June 2024
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3 Reads
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June 2024
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3 Reads
June 2024
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2 Reads
April 2024
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48 Reads
The electrolytes for lithium metal batteries (LMBs) are plagued by a low Li⁺ transference number (T+) of conventional lithium salts and inability to form a stable solid electrolyte interphase (SEI). Here, we synthesized a self‐folded lithium salt, lithium 2‐[2‐(2‐methoxy ethoxy)ethoxy]ethanesulfonyl(trifluoromethanesulfonyl) imide (LiETFSI), and comparatively studied with its structure analogue, lithium 1,1,1‐trifluoro‐N‐[2‐[2‐(2‐methoxyethoxy)ethoxy)]ethyl]methanesulfonamide (LiFEA). The special anion chemistry imparts the following new characteristics: i) In both LiFEA and LiETFSI, the ethylene oxide moiety efficiently captures Li⁺, resulting in a self‐folded structure and high T+ around 0.8. ii) For LiFEA, a Li−N bond (2.069 Å) is revealed by single crystal X‐ray diffraction, indicating that the FEA anion possesses a high donor number (DN) and thus an intensive interphase “self‐cleaning” function for an ultra‐thin and compact SEI. iii) Starting from LiFEA, an electron‐withdrawing sulfone group is introduced near the N atom. The distance of Li−N is tuned from 2.069 Å in LiFEA to 4.367 Å in LiETFSI. This alteration enhances ionic separation, achieves a more balanced DN, and tunes the self‐cleaning intensity for a reinforced SEI. Consequently, the fast charging/discharging capability of LMBs is progressively improved. This rationally tuned anion chemistry reshapes the interactions among Li⁺, anions, and solvents, presenting new prospects for advanced LMBs.
March 2024
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10 Reads
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1 Citation
Advanced Fiber Materials
Sulfurized polyacrylonitrile (SPAN) has emerged as an excellent cathode material for lithium–sulfur batteries (LiSBs), and it addresses the shuttle effect through a solid‒solid reaction. However, the actual sulfur loadings in SPAN often remain below 40 wt%. Due to the susceptibility of polysulfides-to-nucleophilic reactions with electrolytes, achieving physical encapsulation of elemental sulfur is a challenging task. In this study, a free-standing cathode material with a high sulfur/selenium (S/Se) loading of 55 wt% was fabricated by introducing SeSx into the unique lotus root-like pores of porous SeSxPAN nanofiber membranes by electrospinning and a two-step heat treatment. Insoluble compounds were formed due to nucleophilic interactions between lithium polyselenosulfides (LiSeSx) and the electrolyte, which potently blocked the existing lotus root-like pores and facilitated the creation of a thin cathode–electrolyte interphase on the fiber surface. This dual functionality of LiSeSx safeguarded the active material embedded within the porous structure. The SeS15PAN cathode exhibited remarkable cycling stability with almost no degradation after 200 cycles at 0.2 C, along with a high discharge capacity of 580 mAh/g. This approach presents a solution for addressing the insufficient sulfur content in SPAN.
March 2024
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10 Reads
Angewandte Chemie
The electrolytes for lithium metal batteries (LMBs) are plagued by a low Li+ transference number (T+) of conventional lithium salts and inability to form a stable solid electrolyte interphase (SEI). Here, we synthesized a self‐folded lithium salt, lithium 2‐[2‐(2‐methoxyethoxy)ethoxy]ethanesulfonyl(trifluoromethanesulfonyl) imide (LiETFSI), and comparatively studied with its structure analogue, lithium 1,1,1‐trifluoro‐N‐[2‐[2‐(2‐methoxyethoxy)ethoxy)]ethyl]methanesulfonamide (LiFEA). The special anion chemistry imparts the following new characteristics: i) In both LiFEA and LiETFSI, the ethylene oxide moiety efficiently captures Li+, resulting in a self‐folded structure and high T+ around 0.8. ii) For LiFEA, a Li‐N bond (2.069 Å) is revealed by single crystal X‐ray diffraction, indicating that the FEA anion possesses a high donor number (DN) and thus the intensive interphase “self‐cleaning” function for an ultra‐thin and compact SEI. iii) Starting from LiFEA, an electron‐withdrawing sulfone group is introduced near the N atom. The distance of Li‐N is tuned from 2.069 Å in LiFEA to 4.367 Å in LiETFSI. This alteration enhances ionic separation, achieves a more balanced DN, and tunes the self‐cleaning intensity for a reinforced SEI. Consequently, the fast charging/discharging capability of LMBs is progressively improved. This rationally tuned anion chemistry reshapes the interactions among Li+, anions, and solvents, presenting new prospects for advanced LMBs.
March 2024
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7 Reads
Applied Surface Science
February 2024
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2 Citations
Materials Letters
January 2024
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1 Read
Energy & Environmental Science
Electrolyte for low temperature high energy lithium metal battery is expected to possess both fast Li+ transfer in the bulk (low bulk resistance) and fast Li+ de-solvation process at the...
December 2023
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1 Read
December 2023
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3 Reads
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1 Citation
ACS Applied Nano Materials
... Kai Liu's team designed asymmetric trihaloaromatic lithium salts for solid polymer electrolytes to promote the formation of SEI film enriched with LiF and LiBr, thereby improving interface stability (Figure 6 b). [120] The incorporation of LiF and LiBr in the SEI film was found to significantly enhance Young's modulus and surface energy, thereby promoting the homogenization of Li + flux. Moreover, the presence of LiBr effectively reduces the diffusion barrier for Li + within the SEI film. ...
October 2023
ACS Nano
... Upon cycling, the O spectrum collected at the Li/LPS-0.05SnO 2 interface additionally shows a Li 2 O peak at 526.6 eV. The presence of Li 2 O in the interphase would modulate interfacial lithium deposition behaviors and maintain the stability of the SSE/Li interphase, thus inhibiting lithium dendrite formation within the SSE [46,47] . The initial S spectrum of LPS-0.05SnO 2 is ascribed to non-bridging sulfur Li-S-P and bridging sulfur P-S-P. ...
August 2023
ACS Nano
... where V cell and C full are the average working voltage and the reversible capacity of the full cell, respectively, m total is the total weight based on the sum of current collector, cathode, anode, separator and electrolyte. The weight of the packing cell bag is excluded from the specific energy calculation due to our limited size of cell 42,43 . To assess the overcharge-safety, the pouch cells were charged from the open circuit voltage to 9 V at a scan rate of 20 mV s -1 , and the infrared thermography images of the pouch cells were captured using a FLIR ONE PRO. ...
May 2023
ACS Nano
... Compared with traditional nanomaterials such as metal nanomaterials, lipid nanoparticles, polymer nanoparticles, and carbon nanomaterials, biomass materials have good reproducibility and biocompatibility, and their development value far exceeds that of other materials (Lugoloobi et al. 2021;Liu et al. 2023a). As representatives of biomass materials, cellulose nanocrystals (CNCs) and polydopamine (PDA) have received extensive attention in the biomedical field for their strong hydrophilicity, good biocompatibility, and ability to be prepared in large quantities (Long et al. 2021;Cui et al. 2023;Liu et al. 2022). It is reported that the morphology, proper aspect ratio, and rigid backbone of the materials affect the cellular uptake, while the rod-like structure of CNCs can enhance cellular internalization and improve transfection efficiency Gratton et al. 2008;Lin et al. 2015). ...
March 2023
Cellulose
... However, their activities still fell short compared to those of carbon catalysts and commercial Pt/C catalysts, and the current record for a half-wave potential is 0.75 V vs. RHE. This limited activity was attributed to the poor electron conductivity of the frameworks and the weak binding of O 2 and other oxygen-containing intermediates 51 . Thus, developing electronic conductive frameworks with strong polar sites holds promise for constructing highly active metal-free ORR catalysts [52][53][54][55][56][57] . ...
March 2023
... The NiS NPs' wrapping around porous carbon may be the cause of this. As a result, the carbon diffraction peaks are obscured by the strong characteristic peaks of NiS, suggesting a strong chemical bond between NiS NPs and AC (Zhu et al. 2021;Liu et al. 2023). In addition, the lack of any extra peaks resulting from impurities demonstrates the high purity of the NiS NPs-AC nanocomposite. ...
November 2022
Colloids and Surfaces A Physicochemical and Engineering Aspects
... The TRPS material provides high electronic conductivity, high thermal sensitivity (rapid response in less than 1 s at 70°C), and excellent electrochemical stability for LIBs. Jia et al. 186 developed a smart thermally responsive current collector by combining the shape memory polymer (EPON cross-linking network), which could be pulled up to restore the original shape and pierce the cover Cu layer with a circuit disconnection when the temperature exceeded its shape memory triggering temperature (Fig. 12d, 90°C, i.e., self-shutdown). ...
November 2022
Nano Letters
... As a result, the distance between friction layers can be left uncontrolled, resulting in better energy conversion. The most widely used polymer matrices for MXene-reinforced nanofibers are PLA [93][94][95], PVA [88,90], PVDF [89,96] and CA [97]. Zhang et al. reported the preparation of endogenous TENG by electrospinning PLA fiber films with the addition of MXene as filler. ...
September 2022
ACS Applied Nano Materials
... Among them, the compounds such as vanadium nitride (VN) [11], titanium dioxide (TiO 2 ) [12], cobalt phosphide (CoP) [13], etc., provided with promoted chemical affinity of LiPS and efficient utilization of the active material. Furthermore, increased interaction of LiPS with carbon and metal compounds led to improved conductivity, buffering volumetric changes of sulfur and enhanced kinetics of RedOx reactions in Li-S cells afterwards [15,16]. ...
May 2022
Colloids and Surfaces A Physicochemical and Engineering Aspects
... In contrast to conventional flat displays, foldable and flexible displays offer a range of form factors for implementing flexible electronics [1][2][3] . As the outermost layer of these displays, developing a foldable and flexible cover window is crucial to replace the conventional rigid cover glass 1,[3][4][5] . ...
March 2022
ACS Applied Materials & Interfaces