To avoid these hazards, many materials strategies have been trialed to prevent ice accretion over the past decades [6][7][8][9][10]. Active anti-icing materials with low ice adhesion strength were built to achieve easy ice removal, including self-lubricated surfaces and low modulus surfaces [11][12][13][14][15][16]. ...
... The reason is that it is difficult to achieve lightto-heat properties and transparency simultaneously. 209,210 To achieve photothermal and transparency properties, MXenes are the best candidates for the replacement of other types of carbon materials. 211,212 Niu et al. 191 developed a transparent self-healable solar anti-/deicing surface of MXene, which was assembled layer-by-layer. ...
... The low-defective GO suspension was prepared by a modified Hummers' method 55 . For this aim, 46 ml of H 2 SO 4 was taken into a beaker, which was stirred in an ice water bath at 200 rpm min −1 . ...
... [38] This excess Fe 3+ can greatly intensify the Fe 3+ /Fe 2+ redox cycle, thus reducing the coordination ability and further weakening the mechanical properties of hydrogels. [38][39][40] Additionally, Fe 3+ ions in a hydrogel hinder free-radical polymerization, resulting in mechanical degradation. [41] To address these issues, low-concentration Fe 3+ ions were introduced to the pre-gel solution before polymerization. ...
... The stability of these H-bonds is higher than that among water molecules, as depicted in Figure 6b. Some inorganic acids, such as sulfuric acid (H 2 SO 4 ) [102] and phosphoric acid (H 3 PO 4 ), [103] have similar effects. The introduction of water-miscible organic solvents into hydrogels is a straightforward process and can be applied to various hydrogel systems. ...