A.Ye. Freiman's scientific contributions
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Publication (1)
The copolymerization of ethylene with vinyl acetate under 25 MPa pressure at 383°K has been studied in different solvents. The constants for chain transfer to the solvent were determined for the entire range being studied. It was shown that the solvent concentration in the reaction mixture has a substantial effect on the copolymerization rate and c...
Citations
... L'EVA est un copolymère statistique, obtenu par polymérisation radicalaire d'éthylène et d'acétate de vinyle, réalisé à haute pression [25] ( Figure A-7). Dans le cadre de l'application en câblerie, la polymérisation s'effectue en solution dans un solvant, conduisant à de plus fortes masses molaires que dans le cas de la polymérisation en masse [26]. ...