C. D. Cook's research while affiliated with University of Toronto and other places
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Publications (8)
Die Kristallstruktur von Äthylen-bis-[triphenylphosphin]-platin wird mit Literaturdaten von Äthylen-bis-[triphenylphosphin]-nickel verglichen.
Ligand-exchange reactions in complexes of the type (P(C6H5)3)2Pt(ac), where ac is a phenylacetylene, have been reinvestigated, and the previously suggested mechanism has been modified.
The result of an X-ray crystallographic study of the complex (P(C6H5)3)2Pt(C2H 4) is presented together with refined values of bond lengths and angles for the nickel analog (P(C6H5)3)2Ni(C2H 4). The solution behavior of both complexes has been studied by nmr spectroscopy and marked differences in behavior have been observed. (P(C6H5)3)2Pt(C2H 4) is...
Die Komplexe (I), in denen Pt in einer formal niedrigen Oxidationsstufe ist, werden mit der ESCA-Technik untersucht.
Es werden NMR-Untersuchungen an den mit 13C markierten Komplexen (I) und (II) durchgeführt.
Citations
... (PPh,),-PtC2(CN), (2), (PPh,),PtC,Cl, (3), and (PPh,),-NiC2H4 (4). In order to make a critical appraisal of the D-C-D model and to learn the role played by the electron-withdrawing groups -CN and -C1 we have undertaken a threedimensional X-ray analysis of the ethylene complex (PPh,),PtC2H4, a brief report on which has already been published (5). ...
