Qun Gu's research while affiliated with Chinese Academy of Sciences and other places

Publications (20)

Article
Ring-banded morphology of polymerized cyclic butylene terephthalate (pCBT) accompanied by the synchronous evolution of non-ring-banded patterns was investigated for the first time through the crystallization of pCBT prepared by ring-opening polymerization (ROP) of cyclic butylene terephthalate oligomers (CBT). The result of gel permeation chromatog...
Article
Ultra-high molecular weight polyethylene (UHMWPE)/chitin nanocrystals (CNC) and UHMWPE/acetylated chitin nanocrystals (ACNC) fibers were prepared. The addition of CNC and ACNC significantly enhanced the ultimate tensile strength and Young's modulus of the UHMWPE fibers matrix. Compared with that of pure UHMWPE fibers, the ultimate tensile strength...
Article
Microbeam wide-angle X-ray diffraction (WAXD) experiments were carried out at different structural knot positions of SIOC and M4 fibers of ultra-high molecular weight polyethylene (UHMWPE). The optical microscope images revealed that SIOC fiber had bamboo-like structural knots, and M4 fiber had chaotic distribution of structural knots. WAXD pattern...
Article
The crystallization morphology and lamellae thickness of poly(ethylene oxide)-b-poly(ε-caprolactone) (PEO-b-PCL) under high pressure CO2 was studied by means of wide-angel X-ray diffraction (WAXD) and small-angel X-ray scattering (SAXS). For the sample of PEO0.5k-b-PCL24.5k, only PCL blocks crystallized under 1-3 MPa CO2 and the lamellae thickness...
Article
Nanostructures of stereocomplex polylactide (sc-PLA) are obtained and studied in poly(l-lactide) (PLLA) doped with a low amount of poly(d-lactide) (PDLA) during successive melt-quenching, extrusion, spinning, and drawing processes corresponding to quiescent, shear flow, elongational flow, and tensioned annealing conditions, respectively. Nanogranul...
Article
Full-text available
Two kinds of organophosphorous-functionalized ionic liquid (ILs) were synthesized and confirmed by FT-IR, HRMS and NMR. The ionic liquids have good thermostability and the viscosity decrease with the increasing temperature. They were used as plasticizer for PMMA by melt blending. The glass transition temperature (Tg) and melt viscosity of the plast...
Article
Two types of fibers were prepared by using bio-based materials: a mono-filament made from poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) and a multi-filament made from poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and polylactic acid (PLA) blend. The two fibers were evaluated for mechanical properties, biocompatibility and degradabili...
Article
Full-text available
Poly(lactic acid) (PLA)/graphene nanocomposites were prepared by solution blending and the dispersibility of graphene in the PLA matrix was examined by transmission electron microscopy (TEM). The non-isothermal crystallization behaviors of pure PLA and PLA/graphene nanocomposites from the melt were investigated by differential scanning calorimetry...
Article
Specific accumulation of therapeutics at tumor sites to improve in vivo biodistribution and therapeutic efficacy of anticancer drugs is a major challenge for cancer therapy. Herein, we demonstrate a new generation of intelligent nanosystem integrating multiple functionalities in a single carrier based on multifunctional multiblock polyurethane (MMP...
Article
A super-nanodevice engineered at molecular level integrates various desired properties in a smart and coordinated way, and can "switch on" or "turn off" certain functionalities as required. Importantly, it can break through complex physiological barriers, and then precisely ferry potent toxic triptolide into tumor cells in vivo, thus significantly...
Article
A molecularly engineered super-nanodevice integrates various desired properties in a smart and co-ordinated way, allowing certain functionalities to be switched on or off as required. As shown on page 3639 by H. Tan, Q. Fu, and co-workers, this nanovehicle could break through complex physiological barriers, and then precisely ferry potent toxic dru...
Article
To obtain controllable stepwise biodegradable polymer for multifunctional antitumor drug carriers, pH-sensitive biodegradable polyurethanes were firstly synthesized using poly(ε-caprolactone) (PCL) and pH-sensitive poly(ε-caprolactone)-hydrazone-poly(ethylene glycol)-hydrazone-poly(ε-caprolactone) macrodiol (PCLH) as soft segment; l-lysine ethyl es...
Article
The effective passage of drug formulations into tumor cells is a key factor in the development of nanoscale delivery systems. However, rapid cellular uptake with reduced toxicity remains a great challenge for efficient and safe delivery. In this study, we first use gemini quaternary ammonium (GQA) as a cell internalization promoter to enhance the c...
Article
Full-text available
Poly(lactic acid) (PLA)/graphene nanocomposites were prepared by direct solution blending of PLA with graphene using chloroform as a mutual solvent. Graphene was prepared by a solution-phase processing followed by thermal reduction, which can be dispersed stably in chloroform for more than one month. Transmission electron microscopy (TEM) was used...
Article
Poly(lactic acid) (PLA)/graphene nanocomposites were prepared by solution blending using chloroform as a mutual solvent. Transmission electron microscopy (TEM) was used to examine the quality of the dispersion of graphene in the PLA matrix. The isothermal crystallization behaviors of PLA and PLA/graphene nanocomposites were investigated by differen...
Article
We have recently developed a new group of cationic biodegradable multiblock poly(ε-caprolactone urethane)s bearing gemini quaternary ammonium pendant groups and methoxyl-poly(ethylene glycol) (m-PEG) end chains. In this study, to endow polyurethane with attractive amphiphilicity and good biocompatibility, and to achieve a fundamental understanding...
Article
The effects of the blend composition and rotation speed on the morphological evolution of polypropylene (PP)/polystyrene (PS) blends were investigated in a twin‐screw extruder. When PS was the major component, the rate of melt and the rate of dispersion played final roles in the morphological development of the polymer melts. However, when PP was t...
Article
The periodical cooperative twisting of lamellar crystals in poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) ring-banded spherulites was studied using mild methylamine vapor etching method. The samples were first dissolved in chloroform and then precipitated with methyl alcohol. The precipitates were collected by centrifugation and dried in vacu...
Article
Efficient procedures for the preparation of organic-soluble starch nanocrystal (SN) derivatives have been established with different degrees of substitution (DS). The resulting acetylated starch nanocrystals exhibit much improved solubility in common organic solvents such as N,N-dimethylformamide, acetone, carbon tetrachloride and toluene. The obta...
Article
Novel cationic biodegradable multiblock poly(epsilon-caprolactone urethane)s that contain gemini quaternary ammonium side groups on the hard segments were developed. To obtain these polyurethanes, a new L-lysine-derivatized diamine containing gemini quaternary ammonium side groups (GA8) was first synthesized and characterized by Fourier transform i...

Citations

... The growth of crystalline aggregates is not confined to polymers; it can also occur in tiny molecule compounds with similar optical patterns [10][11][12][13][14]. For the past half a century, the phenomena of circular ringed spherulites with periodicity and optical birefringence spiral/concentric bands have attracted interest [15][16][17][18][19]. Polymer spherulites are composed of lamellae-like crystals that are self-arranged by radiating outward from a common center; often, polymer spherulites display periodic bands, as exemplified in several recent review articles [20][21][22][23][24][25][26]. Such a ring-banded assembly is also common in aromatic polyesters, which are defined by repeating chemical units of varying lengths of methylene segments between two terephthalate groups. ...
... Ultra-high-molar mass polyethylene (UHMWPE) is an important polymer that has been widely used in a variety of applications, such as in the biomedical area for surgical lines, implants and orthopedic joint replacement components, as well as in the aerospace, steel industry and ballistic armor [1][2][3][4]. ...
... The UHMWPE peak was seen to exhibit sharp increase of crystalline peak befitted long and unbranched polymer crystalline structure and arrangement [76,77], while CNF peak shows semi crystalline pattern indicating existence of crystalline and amorphous region of the cellulose chains [78,79]. Additionally, all polymer and bionanocomposites samples exhibited similar pattern with two prominent diffraction peaks centered at around 22.0 • and 24.4 • of 2θ, which correspond to (110) and (200) reflection of polyethylene in orthorhombic phase [80][81][82]. The diffraction peak of the filler could not be observed due to low percent loading [81,83] and overlapped peak of UHMWPE with CNF at around 22 • in 2θ, which was in agreement with reported studies involving nanocellulose filler in polyethylene matrix [40,84]. ...
... The peculiarities of PLA stereocomplexation are widely studied in the literature (see e.g. [4][5][6][7][8][9][10] ). It is well known that a number of parameters such as: the molar mass and the optical purity of the enantiomers, the mixing ratio between the two isomers as well as the processing technique applied for the preparation of the polymer material; affect the formation of scPLA. ...
... The crystallinity (X c %) of all samples in two methods has increased compared to neat PLLA. This enhancement in crystallinity is attributed to nucleating effect of GnP particles which is in agreement with other works [18,19]. However, the effect of GnP in the crystallinity is highest in the GC. ...
... The authors also observed that the cold crystallization temperature of the nanocomposite increased with higher graphene content. In their study, Chen et al. [29] investigated the PLA/graphene microstructure under non-isothermal crystallization, varying the cooling rate from 0.5 to 4 °C min −1 , revealing that as the cooling rate increased, the maximum mass loss rate and crystallization temperatures decreased. On the other hand, Chartarrayawadee et al. [30] found that the addition of graphene did not significantly affect the glass transition and melting temperatures of PLA. ...
... The authors achieved a sustained release of the antibiotic for months as well as a strong bacterial zone inhibition of S. epidermidis after 7 days in release media. PLLA is one of the gold standard biopolymers used for biomedical applications; however, other biopolymers such as polylactide glycolide (PLGA) [18], polydioxanone (PDS) [19] polylactide (PLA), [6,20] and polyhydroxyalkanoates (PHAs) [20,21] can also be used as innovative materials to generate sutures. ...
... However, the molecular weight distributions differed slightly, possibly due to the different interactions between the functional segments and GPC chromatographic columns. 43 Sequence-controlled self-assembly and drug delivery properties ...
... Researches of virgin PP/PS mixtures are found in the scientific literature [27][28][29][30] , mainly due to the low cost and technological relevance of these materials. Brostow et al 31 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 A c c e p t e d M a n u s c r i p t There are several works in the scientific literature 28,[33][34][35][36][37] which have reported the development of blends made with virgin PS/PP and PS/PP/compatibilizer, emphasizing mechanical, thermal, rheological and morphological properties, being widely discussed. However, these works used virgin PP and no mention was made about blends based on hybrid and recycled PPs with PS matrix, thus configuring a relevant point to be explored. ...
... These scaffolds exhibited good biocompatibility and biodegradability and were shown to promote the repair of neurological defects in brain-injured rats [27]. In addition, we have successfully developed a series of PU NPs and drug-loaded PU scaffolds that can target tumors at multiple levels, increase drug uptake, and effectively inhibit tumor growth [28][29][30][31][32][33]. ...