Nicolas Mangold's research while affiliated with French National Centre for Scientific Research and other places

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Publications (251)


Figure 1. Mars Raman spectra acquired with SuperCam on apatite SCCT (TAPAG) on different sols throughout the mission, normalized to the mean signal. The plots are color coded with sol number. (A) Normalized spectra (x axis shows wavenumber in cm −1 ); (B) Close-view in the 900-1000 cm −1 spectral range; baseline-corrected experimental data ( +) and fitted pseudo-Voigt profile (full lines). (C) Intensity of the ν 1 mode of apatite extracted from the normalized spectra (area of the fitted pseudo-Voigt profile) as a function of the sol of the observation. The error bars represent the uncertainty values of the parameters derived from the peak fitting procedure.
Figure 2. Laboratory Raman spectra acquired on an apatite target after different durations of UV irradiation (0 min, 5 min, 30 min, 270 min, 1270 min), normalized to the mean signal. The plots are color coded with irradiation time. (A) Normalized spectra (x-axis shows wavenumber in cm −1 ); (B) Close-view in the 900-1000 cm −1 spectral range; baseline-corrected experimental data ( +) and fitted pseudo-Voigt profile (full lines). (C) Intensity of the ν 1 mode of apatite extracted from the normalized spectra (amplitude of the fitted pseudo-Voigt profile) as a function of the duration of target irradiation. The error bars represent the uncertainty values of the parameters derived from the peak fitting procedure (smaller than the markers, in this case).
Figure 3. Remote microimages (RMIs) of the apatite SCCT acquired on Mars with SuperCam, corresponding to the first and one of the latest Raman spectra considered in this study (sols 51 and 836). The yellow ellipses represent the fields of view of the Raman observation (dashed: 68%; full line: 95%).
Radiation-induced alteration of apatite on the surface of Mars: first in situ observations with SuperCam Raman onboard Perseverance
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May 2024

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136 Reads

Scientific Reports

E. Clavé

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O. Beyssac

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S. Bernard

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[...]

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Allison Zastrow

Planetary exploration relies considerably on mineral characterization to advance our understanding of the solar system, the planets and their evolution. Thus, we must understand past and present processes that can alter materials exposed on the surface, affecting space mission data. Here, we analyze the first dataset monitoring the evolution of a known mineral target in situ on the Martian surface, brought there as a SuperCam calibration target onboard the Perseverance rover. We used Raman spectroscopy to monitor the crystalline state of a synthetic apatite sample over the first 950 Martian days (sols) of the Mars2020 mission. We note significant variations in the Raman spectra acquired on this target, specifically a decrease in the relative contribution of the Raman signal to the total signal. These observations are consistent with the results of a UV-irradiation test performed in the laboratory under conditions mimicking ambient Martian conditions. We conclude that the observed evolution reflects an alteration of the material, specifically the creation of electronic defects, due to its exposure to the Martian environment and, in particular, UV irradiation. This ongoing process of alteration of the Martian surface needs to be taken into account for mineralogical space mission data analysis.

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The high-resolution map of Oxia Planum, Mars; the landing site of the ExoMars Rosalind Franklin rover mission

March 2024

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197 Reads

Journal of Maps

Journal of Maps

This 1:30,000 scale geological map describes Oxia Planum, Mars, the landing site for the ExoMars Rosalind Franklin rover mission. The map represents our current understanding of bedrock units and their relationships prior to Rosalind Franklin’s exploration of this location. The map details 15 bedrock units organised into 6 groups and 7 textural and surficial units. The bedrock units were identified using visible and near-infrared remote sensing datasets. The objectives of this map are (i) to identify where the most astrobiologically relevant rocks are likely to be found, (ii) to show where hypotheses about their geological context (within Oxia Planum and in the wider geological history of Mars) can be tested, (iii) to inform both the long-term (hundreds of metres to ∼1 km) and the short-term (tens of metres) activity planning for rover exploration, and (iv) to allow the samples analysed by the rover to be interpreted within their regional geological context.


Architecture of fluvial and deltaic deposits exposed along the eastern edge of Jezero crater western fan

November 2023

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120 Reads

Early observations from the Perseverance rover suggested a deltaic origin for the western fan of Jezero crater only from images of the Kodiak butte. Here, we use images from the SuperCam Remote Micro-Imager and the Mastcam-Z camera to analyze the western fan front along the rover traverse, and further assess its depositional origin. Outcrops in the middle to lower half of hillslopes are composed of planar, inclined beds of sandstone that are interpreted as foresets of deltaic deposits. Foresets are locally structured in ~20-25 m thick, ~80-100 m long, antiformal structures interpreted as deltaic mouth bars. Above these foresets are observed interbedded sandstones and boulder conglomerates, interpreted as fluvial topset beds. One well-preserved lens of boulder conglomerate displays rounded clasts within well-sorted sediment deposited in fining upward beds. We interpret these deposits as resulting from lateral accretion within fluvial channels. Estimations of peak discharge rates give a range between ~100 and ~500 m3.s-1 consistent with moderate to high floods. By contrast, boulder conglomerates exposed in the uppermost part of hillslopes are poorly sorted and truncate underlying beds. The presence of these boulder deposits suggests that intense, sediment-laden flood episodes occurred after the deltaic foreset and topset beds were deposited, although the origin, timing, and relationship of these boulder deposits to the ancient lake that once filled Jezero crater remains undetermined. Overall, these observations confirm the deltaic nature of the fan front, and suggest a highly variable fluvial input.




Fig. 1: A. Perseverance rover's route in Jezero crater up to sol 640. B.-E. Light-toned veins observations and compositional analysis via the SuperCam instrument.
Fig. 2: Examples of light-toned veins and material. As seen via Mastcam-Z & RMI images in sedimentary rocks (A-C) and at Kibler Knob (D). E: In an abraded patch (WATSON & Mastcam-Z images). F: Sampling tube CacheCam image. Mcam-Z images IDs:
Fig. 3: Composition of a light-toned vein as analyzed with the SuperCam instrument's LIBS technique. Mcam-Z image ID: ZLF_0510_0712218603_973RAD_N0261222ZCAM08533_1100LMJ01.
LIGHT-TONED VEINS AND MATERIAL IN JEZERO CRATER, MARS, AS SEEN IN-SITU VIA NASA'S PERSEVERANCE ROVER (MARS 2020 MISSION): STRATIGRAPHIC DISTRIBUTION AND COMPOSITIONAL RESULTS FROM THE SUPERCAM INSTRUMENT

March 2023

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36 Reads

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4 Citations

Within Jezero crater, the Perseverance rover currently explores the lowermost-exposed scarp of the delta (Fig. 1) [1,2]. Here we: (1) present the distribution of light-toned veins currently observed via the rover along its route in Jezero crater; (2) introduce compositional results of veins as analyzed via Perseverance’s SuperCam instrument, and place them into the context of results from the other instruments.


THE DELTAIC DEPOSITIONAL ENVIRONMENTS AND STRATIGRAPHY OF THE KODIAK BUTTE (JEZERO CRATER, MARS)

March 2023

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6 Reads

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1 Citation

For two years, the Perseverance rover has been exploring the Jezero crater floor. A lot of remote observations have been made on the delta front and its remnants, and notably toward the Kodiak butte, situated about 1 km south of the main delta front (Fig. 1). There, morphologies typical of a Gilbert-type delta have been identified [1] using long-distance observations carried out by SuperCam’s Remote Micro-Imager (RMI) and Mastcam-Z (Fig. 2). In this work, we use high-resolution 2D images, as well as 3D Digital Outcrop Models [2;3], to document and characterize the sedimentary succession observed up the cliffs of Kodiak. We divide the Kodiak butte into 3 units (0 to 2) with further sub-facies divisions described below.


Fig. 1: Region of interest with main targets. Location of Fig. 4 is indicated. Scale bar is 50m.
Figure 2 depicts representative textures along the transect. The igneous Séítah unit outcrops to the south (sols 417-420) and is the lowest exposed crater floor formation visited by the rover. The rocks are massive and dispersed among the regolith ripples. They appear relatively flat although it is hard to define a clear bedding. Texturally, the rocks are granular (mm grains), bearing high similarity with the cumulate texture described for Séítah outcrops explored previously [4,6,7]. The King Salmon group is composed of flat rock exposures gently dipping (a few degrees) towards the north. At King Salmon (sol 421), texture is granular, similar to Séítah, while it is still granular but texturally altered to the north (TwoHeaded Island sol 642). Before reaching the delta sediments, the rover crossed an area filled by regolith with disperse exposures of small ridges forming outcrops: these ridges are composed of granular rocks with 1-2 mm rounded grains (Alagogshak sol 456). Upsection, the delta sediments appear as flat-lying outcrops with a completely different texture composed of fine-grained sandstones with thin planar mm to cm thick layers. Rocks are greyish on vertical faces and more reddish on horizontal faces suggesting the presence of coatings or dust crust.
Fig. 3: Top: Pyroxene composition for Séítah (white, from [6]), Máaz (black, from [5]), delta sediments at Enchanted Lake (red), King Salmon rocks (green) and Alagogshak (orange). Bottom: olivine Mg# for all Séítah (data from [6] plus King Salmon) and for possible olivine in mixtures for the delta.
Fig. 4: Schematic section illustrating the transition from Séítah to the delta. Location shown on Fig. 1.
A JOURNEY ACROSS THE TRANSITION BETWEEN THE IGNEOUS SÉÍTAH FLOOR UNIT AND THE DELTA WITH THE MARS2020 SUPERCAM INSTRUMENT AT JEZERO CRATER, MARS

During the first scientific campaign, Perseverance explored the Jezero crater floor and found two main igneous formations: the basaltic Máaz unit, and Séítah, consisting of an olivine-rich cumulate. Then the rover did a rapid traverse towards the second campaign region, Jezero’s delta. Just before reaching the lowest part of the delta, Perseverance encountered the Séítah formation again, with some variability in the degree of alteration. Here, we use the data obtained by the SuperCam instrument to document the structure and texture of rocks at the transition between Séítah and the delta front, its geochemistry and its primary and secondary mineralogy. Then, we discuss the simi-larities/differences between these rocks and discuss a geological scenario to account for these observations.


3D RECONSTRUCTION OF LUNAR ROCK SAMPLES FROM THE APOLLO 17 MISSION

The Apollo 17 manned mission land-ed in the Taurus Littrow valley on the Moon in De-cember 1972. The geology of this site was thoroughly investigated during extra vehicular activities performed during three days spent at the surface [1, 2]. A total of 111 kg of well-documented rock and soil samples were collected and brought back to Earth. Among several waypoints of interest, astronauts spent more than one hour to investigate five large boulder fragments at Sta-tion 6, lying at the base of the North Massif. Schmitt et al.’s [2] analysis indicates that original single boulder originated in Crisium-age melt breccia ejecta overlain by Serenitatis-age melt breccia ejecta. Earlier photoge-ologic interpretations had suggested that the North Massif was largely Serenitatis in age [3, 4]. In a previ-ous study [5], we used scanned photographs taken in situ with astronaut’s Hasselblad film cameras to recon-struct a 3D model of each of the boulders using Struc-ture-from-Motion photogrammetry techniques. In addi-tion to the 3D reconstruction of the boulders them-selves reported in [5], we have now reconstructed in 3D several rock samples hammered from the boulders, using archived photographs from the Lunar Receiving Lab facility in Houston.


Figure 1 -Geochemistry of the main geologic units of the delta front, from SuperCam LIBS data.
Figure 2 -Average near-infrared reflectance spectra of the main geologic units of the delta front.
OVERVIEW OF THE BEDROCK GEOCHEMISTRY AND MINERALOGY OBSERVED BY SUPERCAM DURING PERSEVERANCE'S DELTA FRONT CAMPAIGN

March 2023

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21 Reads

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6 Citations

In February 2021, the Perseverance rover landed in Jezero crater, Mars. The crater floor was found to be composed of lava flows and cumulate rocks [1-5]. These magmatic rocks appear to have undergone some limited aqueous alteration; however, it is not clear whether this alteration is related to the lacustrine phase of the crater [1,3,6,7]. After completing its exploration of the crater floor, Perseverance reached the foot of the Jezero western fan in late April 2022 (sol ~422). Long-distance images acquired earlier in the mission had already confirmed the deltaic nature of the fan [8], which had long been suspected from orbital observations [9,10]. Between April and December 2022, Perseverance investigated the basal layers of the delta at two locations named Hawksbill Gap and Cape Nukshak, which are ~400 m apart [11]. Here, we present an overview of the geo-chemistry and mineralogy of the delta rocks as observed by SuperCam, and show that these rocks record a diver-sity of past aqueous alteration environments.


Citations (47)


... Sulfate has also been observed to occur as light-toned veins in the Gale Crater, Jezero Crater, and Endeavor Crater [18][19][20][21]. The predominant phases in these light veins have primarily been identified as calcium sulfates exhibiting varying degrees of hydration, including anhydrite, bassanite, and gypsum [18][19][20][21]. ...

Reference:

Spectroscopy of Magnesium Sulfate Double Salts and Their Implications for Mars Exploration
LIGHT-TONED VEINS AND MATERIAL IN JEZERO CRATER, MARS, AS SEEN IN-SITU VIA NASA'S PERSEVERANCE ROVER (MARS 2020 MISSION): STRATIGRAPHIC DISTRIBUTION AND COMPOSITIONAL RESULTS FROM THE SUPERCAM INSTRUMENT

... These columns include only those strata of the western fan front that have been designated Shenandoah formation by the Mars 2020 Science Team. These columns do not include strata exposed in the fan front exposures above the Shenandoah formation (e.g., Gupta et al. (2023) and Mangold et al. (2023)). ...

FROM LAKE DEPOSITS TO FLUVIAL FLOODS AT THE EASTERN DELTA FRONT OF JEZERO CRATER, MARS

... The maximum height of the butte is ∼75 m above the local crater floor level (Figure 1d), with the top elevation nearly identical to that of the main fan front (Figures 1c and 1d). The similar elevation and erosional expression observed on both the butte and the main fan (e.g., Gupta et al., 2022;Mangold et al., 2021;Mangold et al., 2024) suggests Kodiak as an erosional remnant that has been isolated from the main fan (cf. Stack et al., 2020). ...

FINE-SCALE SEDIMENTARY ARCHITECTURE OF THE UPPER PART OF THE JEZERO WESTERN DELTA FRONT

... The closest match is vermiculite, a phyllosilicate phase with a structure intermediate between mica, smectite, and saponite (Mandon et al., 2021). Vermiculite was also detected at Jezero Crater where the Perseverance rover landed in February 2021 (Dehouck et al., 2023). Phyllosilicates are characterized by a high organic sequestration and preservation potential (Ehlmann et al., 2008), which makes them desirable targets for investigations on Mars. ...

OVERVIEW OF THE BEDROCK GEOCHEMISTRY AND MINERALOGY OBSERVED BY SUPERCAM DURING PERSEVERANCE'S DELTA FRONT CAMPAIGN

... In total, 10 astronauts from ESA, NASA and Roscosmos and additional 5 non-astronaut trainees including space engineers, EVA and operation specialists have attended the course. In this work we will summarise the course strategy, structure and lessons learned, but for a more detailed description the reader is referred to Sauro et al. [1] . ...

Training astronauts for scientific exploration on planetary surfaces: The ESA PANGAEA programme
  • Citing Article
  • December 2022

Acta Astronautica

... Phobos also possesses a nearly circular orbits very close to its parent planet, 6,000 kilometers above the Martian surface, within a few degrees of the equatorial plane. [25] [26] This coupled with the size of Stickney Crater, about 9km wide and 22km deep, means the Phari base would be offered an almost unprecedented amount of radiation protection from galactic cosmic rays (GCRs) and solar energetic particles (SEPs) simply being shielded by both planetary bodies. [27] It has been proposed that any object positioned inside Stickney Crater would be shielded from as much as 90% of galactic cosmic radiation, with an increase to that percentage of the base were placed on the west side of the slope. ...

From science questions to Solar System exploration
  • Citing Chapter
  • January 2022

... The outcomes of the non-rejected predictions are shown in Figure 17 in the same type of bar plot as the clustering results. The period corresponds to section F in Figure 10 and is also discussed in Dehouck et al. (2021aDehouck et al. ( , 2021b in more detail. Due to a technical issue with the ChemCam laser, no LIBS measurements were possible in the time period of sols 3008-3106, which appears as a gap in Figure 10. ...

Bedrock geochemistry measured by ChemCam along a 2-km eastward traverse in the Glen Torridon region, Gale crater, Mars

... 64 1 Introduction 67 Analyses of X-ray diffraction data from the CheMin instrument on the Mars Science 68 Laboratory rover have documented abundant (15-73 wt.%) X-ray amorphous material, likely 69 encompassing amorphous material, short-range order phases, and nanocrystallites less than 70 roughly 100 nm in diameter (Klug & Alexander, 1974;, in all ancient 71 fluvial-lacustrine and aeolian rocks and modern aeolian sediments analyzed to date at Gale SiO 2 , SiO 2 that is directly proportional to total X-ray amorphous wt.% abundance, and potential 85 primary glass contributions of ~0.1-57 wt.% are consistent with a substantial proportion of the 86 Gale crater X-ray amorphous material being composed of aqueous alteration products (Smith et (Greenberger et al., 2015) and methane (Szponar et al., 2013) to the early martian atmosphere, 97 and the potential for serpentinization to produce clay and carbonate mineral assemblages similar 98 to those found in Jezero crater (Grosch et al., 2021). Serpentinized minerals (serpentine and talc) 99 have also been directly detected within Jezero crater where the Perseverance rover is currently 100 caching samples for return to Earth (Farley et al., 2022;Liu et al., 2022), and the serpentine 101 polymorph greenalite is potentially present in the sedimentary rocks at Glen Torridon in Gale 102 crater (Thorpe et al., 2022). Serpentine soils therefore provide a useful Mg/Fe/Si-rich and Al-103 poor chemical environment for studying the influence of climatic variation on the development 104 of Fe/Si-rich, sometimes Mg-rich, and Al-poor X-ray amorphous aqueous alteration products 105 like those found in Gale crater and potentially elsewhere on Mars. ...

Aqueously altered igneous rocks sampled on the floor of Jezero crater, Mars
  • Citing Article
  • September 2022

... Despite the extensive green-red mottling in the Cardiff paleosols, Fe oxide signatures are largely absent in visible wavelengths. Only one sample, the A-horizon of the lowermost profile, had band centers near 0.5 and 0.86 µm, characteristic of Fe oxides such as hematite 53,54 . Interestingly, the lowermost profile was the reddest of the three profiles and suggested it may have been less affected by early diagenetic burial gleization 55 . ...

Mineralogy of a Possible Ancient Lakeshore in the Sutton Island Member of Mt. Sharp, Gale Crater, Mars, From Mastcam Multispectral Images

... www.nature.com/scientificreports/ detection and characterization of mineral phases, including perchlorate, sulfate, olivine and carbonate, in Martian geologic targets [21][22][23][24][25][26][27][28] . The SuperCam instrument also enables chemical analyses with laser-induced breakdown spectroscopy (LIBS), mineralogical analyses with visible and near-infrared reflectance spectroscopy (VISIR), texture characterization with a remote microimager (RMI) and acoustic measurements with a microphone 15,16 . ...

Compositionally and density stratified igneous terrain in Jezero crater, Mars

Science Advances