Limin Sun's research while affiliated with Zhengzhou University and other places

High-performance electrodes can solve problems of high voltage and large electricity consumption existing in chlor-alkali industry. A Ti/Al laminate composite (named as Ti/Al-LC) with three-layered structure (Ti/Al 3 Ti/Ti) is prepared as a new type of anode electrode for chlor-alkali electrolysis. Scanning electron microscope observation shows that the Ti/Al-LC is composited of a thicker inner layer with thickness about 700 µm and two thinner outer layers with thickness about 300 µm. From the X-ray diffraction pattern, it is known that the outer layers consisted of α-Ti and β-Ti phases, while the inner layer consisted of Al 3 Ti intermetallic phase. A saturated sodium chloride (NaCl) solution at 70°C is purposely chosen as the corrosion electrolyte to analyze the corrosion behavior of Ti/Al-LC as anode electrode for chlor-alkali electrolysis. Electrochemical tests, including potentiodynamic polarization and electrochemical impedance spectroscopy measurements, on a three-electrode system indicate that the Ti/Al-LC has a low corrosion rate with corrosion current density of 1.94 µA cm ⁻² and stable surface passive film in saturated NaCl solution at 70°C.

The metal-intermetallic laminate composite Ti/Al 3 Ti can be used as protective armor in aerospace and military applications, due to its low density, high strength, and superior impact-resistant performance. The ballistic performance of the laminate composite was studied by ballistic testing and finite element technology. The failure modes, such as radical cracks, layer delamination, and plastic deformation, have been found after the ballistic test, and the specific energy absorption was used to evaluate the ballistic capacity of the material. The finite element model of the Ti/Al 3 Ti impacted by the projectile was established by considering the interface, which was simulated by the solid elements with zero thickness. The simulation results demonstrate the failure process of the interface during penetration. The interfacial failure allowed for layer detachment with its labor layers. The simulation results agree well with that of the experiment, and the practicality and credibility of the model is verified.