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November 2016
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53 Reads
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31 Citations
Organic & Biomolecular Chemistry
We report novel synthetic routes for facile preparation of highly functionalized fullerene derivatives C60(OR)5X (X = H, Cl, Br), C60(OR)4O and C60(OR)2 from chlorofullerene C60Cl6. The first water-soluble fullerene compound bearing residues of 3-oxypropanoic acid demonstrated a potent anti-HIV activity.
... Besides these studies, there are works devoted to the synthesis of various highly symmetric fullerene C 60 polyadducts, when a chlorofullerene C 60 Cl 6 was used as a starting compound. Indeed, this method makes it possible to obtain various alkoxyfullerenes [12], aminofullerenes [13], sulfides [14], and arylated [15] C 60 derivatives, which have particular interest and application in medicine [16,17]. ...
November 2016
Organic & Biomolecular Chemistry
