Kunpeng Dou's research while affiliated with Ocean University of China and other places

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Publications (30)


Highly efficient photocatalytic antifouling activity of core–shell structural encapsulation Bi2MoO6 with visible-light responsive ZIF-67
  • Article

April 2024

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18 Reads

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1 Citation

Applied Surface Science

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Nan Wang

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[...]

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Baorong Hou
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Fig. 3 The negative decay factor β for atomic models in Fig. 2
Fig. 4 Nonadditive and additive transport in all carbon double-channel single-molecule circuits. The models in the upper panel are double polyacene (PA) bridging carbon nanotube (CNT) electrodes which deviate from Kirchhoff's circuit laws. The lower models are double PA bridging zigzag graphene nanoribbon (GNR) electrodes which fulfill the linear conductance superposition rule. Reprinted with permission from ref [22]. Copyright 2016 American Chemical Society
Collection of unconventional transport phenomena: natural obstacle or vibrant guiding principle for the design of molecular junctions?
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  • Full-text available

January 2024

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32 Reads

AAPPS Bulletin

The real atomic scale details of molecular junctions would be of much complexity and can yield a plethora of “counterintuitive” results. Here, we provide an overview of four unconventional intentional or unintentional transport phenomena in molecular junctions, in particular, unconventional tunneling length-dependent transport behavior, deviation from Kirchhoff’s superposition law, dual roles of imperfect engineering, and masked quantum interference. These abnormal phenomena are not engaged in a dead end. On the contrary, it offers plenty of research opportunities in molecular electronics.

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Ascorbic Acid Induced the Improved Oxygen Vacancy Defects of Bi4O5Br2 and Its Application on Photoelectrochemical Detection of DNA Demethylase MBD2 with Improved Detection Sensitivity

November 2023

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14 Reads

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4 Citations

Small

Oxygen vacancy defects (OVs) are one of the main strategies for nanomaterials modification to improve the photoactivity, but current methods for fabricating OVs are usually complicated and harsh. It is important to develop simple, rapid, safe, and mild methods to fabricate OVs. By studying the effects of different weak reducing agents, the concentration of the reducing agent and the reaction time on fabrication of OVs, it is found that L‐ascorbic acid (AA) gently and rapidly induces the increase of OVs in Bi4O5Br2 at room temperature. The increased OVs not only improve the adsorption of visible light, but also enhance the photocurrent response. Based on this, the preparation of OVs in Bi4O5Br2 is employed to the development of a photoelectrochemical biosensor for the detection of DNA demethylase of methyl‐CpG binding domain protein 2 (MBD2). The biosensor shows a wide linear range of 0.1–400 ng mL⁻¹ and a detection limit as low as 0.03 ng mL⁻¹ (3σ). In addition, the effect of plasticizers on MBD2 activity is evaluated using this sensor. This work not only provides a novel method to prepare OVs in bismuth rich materials, but also explores a new novel evaluation tool for studying the ecotoxicological effects of contaminants.



S vacancy in MoS2 nanosheets induces H2O cleavage: a new era for 2D nanozyme

September 2023

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38 Reads

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2 Citations

Research on Chemical Intermediates

Nanozyme is a promising approach in treating pollution in drinking water sources. 2D MoS2 nanosheets, with abundant active sites and Lewis acid sites, exhibit outstanding peroxidase-like activity. Verified by density functional calculation, S vacancies in 2D MoS2 nanosheets can cleavage H2O to yield H⁺ and ·OH. The spontaneous generation of acid environment and oxygen free radicals enables 2D MoS2 nanosheets to be effectively exploited in the depuration of polluted water, creating a new era for multifunctional nanozymes.



Figure 2
S vacancy in MoS 2 nanosheets induce H 2 O cleavage: a new era for 2D nanozyme

June 2023

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25 Reads

Nanozyme is a promising approach in treating pollution in drinking water sources. 2D MoS 2 nanosheets, with abundant active sites and Lewis acid sites, exhibits outstanding peroxidase-like and antibacterial activities. Verified by density functional calculation, S vacancies in 2D MoS 2 nanosheets can cleavage H 2 O to yield H ⁺ and ·OH. The spontaneous generation of acid environment and oxygen free radicals enables 2D MoS 2 nanosheets to be effectively exploited in the depuration of polluted water, creating a new era for multifunctional nanozymes.



Citations (21)


... The degradation of ciprofloxacin was significantly enhanced by the photocatalytic activity of Bi/BiOF/Bi/BiOF/ Bi 2 O 2 CO 3 , which was 7 and 3.5 times greater than that of BiOF and Bi/BiOF/Bi 2 O 2 CO 3 respectively. [270] The Y-doped bismuth oxy fluoride/reduced graphene oxide (Y-BiOF/RGO) composite was synthesized using a straightforward solvothermal technique. The synthesized composite has been studied employing techniques that include transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), photoluminescence spectroscopy (PL), UV-Vis diffuse reflectance spectroscopy (DRS), FT-IR, and X-ray diffraction (XRD). ...

Reference:

Review On Strategies For the Design and Synthesis of Flower‐Like Bi2WO6 and BiOX (X=F, Cl, Br, I) Composites for Photocatalytic Environmental Remediation
One-pot preparation of Bi/BiOF/Bi2O2CO3 Z-scheme heterojunction with enhanced photocatalysis activity for ciprofloxacin degradation under simulated sunlight
  • Citing Article
  • December 2023

Materials Today Nano

... Generally, the total friction between layers and surfaces of layered 2D materials is composed of internal friction and edge friction. In 2D materials with small sizes, the friction is mainly caused by the edges [49,84,95,110]. Especially for heterogeneous structures, the contribution of edge atoms to friction is one to two orders of magnitude larger than that of in-plane atoms [111]. ...

Edge-pinning effect of graphene nanoflakes sliding atop graphene
  • Citing Article
  • November 2023

Materials Today Physics

... Supported metal catalysts are important catalysts for catalytic hydrogenation and upgrading of oil products in reducing the content of aromatics. Metal sulfides (CoMoS, NiMoS) [3][4][5] and metals (Ni, Pt, Pd) [6][7][8][9][10] were widely studied in this kind of reaction as active components. Metal sulfide catalysts can effectively improve the resistance of catalysts to sulfur, but the reaction conditions were harsh. ...

S vacancy in MoS2 nanosheets induces H2O cleavage: a new era for 2D nanozyme

Research on Chemical Intermediates

... Therefore, the potential of green mussel shells as a material for HA synthesis will be examined in this research. 14 Green mussel shells contain two polymorphs of calcium carbonate (CaCO 3 ), namely calcite and aragonite. 15 Most organic compounds can be found among the crystallites (intercrystalline), but some organic molecules (intercrystalline) are also intercalated in the crystal lattice. ...

Trash to treasure: Green synthesis of novel Ag2O/Ag2CO3 Z-scheme heterojunctions with highly efficient photocatalytic activities derived from waste mussel shells
  • Citing Article
  • November 2022

Chemical Engineering Journal

... However, dye wastewater contains a large amount of azoles and polycyclic aromatics that are challenging to degrade [2], which leads to environment pollution and serious threat to human health [3,4]. To solve those problems, various methods, including adsorption [5][6][7], flocculation [8][9][10][11], biological oxidation [12][13][14], and photodegradation [15][16][17][18] are employed. Among these, photodegradation technology has garnered significant attention due to its merits, such as high efficiency, low cost, and ease of operation [19]. ...

1D Bi2S3 nanorods modified 2D BiOI nanoplates for highly efficient photocatalytic activity: Pivotal roles of oxygen vacancies and Z-scheme heterojunction
  • Citing Article
  • November 2022

Journal of Material Science and Technology

... Additionally, the photo-corrosion phenomenon can be developed due to the low migration efficiency of photo-excited charge carriers, further limiting the photocatalytic activity of Bi 5 O 7 I [90]. Fortunately, a series of adequate optimizing modifications, like semiconductor composites, noble metal doping, and surface engineering, can be harvested to strengthen solar light utilization and improve the optical properties of Bi 5 O 7 I-based heterojunction [91]. ...

In-situ topotactic construction of novel rod-like Bi2S3/Bi5O7I p-n heterojunctions with highly enhanced photocatalytic activities
  • Citing Article
  • August 2022

Journal of Material Science and Technology

... eV), indicating that the Fe 1 CN-20 catalyst can readily adsorb PMS molecules. This also means that PMS molecules are more easily adsorbed and activated on Fe 1 CN-20 [89]. Meanwhile, the glucose adsorption energy (E ab = -4.629 ...

“Nano Killers” Activation by Permonosulfate Enables Efficient Anaerobic Microorganisms Disinfection
  • Citing Article
  • August 2022

Journal of Hazardous Materials

... In Fig. 7a, the 0.2CBO/BMO curve exhibited the smallest radius, confirming that the electron transfer efficiency of 0.2CBO/BMO was greater than that of CBO and BMO. Additionally, the current density of 0.2CBO/BMO was much greater than that of CBO and BMO, providing evidence that the combination of CBO and BMO effectively promoted the migration of photogenerated carriers (Fig. 7b) [44][45][46]. Figure 8a shows the degradation curve of TC using a series of photocatalysts under visible light conditions. Prior to photocatalytic degradation, the reaction system was placed in a dark environment and stirred for 30 min to achieve adsorption equilibrium. ...

Facile in-situ construction of plate-on-plate structured Bi2MoO6/BiOI Z-scheme heterojunctions enriched with oxygen vacancies for highly efficient photocatalytic performances
  • Citing Article
  • July 2022

Applied Surface Science

... After composited into the MoS 2 -Zn coatings, it remained the same antibacterial mechanism as MoS 2 particles, described as follows: Under light irradiation, MoS 2 in the MoS 2 -Zn coatings were excited, leading to the transition of e − from the valence band (VB) to the conduction band (CB), and then leaving h + on the VB. The sufficiently reducing e − on the CB of MoS 2 trapped dissolved oxygen in the water and reacted by catalytic reaction to produce the dominant active radicals ⋅O 2 - [70]. Meanwhile, H 2 O was also catalyzed by a small amount of ⋅O 2 to produce ⋅OH [71], which was tested as the subordinate active radical in the antifouling process. ...

Facile fabrication of a novel spindlelike MoS2/BiVO4 Z-scheme heterostructure with superior visible-light-driven photocatalytic disinfection performance
  • Citing Article
  • July 2022

Separation and Purification Technology

... Liu et al. [20] prepared an in situ Z-scheme Bi 2 MoO 6 /AgI heterojunction, where the photogenerated electrons at the heterojunction interface were effectively transferred from AgI to Bi 2 MoO 6 , which exhibited excellent photocatalytic activity for the degradation of malachite green (MG). Compared with conventional heterojunction structures, p-n heterojunctions are more favorable for carrier separation due to their unique energy band structure and carrier transport properties [21,22], such as Bi 2 MoO 6 /KNbO 3 [23], BiOBr/Bi 2 MoO 6 [24], and Bi 2 MoO 6 /CuBi 2 O 4 [25]. Particularly, CuS as a conventional p-type narrow band gap semiconductor has recently attracted attention due to its excellent photoelectrochemical properties, low toxicity, and structural stability [26,27]. ...

Novel plate-on-plate hollow structured BiOBr/Bi2MoO6 p-n heterojunctions: In-situ chemical etching preparation and highly improved photocatalytic antibacterial activity
  • Citing Article
  • July 2022

Separation and Purification Technology