Peng Wu's research while affiliated with South China University of Technology and other places

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Publications (35)


Constructing Highly Active Metal Oxides for Toluene Degradation by Fenton Iron Mud Modulation
  • Article

April 2023

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31 Reads

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2 Citations

ACS Applied Materials & Interfaces

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Yifei Li

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Jiajin Lin

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[...]

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Fenton iron mud (IM) is a hazardous solid waste produced by Fenton oxidation technology after treating industrial wastewater. Thus, it is necessary and challenging to develop a recycling technology to back-convert dangerous materials into useful products. Herein, we develop a sustainable approach to prepare highly active metal oxides via a solid-state grinding method. IM, as an amorphous material, can disperse and interact well with these supported metal oxides, boosting toluene degradation significantly. Among these IM-based catalysts, the catalyst 8% MnOx/IM-0.2VC exhibits the best performance (T100 = 290 °C), originating from the oxide-support interaction and optimal balance between low-temperature reducibility and oxygen vacancy concentration. In addition, in situ diffuse reflectance infrared Fourier transform spectrometry (DRIFTS) results expound that ring breakage is prone to occur on MnOx, and oxygen vacancies are beneficial to adsorb oxygen and activate oxygen species to boost toluene oxidation following the Mars-van Krevelen mechanism. This work advances a complete industrial hazardous waste recycling route to develop extremely active catalysts.

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Self-standing ultrathin NiCo 2 S 4 @carbon nanotubes and carbon nanotubes hybrid films as battery-type electrodes for advanced flexible supercapacitors

July 2022

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65 Reads

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26 Citations

Journal of Power Sources

An electrode with flexible construction, high capacity, and battery-type Faradaic mechanism is highly required for emerging wearable and portable electronics. A class of materials with favorable architectures that store energy through the Faradaic mechanism is a fertile ground for breaking through the energy density limit of an electric double-layer-based supercapacitor. Herein, a typical battery-type electrode of NiCo2S4 composited with carbon nanotubes (CNT) has been developed via a facile two-step solution reaction. The NiCo2S4@CNT composite exhibits good energy storage ability with an ultrahigh specific capacitance of 1,123 F g−1 at 0.5 A g−1 and superior stability. After being shaped into films via alternately stacking with pure CNT films, lightweight, flexible, and self-standing NiCo2S4@CNT/CNT hybrid film electrodes are fabricated, which exhibit a high volumetric capacitance of about 443 F cm−3. All-solid-state asymmetric supercapacitors with high flexibility are assembled using the hybrid film as cathode, treated carbon cloth as anode, and polyvinyl alcohol/KOH gel as solid electrolyte. Counting the weight of the two electrode films, a high energy density of 11.7 Wh kg−1 at 1.32 kW kg−1 with good cycling stability (66% of the initial capacitance after 25,000 cycles) is accomplished, suggesting promising potential for practical application in load-leveling wearable equipment.


Quenching-induced surface modulation of perovskite oxides to boost catalytic oxidation activity

July 2022

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32 Reads

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18 Citations

Journal of Hazardous Materials

Quenching is a powerful method for modulating surface structures of metal oxide nanocatalysts to achieve high catalytic oxidation activities, but it is still challenging. Herein, a catalyst of ultrafine Co3O4 nanoparticles decorated on Co-doped LaMnO3 (Co3O4/LaCoxMn1−xO3) is synthesized via one-step quenching perovskite-type LaMnO3 nanocatalyst into an aqueous solution of cobalt nitrate, which exhibits significantly improved catalytic performance with toluene (1000 ppm) conversion of 90% at 269 °C under the gas hourly space velocity of 72000 mL g⁻¹ h⁻¹. The high catalytic activity correlates with large surface area, abundant oxygen vacancies and good reducibility. Furthermore, density functional theory calculations disclose that Co doping and interfacial effect of Co3O4/LaCoxMn1−xO3 can achieve lower C−H bond activation energy. These findings provide a unique and effective route towards surface modification of nanocatalysts.


A dual plasmonic core—shell Pt/[TiN@TiO2] catalyst for enhanced photothermal synergistic catalytic activity of VOCs abatement

May 2022

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29 Reads

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21 Citations

Nano Research

Volatile organic compounds (VOCs) are ubiquitous organic pollutants affecting atmospheric environment and human health. The development of new efficient and environmentally friendly materials utilizing photothermal synergistic catalysis for purification of VOCs is still challenging. Herein, we design and prepare a core—shell TiN@TiO2 nanostructure integrating with nanoscaled Pt (Pt/[TiN@TiO2]) by an attractive quenching method. The strong light-harvesting capability of Pt and TiN components improve light-to-heat utilization efficiency by their intrinsic surface plasmon resonance effect. The TiO2 component upon the surface and the coexisting coupling effect of Pt0 and Pt2+ enhance the photocatalytic effect of the system. As a result, the catalytic performance is significantly improved with toluene (120 ppm) conversion of 100% under the gas hourly space velocity of 72,000 mL·g−1·h−1 and light illumination of 500 mW·cm−2. The desired catalyst thus achieves highly efficient coupling effect of photocatalysis and light-to-heat conversion for promoting VOCs abatement.







Acid-activated layered δ-MnO2 promotes VOCs combustion

October 2021

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48 Reads

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25 Citations

Applied Surface Science

The layered δ-MnO2 nanomaterial is an inexpensive and environmentally friendly nanocatalyst for volatile organic compounds (VOCs) catalytic oxidation. However, easy agglomeration and sluggish kinetics lead to its poor catalytic activity. Herein, we develop an acid-activated method to prepare δ-MnO2 catalysts with weakened Mn-O bonds, enhanced specific surface area and increased active surface lattice oxygen species, which significantly enhances catalytic performance for toluene oxidation. The δ-MnO2 catalyst treated by 1 M hydrochloric acid for 3 h can completely convert toluene into CO2 and H2O at 280 oC under the GHSV of 72000 mL g⁻¹ h⁻¹, and it can maintain good catalytic stability for more than 50 h without obvious potential decay. Further, the acid-activated strategy can be extended to other phase structured MnO2 with varying degrees of catalytic activity enhancement. The results demonstrate that the acid-activated way has great potential in improving catalytic oxidation activity of nanocatalysts for eliminating VOCs.


Citations (30)


... The electrochemical properties of supercapacitors on the basis of Ni materials and CNTs composite electrodes have been reported in [158]. A typical battery-type electrode of NiCo 2 S 4 /CNTs prepared by Yao et al. [159] exhibited ultrahigh specific capacitance of 1123 F g -1 at 0.5 A g -1 , superior stability, and good energy storage ability. A supercapacitor constructed from this electrode (cathode) and treated carbon cloth (anode) showed a high energy density of 11.7 Wh kg -1 with good cycling stability. ...

Reference:

Recent Advances in Ni-materials/Carbon Nanocomposites for Supercapacitors Electrode
Self-standing ultrathin NiCo 2 S 4 @carbon nanotubes and carbon nanotubes hybrid films as battery-type electrodes for advanced flexible supercapacitors
  • Citing Article
  • July 2022

Journal of Power Sources

... At present, the thermal-coupled photocatalysis degradation of VOCs has made great progress. Common VOCs, including toluene [120][121][122][123][124], benzene [136], phenol [132,133], and 2,4-dichlorophenol [125][126][127][128], be efficiently degraded under thermal-coupled photocatalysis. Jiang et al. investigated the performance of Pt−Cu/TiO 2 nanocatalysts for photo−thermal catalytic degradation of toluene [120]. ...

A dual plasmonic core—shell Pt/[TiN@TiO2] catalyst for enhanced photothermal synergistic catalytic activity of VOCs abatement
  • Citing Article
  • May 2022

Nano Research

... Tricobalt tetraoxide has been widely studied because it possesses abundant reactive oxygen species [9,10]. Li et al. [11] developed a cobalt oxide with the presence of vacancies (denoted as Co 3-x O 4-y ), which exhibits better catalytic activity in toluene oxidation than the crystalline catalyst Co 3 O 4 and the catalysts Co 3-x O 4 with only cobalt defects or Co 3 O 4-y with oxygen vacancies. Cerium is widely used due to its excellent oxygen storage capacity, electron-releasing properties, redox and the feasible valence transition from Ce 4+ to Ce 3+ , which effectively enhances the formation of oxygen vacancies [12]. ...

Engineering Cobalt Oxide with Coexisting Cobalt Defects and Oxygen Vacancies for Enhanced Catalytic Oxidation of Toluene
  • Citing Article
  • April 2022

ACS Catalysis

... The enhanced catalytic activities of perovskite oxide were due to a larger amount of O* and the participation of bulk oxygen in the HCHO oxidation on account of the higher reactivity of Mn 4+ species located in the bulk of the substituted materials. A quenching method can introduce other metals to ABO 3 and boost the oxidation activity of catalyst [88]. The Co 3 O 4 /LaCo x Mn 1− x O 3 was prepared by one-step quenching perovskite-type LaMnO 3 into cobalt nitrate solution. ...

Quenching-induced surface modulation of perovskite oxides to boost catalytic oxidation activity
  • Citing Article
  • July 2022

Journal of Hazardous Materials

... 100 % oxidation of toluene was achieved in 3 h under 280°C. [126] In addition, cobalt oxides in different molecular formula like other metal oxides have different catalytic activity; nonetheless, its Co 4 + has been proven highly reactive. Co 3 O 4 is the famous cobalt oxide in Co 4 + oxidation states, and it has a very strong acidic site, which promotes strong adsorbate-adsorbent interaction. ...

Acid-activated layered δ-MnO2 promotes VOCs combustion
  • Citing Article
  • October 2021

Applied Surface Science

... The enthalpic penalties of elemental mixing are overcome by an increase in configurational entropy, which acts to stabilize HEOs, particularly at high temperatures [12]. HEOs have been applied as catalysts and catalyst supports for PGM in the previous literature for oxidation reactions [6,[13][14][15][16][17][18]. In several studies, HEO supports of rock salt and fluorite phases demonstrated the ability to thermally stabilize supported gold, palladium, ruthenium, and platinum species [13,15,16]. ...

A Hydrothermally Stable Single-Atom Catalyst of Pt Supported on High-Entropy Oxide/Al2O3: Structural Optimization and Enhanced Catalytic Activity
  • Citing Article
  • October 2021

ACS Applied Materials & Interfaces

... By combining temperature-programmed reduction (TPR) data and CO chemisorbed Fourier-transformed infrared spectroscopy (CO-FTIR), the authors demonstrated the formation and importance of Pt−O v −Ti 3+ sites (O v �oxygen vacancy). Chen et al. 12 further explored the oxide functionalization and its effect on vacancy formation by preparing Pt/TiO 2 catalysts by wet impregnation with [Pt(NH 3 ) 4 ](NO 3 ) 2 and using as support anatase TiO 2 nanosheets doped with nitrogen on the surface. Activation took place under both oxidizing and reducing conditions at 300°C. ...

Reciprocal Regulation between Support Defects and Strong Metal-Support Interactions for Highly Efficient Reverse Water Gas Shift Reaction over Pt/TiO2 Nanosheets Catalyst
  • Citing Article
  • July 2021

Applied Catalysis B Environmental

... 11 It is generally agreed that CH 4 total oxidation proceeds through a Mars-Van Krevelen (M-vK) mechanism, during which the hydrocarbon molecules get adsorbed on the metal active sites followed by stepwise oxidation using lattice oxygen. 2 The oxygen vacancies created as a result can be filled by adsorption and dissociation of oxygen from the air during reaction. While supported PdO x nanoparticles are the state-ofthe-art catalytic materials for CH 4 complete oxidation, 12 nonnoble metal oxides such as Co 3 O 4 hexagonal nanosheets, 13,14 Co 3 O 4 nanoparticles, 5,15 Co 3 O 4 nanotubes, 16 CuO nanobelts, 17 bowtie-shaped spinel NiCo 2 O 4 catalysts, 18 and composites such as Co 3 O 4 /CeO 2 , 19 MnO x -NiO 20 and NiO/CeO 2 21 have also proved to be appealing candidates, with the added benefit of being much cheaper than noble metal catalysts. Spinel Co 3 O 4 or NiCo 2 O 4 type materials are among the most attractive as they can deliver complete CH 4 oxidation at temperatures in the neighbourhood of 500 1C. ...

Engineering Co3+-rich Crystal Planes on Co3O4 Hexagonal Nanosheets for CO and Hydrocarbons Oxidation with Enhanced Catalytic Activity and Water Resistance
  • Citing Article
  • May 2021

Chemical Engineering Journal

... [6] Therefore, in light of the escalating emission of VOCs and their consequential hazards, several control technologies have been developed to alleviate the influx of VOCs into the environment. [7,8] Currently, several destruction technologies, including thermal/catalytic oxidation, photocatalytic oxidation, and plasma catalysis, are employed to abate VOCs pollution by converting the VOCs into non or less toxic compounds such as CO 2 and H 2 O. [8,9] Among these technologies, catalytic combustion, which can operate at low-temperature to reduce the energy input, has garnered widespread recognition as one of the most dependable and efficient technique, [1] thereby witnessing extensive deployment by industrial facilities for VOCs treatment. [10] Iron, a representative earth-abundant transition element, [11,12] has evolved into an essential catalytic material and is used as both a support and an active component due to its distinctive physiochemical properties, such as various oxidation valence and large surface area. ...

Recent Progress of Thermocatalytic and Photo/Thermocatalytic Oxidation for VOCs Purification over Manganese-based Oxide Catalysts
  • Citing Article
  • March 2021

Environmental Science and Technology

... Previous research suggests that interlayer carbon can enhance electronic conductivity, suppress volume strain, and prevent the agglomeration of MoS 2 . For instance, MoS 2 -intercalated carbon hetero-layers [11] , fewlayer MoS 2 bonded with carbon [12] , C/MoS 2 /G Van der Waals (vdW) heterostructures [13] and expanded MoS 2 supported by N/O doped carbon [14] were investigated to have enhanced K + storage performance. Besides, building a three-dimensional (3D) charge transport network within the electrode using carbon structures such as a 3D graphene framework [15] or porous carbon skeleton [16,17] is another effective strategy for boosting K + storage performance, which offers feasible interconnected pathways for fast electron and ion transfer throughout the electrode. ...

Van der Waals heterostructure engineering by 2D space-confinement for advanced potassium-ion storage
  • Citing Article
  • January 2021

Nano Research