E. Denkjr's research while affiliated with Tufts University and other places
What is this page?
This page lists the scientific contributions of an author, who either does not have a ResearchGate profile, or has not yet added these contributions to their profile.
It was automatically created by ResearchGate to create a record of this author's body of work. We create such pages to advance our goal of creating and maintaining the most comprehensive scientific repository possible. In doing so, we process publicly available (personal) data relating to the author as a member of the scientific community.
If you're a ResearchGate member, you can follow this page to keep up with this author's work.
If you are this author, and you don't want us to display this page anymore, please let us know.
It was automatically created by ResearchGate to create a record of this author's body of work. We create such pages to advance our goal of creating and maintaining the most comprehensive scientific repository possible. In doing so, we process publicly available (personal) data relating to the author as a member of the scientific community.
If you're a ResearchGate member, you can follow this page to keep up with this author's work.
If you are this author, and you don't want us to display this page anymore, please let us know.
Publication (1)
The nucleation behavior of seeded sodium chlorate solutions was studied experimentally. Because sodium chlorate crystallizes in two easily distinguished enantiomorphic forms, the origin of the secondary nuclei (whether the seed crystal or the solution) could be easily identified.This work shows that secondary nucleation does not involve a singular...
Citations
... 21 Then, primary nucleation can occur in this process only at conditions where the concentration of the undesired enantiomer is larger than that of the desired enantiomer (this is a constraint as we want to convert the former into the latter through the racemization reaction). 35 Therefore, primary nucleation of the desired enantiomer must be avoided, so as to avoid the nucleation of the undesired enantiomer; this can be avoided by keeping the supersaturation level below a (primary nucleation-) specific threshold. Finally, secondary nucleation occurs either by attrition, thus forming new crystals of the same handedness as the parent crystals or via other mechanisms 36−40 that could in principle create nuclei of both enantiomers. ...
