October 1999
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3 Reads
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3 Citations
Asian Journal of Chemistry
Electronic spectral parameters, viz., nephelauxetic ratio (beta), bonding parameter (b(1/2)) and Judd-Ofelt intensity parameter (Th) have been computed for some modified doped systems involving Pr(III) surrounded by sulphonanilide ligand. Oscillator strength of all the four bands (P-3(2), P-3(1), P-3(0) and D-1(2) levels) in each system has been reported and recalculated using Judd-Ofelt equation. The r.m.s. deviations have been found to be +/-1.82 x 10(-9) to +/-9.43 x 10(-9). A linear correlation between oscillator strength of hypersensitive band (P-3(2) level) and vT(6) has been observed.