John Stringer's scientific contributions
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Publications (2)
Electronic and structural properties of short-lived metal-peroxido complexes, which are key intermediates in many enzymatic reactions, are not fully understood. While detected in various enzymes, their catalytic properties remain elusive because of their transient nature, making them difficult to study spectroscopically. We integrated ¹⁷O solid-sta...
Citations
... 522−530 Many recent studies have utilized homo-or heteronuclear proton and fluorine distance restraints in structural refinement. 212,526,531,532 Figure 35a shows the 1 H and 19 F spectra of a few pharmaceutical compounds acquired at 12 kHz and 60 kHz MAS, including posaconazole, 516 indomethacin, 517 aprepitant, 518 and pioglitazone. 519 The comparisons demonstrate significant improvement in both spectral sensitivity and resolution. ...