Carolyn A. Weigelt's research while affiliated with State University of New York at Plattsburgh and other places

What is this page?

This page lists the scientific contributions of an author, who either does not have a ResearchGate profile, or has not yet added these contributions to their profile.

It was automatically created by ResearchGate to create a record of this author's body of work. We create such pages to advance our goal of creating and maintaining the most comprehensive scientific repository possible. In doing so, we process publicly available (personal) data relating to the author as a member of the scientific community.

If you're a ResearchGate member, you can follow this page to keep up with this author's work.

If you are this author, and you don't want us to display this page anymore, please let us know.

Publications (1)

Syntheses of organometallic monomers containing cobalt and manganese
  • Article

June 1992

·

5 Reads

·

3 Citations

Macromolecular Symposia

Edward J. Miller

·

Micheal J. Naughton

·

Carolyn A. Weigelt

·

[...]

·

William J. O'Brien

Direct electrophilic substitution of the cyclopentadienyl ring of cymantrene has been used to prepare five cymantrenyl-monomers with unsaturated sidechains. Direct substitution of cymantrene with acryloyl- and methacryloyl chloride under Friedel-Crafts conditions has led to acryloyl- and methacryloylcymantrene. The complexes have been characterized using 1H and 13C NMR, IR and elemental analysis. Both complexes polymerize under treatment with AIBN at 60–70°C. The chelated complex [n5-C5H4(CH2CH=CH2)]-Co[(NH)2C6H4], was prepared from the treatment of [n5-C5H4(CH2CH=CH2)]Co(CO)2 with I2 followed by (NH)2C6H4 and base. The complex was characterized with 1H NMR and IR but failed to undergo free-radical polymerization. The strategies used to prepare organometallic polymers are discussed.

Share