Eve M. Poland's research while affiliated with University of Tasmania and other places

... , ipso-C of Ph), 134.1 (d, 2 J PC = 21.5 Hz,, 129.1 (s, p-Ph), 127.9 (d,3 J PC = 5.8 Hz, m-Ph), 124.2 (s, C 5 Me 5 ), 117.9 (d, 3 J PC = 4.2 Hz, C 5 H 4 ), 110.2 (s, C 5 H 4 ), 39.0 (d, 1 J PC = 20.7 Hz, CMe 2 ), 25.5 (d, 2 J PC = 18.0 Hz, CMe 2 ), 12.5 (s, C 5 Me 5 ); 31 P{ 1 H}: δ 32.ZrCl 2 ] (2-O). Complex 1 (100 mg, 0.17 mmol) was dissolved in toluene, the solution cooled to −20°C and t-BuOOH (37 μL, 0.20 mmol, 5.5 M in hexanes) was added. ...

Reference:

Luminescent Zirconocene Complexes with Pendant Phosphine Chalcogenide Donor Groups

... Recently, we have presented a series of two 1,4-pyidyl-MIC group 6 carbonyl complexes [M(L)(CO)4] (M = Cr, Mo, W) with two different constitutional isomers (L: C−C = pyridyl-4triazolylidene [41] and C−N = pyridyl-1-triazolylidene [42][43][44]) that exhibit excellent photophysical and photochemical properties, making them suitable candidates in photo-induced small molecule activation [43][44][45][46]. For the first time, details of the influence of the two constitutional isomers were reported in the chemically and electrochemically oxidized [Cr(L)CO)4] complexes, providing detailed insights into the extraordinary −donor properties [41]. ...

Reference:

Investigations on the Influence of Two Pyridyl-Mesoionic Carbene Constitutional Isomers on the Electrochemical and Spectroelectrochemical Properties of Group 6 Metal Carbonyl Complexes