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The lunar basalt samples returned by the Chang’e-5 mission erupted about 2.0 billion years ago during the late period of the Moon’s secular cooling. The conditions of mantle melting in the source region and the migration of magma through the thick lithosphere that led to this relatively late lunar volcanism remain open questions. Here we combine quantitative textural analyses of Chang’e-5 basaltic clasts, diffusion chronometry, clinopyroxene geothermobarometers and crystallization simulations to establish a holistic picture of the dynamic magmatic–thermal evolution of these young lunar basalts. We find that the Chang’e-5 basalts originated from an olivine-bearing pyroxenite mantle source (10–13 kbar or 250 ± 50 km; 1,350 ± 50 °C), similar to Apollo 12 low-Ti basalts. We propose these magmas then ascended through the plumbing system and accumulated mainly at the top of the lithospheric mantle (~2–5 kbar or 40–100 km, 1,150 ± 50 °C), where they stalled at least several hundred days and evolved via high-degree fractional crystallization. Finally, the remaining evolved melts erupted rapidly onto the surface over several days. Our magmatic–thermal evolution model indicates abundant low-solidus pyroxenites in the mantle source with a slightly enhanced inventory of radioactive elements can explain the prolonged, but declining, lunar volcanism up to about 2 billion years ago and beyond.
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Nature Geoscience | Volume 16 | April 2023 | 301–308 301
nature geoscience
https://doi.org/10.1038/s41561-023-01146-x
Article
The magmatic architecture and evolution of
the Chang’e-5 lunar basalts
Biji Luo  1 , Zaicong Wang  1 , Jiale Song1, Yuqi Qian  1, Qi He1, Yiheng Li1,
James W. Head2, Frédéric Moynier  3, Long Xiao  1, Harry Becker4,
Bixuan Huang1, Bing Ruan1, Yangxuan Hu1, Fabing Pan1, Chang Xu1, Wenlong Liu1,
Keqing Zong1, Jiawei Zhao1, Wen Zhang1, Zhaochu Hu1, Zhenbing She  1,
Xiang Wu1 & Hongfei Zhang1
The lunar basalt samples returned by the Chang’e-5 mission erupted about
2.0 billion years ago during the late period of the Moon’s secular cooling.
The conditions of mantle melting in the source region and the migration
of magma through the thick lithosphere that led to this relatively late lunar
volcanism remain open questions. Here we combine quantitative textural
analyses of Chang’e-5 basaltic clasts, diusion chronometry, clinopyroxene
geothermobarometers and crystallization simulations to establish a
holistic picture of the dynamic magmatic–thermal evolution of these
young lunar basalts. We nd that the Chang’e-5 basalts originated from
an olivine-bearing pyroxenite mantle source (10–13 kbar or 250 ± 50 km;
1,350 ± 50 °C), similar to Apollo 12 low-Ti basalts. We propose these magmas
then ascended through the plumbing system and accumulated mainly at
the top of the lithospheric mantle (~2–5 kbar or 40–100 km, 1,150 ± 50 °C),
where they stalled at least several hundred days and evolved via high-degree
fractional crystallization. Finally, the remaining evolved melts erupted
rapidly onto the surface over several days. Our magmatic–thermal evolution
model indicates abundant low-solidus pyroxenites in the mantle source
with a slightly enhanced inventory of radioactive elements can explain the
prolonged, but declining, lunar volcanism up to about 2 billion years ago
and beyond.
Volcanism is the primary endogenic process of the terrestrial planets,
reflecting their internal thermal state and evolution1,2. Volcanic activity
on the Moon is the key record of its thermo-chemical evolution
3
. Lunar
mare basalts were erupted mainly in two major pulses of ~3.9–3.6 bil-
lion years ago (Ga) and ~3.4–3.1 Ga, significantly fewer were emplaced
between ~3.1 and 2.0 Ga as the lunar mantle cooled, and the process
finally ceased at ~1.2 Ga46. Available data suggested that the majority of
the lunar mare basalts were erupted in the Procellarum KREEP Terrane
(PKT), a region rich in potassium, rare-earth elements and phospho-
rus (KREEP)5,7. These observations have led to the hypothesis that the
elevated KREEP in mare basalt mantle sources was the heat source for
prolonging lunar volcanism
8,9
and, presumably, asymmetric thermal
evolution of the Moon10.
China’s Chang’e-5 (CE-5) mission landed in northern Oceanus
Procellarum within the PKT and sampled the youngest (~2.0 Ga) lunar
basalts radiometrically dated so far
11,12
. However, the mantle source
Received: 13 March 2022
Accepted: 16 February 2023
Published online: 20 March 2023
Check for updates
1State Key Laboratory of Geological Processes and Mineral Resources, School of Earth Sciences, China University of Geosciences, Wuhan, China.
2Department of Earth, Environmental and Planetary Sciences, Brown University, Providence, RI, USA. 3Institut de Physique du Globe de Paris, Université
Paris Cité, CNRS, UMR 7154, Paris, France. 4Institut für Geologische Wissenschaften, Freie Universität Berlin, Berlin, Germany. e-mail: luobj@cug.edu.cn;
zaicongwang@cug.edu.cn
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... Geochemical analyses of CE-5 mare basaltic clasts have been performed to elucidate the origin and evolution of these young basalts (e.g., Che et al., 2021;He et al., 2022;Hu et al., 2021;Ji et al., 2022;Jiang et al., 2022;Li et al., 2021Li et al., , 2022Luo et al., 2023;Tian et al., 2021;Zhang et al., 2022;Zong et al., 2022). The bulk rock compositions of the CE-5 basaltic clasts had variable TiO 2 contents ranging from 3 to >12 wt% (Tian et al., 2021), from $6 to 8 wt% (Che et al., 2021), and from 2.10 to 5.52 wt% . ...
... Therefore, the whole-clast compositions may not represent the bulk rock composition of basalts (e.g., Karner et al., 2004;Snape et al., 2014;Zolensky et al., 2000). Furthermore, partial melting and fractional crystallization that occurred during formation of parental melt of CE-5 basalts from a mantle source (Luo et al., 2023;Su et al., 2022;Tian et al., 2021;Zong et al., 2022) could make deciphering the mantle source region of CE-5 basalts difficult. ...
... The concentrations of FeO, MgO, and TiO 2 in the melt at the onset of plagioclase crystallization are $15, $6, and $3 wt%, respectively, indicating a low-Ti and low-Mg# parental melt of CE-5 basalts. The low-degree partial melting of the mantle source and extensive fractional crystallization of the magma (Luo et al., 2023;Su et al., 2022;Tian et al., 2021;Zong et al., 2022) resulted in REE enrichments in the CE-5 basalts. Crystallization of plagioclase and olivine in the CE-5 magma enriched the concentrations of TiO 2 and FeO in the melt, which resulted in a wide range of TiO 2 contents in CE-5 bulk clasts and in the extensive crystallization of ilmenite. ...
Article
The regolith samples returned by the Chang'E‐5 mission (CE‐5) contain the youngest radiometrically dated mare basaltic clasts, which provide an opportunity to elucidate the magmatic activities on the Moon during the late Eratosthenian. In this study, detailed petrographic observations and comprehensive geochemical analyses were performed on the CE‐5 basaltic clasts. The major element concentrations in individual plagioclase grain of the CE‐5 basalts may vary slightly from core to rim, whereas pyroxene has clear chemical zonation. The crystallization sequence of the CE‐5 mare basalts was determined using petrographic and geochemical relations in the basaltic clasts. In addition, both fractional crystallization (FC) and assimilation and fractional crystallization models were applied to simulate the chemical evolution of melt equilibrated with plagioclase in CE‐5 basalts. Our results reveal that the melt had a TiO 2 content of ~3 wt% and an Mg# of ~45 at the onset of plagioclase crystallization, suggesting a low‐Ti parental melt of the CE‐5 basalts. The relatively high FeO content (>14.5 wt%) in melt equilibrated with plagioclase could have resulted in extensive crystallization of ilmenite, unlike in Apollo low‐Ti basalts. Furthermore, our calculations showed that the geochemical evolution of CE‐5 basaltic melt could not have occurred in a closed system. On the contrary, the CE‐5 basalts could have assimilated mineral, rock, and glass fragments that have higher concentrations of KREEP elements (potassium, rare earth elements, and phosphorus) in the regolith during magma flow on the Moon's surface. The presence of the KREEP signature in the CE‐5 basalts is consistent with literature remote sensing data obtained from the CE‐5 landing site. These KREEP‐bearing fragments could originate from KREEP basaltic melts that may have been emplaced at the landing site earlier than the CE‐5 basalts.
... Luo et al. 1 present exciting new data on lunar basalt samples erupted at ~2 Ga, and brought to Earth by the Chang'e-5 (CE-5) mission. These samples offer important new opportunities to understand lunar magmatic systems. ...
... These samples offer important new opportunities to understand lunar magmatic systems. Luo et al. 1 use Clinopyroxene-Liquid (Cpx-Liq) thermobarometry and pMELTS modelling of mineral compositions to determine the pressures (P) and temperatures (T) of magma storage on the moon. Specifically, they iterate the barometer of Neave and Putirka 2 and the thermometer of Putirka (eq33) 3 , yielding pressures spanning ~1-12.9 ...
... Recent advances in understanding the sources and magnitudes of error associated with Cpx barometry reveal that the majority of studies utilizing Cpx barometry in the literature neglect to (1) propagate analytical uncertainty into P and T estimates 4 , and (2) ensure that the composition space of the studied magmas is similar to that of the barometer's calibration dataset 5 . Luo et al. 1 allude to point 1 with their sentence 'For this purpose, high-quality concentration data on clinopyroxenes in equilibrium with the host basaltic melts are required'. ...
Preprint
Luo et al.1 present exciting new data on lunar basalt samples erupted at ~2 Ga, and brought to Earth by the Chang’e-5 (CE-5) mission. These samples offer important new opportunities to understand lunar magmatic systems. Luo et al.1 use Clinopyroxene-Liquid (Cpx-Liq) thermobarometry and pMELTS modelling of mineral compositions to determine the pressures (P) and temperatures (T) of magma storage on the moon. However, in this comment we discus the large analytical errors associated with their measurements, and the implications for their intepretation.
... (b) Fields represent Fe# (Fe/(Fe + Mg) molar ratio) versus Ti# (Ti/(Ti + Cr) molar ratio) of clinopyroxene in very low-Ti, low-Ti, and high-Ti mare basalts Robinson et al., 2012). The CE-5 data compiled Luo et al., 2023;Su et al., 2022) show high Ti# at given Fe#. The highly evolved, low-Ti meteorites NWA 4734 and pairs are shown for comparison (Elardo et al., 2014). ...
... Pyroxene data, Fe-Mg isotopes, phase diagram and crystallization modelling increasingly support the clinopyroxene-rich cumulate source for CE-5 basalts, although the specific proportion is variable in different studies Luo et al., 2023;Su et al., 2022;Zong et al., 2022). Following previous work , we modelled this possibility and suggest that 0.5-1.5 modal % KREEP materials would be present in a clinopyroxene-rich (> 30 to 60 molal %) cumulate source of CE-5 basalts (the specific compositions rely on model variables, Fig. 11, see details in Supplementary Materials). ...
... These new basalts will expand our understanding of the Moon's evolution, particularly the late lunar volcanism. Previous studies of CE5 lunar basalts and soil grains have made important advances in the mineralogy, petrology, and geochemistry (e.g., Cao et al., 2022;Chang et al., 2023a;Che et al., 2021;Chen et al., 2023b;Fu et al., 2022;He et al., 2022;Jiang et al., 2023;Li et al., 2021;Luo et al., 2023;Su et al., 2022;Tian et al., 2021Tian et al., , 2023aTian et al., , 2023bYang et al., 2022Yang et al., , 2023Zhang et al., 2022). These findings collectively suggest that the CE5 lunar basalts represent a new rock type, as indicated by their higher FeO content, lower Mg# [defined as 100*molar Mg/(Mg + Fe)], and enrichment of incompatible elements (e.g., U, Th, La) compared to the Apollo and Luna samples. ...
... These results support that the two eras of mare volcanism were derived from different lunar mantle sources. The CE5 mantle source is expected to have more late-stage LMO clinopyroxene-ilmenite cumulates [23,69,85], which might stay in the upper mantle after the mantle overturn [71,86] or sink to the core-mantle boundary followed by the upward movement due to magma upwelling [87,88]. The late-stage LMO cumulates are more easily melted than the early olivine-dominated cumulates [23]. ...
Article
Full-text available
Mare basalts returned by the Chang’E-5 (CE5) mission extend the duration of lunar volcanism almost one billion years longer than previously dated. Recent studies demonstrated that the young volcanism was related neither to radiogenic heating nor to hydrous melting. These findings beg the question of how the young lunar volcanism happened. Here we perform high-precision minor element analyses of olivine in the CE5 basalts, focusing on Ni and Co. Our results reveal that the CE5 basalt olivines have overall lower Ni and Co than those in the Apollo low-Ti basalts. The distinctive olivine chemistry with recently reported bulk-rock chemistry carries evidence for more late-stage clinopyroxene-ilmenite cumulates of the lunar magma ocean (LMO) in the CE5 mantle source. The involvement of these Fe-rich cumulates could lower the mantle melting temperature and produce low MgO magma, inhibiting Ni and Co partitioning into the magma during lunar mantle melting and forming low Ni and Co olivines for the CE5 basalts. Moreover, the CE5 olivines show a continuous decrease of Ni and Co with crystallization proceeding. Fractional crystallization modeling indicates that Co decreasing with crystallization resulted from CaO and TiO2 enrichment (with MgO and SiO2 depletion) in the CE5 primary magma. This further supports the significant contribution of late-stage LMO cumulates to the CE5 volcanic formation. We suggest that adding easily melted LMO components resulting in mantle melting point depression is a key pathway for driving prolonged lunar volcanism. This study highlights the usefulness of olivine for investigating magmatic processes on the Moon.
... 20 These different estimations mainly come from the proposed mineral modes of the mantle source. Tian et al. (2021) 31 and Yang W. et al. (2022) 36 followed the model of Snyder et al. (1992),82 which is widely used to estimate the contribution of KREEP materials in the Apollo samples and lunar meteorites.83 Zong et al. (2022) 20 proposed a new model, adding 40-60% REE-depleted clinopyroxene into the mantle source to make it possible to contain more REE-enriched KREEP-rich materials. ...
Article
Full-text available
The Chang'e-5 (CE-5) mission, the first return of lunar samples to Earth since the Apollo and Luna missions more than 44 years ago, landed on one of the youngest mare basalt units (1.0-3.0 Ga, based on superposed crater counts), located at middle latitude (~43°N) far from previous landing sites. On December 17, 2020, the sample capsule returned to Earth with 1731 grams of lunar soil collected from the upper few centimeters of the surface and from an ~1 meter-long core drilled into the lunar regolith. This paper summarizes the main discoveries of the CE-5 samples allocated since July 12, 2021, and measured with state-of-the-art analytical techniques. Physical property studies indicate that the CE-5 soil is mature, with a peak particle size of ~50 μm (in volume), and a particle size distribution similar to the sub-mature and mature Apollo lunar soils (<1 cm). The soil sample contains basalt and mineral fragments, impact melt breccia, agglutinates, and glasses. The basalt fragments can be divided into several petrographic types, likely crystallized from the same lava flow at different depths and cooling rates. The CE-5 basalt Pb/Pb SIMS analyses yielded a crystallization age of 2.030 ± 0.004 Ga, extending the duration of lunar volcanic activity by ~1.0~0.8 Ga. This age, in turn, has helped to calibrate the widely applied lunar crater chronology model. The isotopic ratios of Pb, Nd and Sr indicate that the contribution of a KREEP component in forming CE-5 basalt is limited (<0.5%), excluding high concentrations of heat-producing radioactive elements in their mantle source. The isotope analyses of H, Cl, and S reveal that the mantle source is dry, which cannot account for the prolonged volcanism observed in the CE-5 landing region. A possible explanation is that the CE-5 mantle source contains enhanced clinopyroxene-ilmenite cumulate (~20%), which reduces the melting temperature by ~80°C. The REE-, FeO-enrichment of the CE-5 basalt can be attributed to a low degree of partial melting followed by extensive fractional crystallization. The CE-5 soil has also recorded a two-billion-year history of meteorite impact and solar wind irradiation. A few exotic fragments have been recognized (some with high-pressure silica phases) and are likely ejected from distant lunar highlands. The U-Pb dating of impact glass beads reveals at least 17 main impact events. New space weathering effects, especially the formation of Fe3+, have been found. In situ reflectance spectra and laboratory analyses of CE-5 soil show the presence of water (in the form of H, OH, and/or H2O). The solar wind hydrogen was implanted and concentrated in the outermost rims (<100 nm) of soil grains, with a temperature (hence latitude)-dependent maximum water concentration of up to ~2 wt%.
Article
Full-text available
The Chang’E-5 (CE5) mission has demonstrated that lunar volcanism was still active until two billion years ago, much younger than the previous isotopically dated lunar basalts. How the small Moon retained enough heat to drive such late volcanism is unknown, particularly as the CE5 mantle source was anhydrous and depleted in heat-producing elements. We conduct fractional crystallization and mantle melting simulations that show that mantle melting point depression by the presence of fusible, easily melted components could trigger young volcanism. Enriched in calcium oxide and titanium dioxide compared to older Apollo magmas, the young CE5 magma was, thus, sourced from the overturn of the late-stage fusible cumulates of the lunar magma ocean. Mantle melting point depression is the first mechanism to account for young volcanism on the Moon that is consistent with the newly returned CE5 basalts.
Article
Full-text available
Lunar impact glasses can provide important information on the bulk compositions of their sources and the impact history of the Moon. Here, we report the chemical composition of fifty-four clean glass spherules containing neither relict clasts nor crystals from the Chang’e-5 (CE5) regolith. They can be subdivided into three compositional groups: (1) mid-Ti basaltic (TiO2 = 4.1∼6.5 wt.%), (2) low-Ti basaltic (TiO2 = 1.3∼3.9 wt.%), and (3) high-Al (Al2O3 >15 wt.%). Fifty-one glasses (∼94%) are mid-Ti basaltic, which form a loose compositional cluster for most major and trace elements. These glasses exhibit considerable variations in SiO2 (35.3∼45.3 wt.%). Their TiO2, Al2O3, MgO and CaO show negative correlations with SiO2, while the Na2O, K2O and P2O5 positively correlate with SiO2, also yielding a positive correlation between the CIPW normative plagioclase and olivine. These variations likely result from differential vaporization of SiO2, strongly suggesting an impact origin of these glasses. Their major and trace element compositions are averagely similar to the bulk-rock, in turn indicating that they were formed from the local regolith. The remaining three glasses, including two low-Ti basaltic and one high-Al variety, exhibit distinct major and trace elements from the regolith, indicating an exotic source. In addition, the mid-Ti basaltic glasses provide another approach for estimating the average composition of the CE5 basalt other than directly measuring the small basalt fragments assuming that the exotic materials in the CE5 regolith were limited. This estimation reveals critical trace element characteristics of the CE5 basalt, e.g., it has higher La/Yb (3.71), Sm/Yb (1.76), Sr/Yb (31.6), and (Eu/Eu*)N (0.45) than KREEP, indicating that CE5 basalt must derive from a non-KREEP source. Chemical modeling indicates that the contribution of KREEP-rich materials in the mantle source should be less than 0.3%. The trace element characteristics of the CE5 basalt can be reproduced by extensive (80%) fractional crystallization after low-degree (2%) melting. We propose that this fractional crystallization process might occur at depth, implying vast igneous underplating (7250∼11750 km³) beneath the CE5 landing area. This study also suggests that the high Th concentration (5.43 ppm) is an inherent property of the CE5 basalt resulting from extensive fractional crystallization. Thus, high Th detected by remote sensing may not be associated directly with a KREEP component but rather with highly fractionated basalts.
Article
Full-text available
Lunar soil is a fine mixture of local rocks and exotic components. The bulk-rock chemical composition of the newly returned Chang’E-5 (CE-5) lunar soil was studied to understand its chemical homogeneity, exotic additions, and origin of landing site basalts. Concentrations of 48 major and trace elements, including many low-concentration volatile and siderophile elements, of two batches of the scooped CE-5 soil samples were simultaneously obtained by inductively coupled plasma mass spectrometry (ICP-MS) with minimal sample consumption. Their major and trace elemental compositions (except for Ni) are uniform at milligram levels (2–4 mg), matching measured compositions of basaltic glasses and estimates based on mineral modal abundances of basaltic fragments. This result indicates that the exotic highland and KREEP (K, rare earth elements, and P-rich) materials are very low (<5%) and the bulk chemical composition (except for Ni) of the CE-5 soil can be used to represent the underlying mare basalt. The elevated Ni concentrations reflect the addition of about 1 wt% meteoritic materials, which would not influence the other bulk composition except for some highly siderophile trace elements such as Ir. The CE-5 soil, which is overall the same as the underlying basalt in composition, displays low Mg# (34), high FeO (22.7 wt%), intermediate TiO2 (5.12 wt%), and high Th (5.14 µg/g) concentrations. The composition is distinct from basalts and soils returned by the Apollo and Luna missions, however, the depletion of volatile or siderophile elements such as K, Rb, Mo, and W in their mantle sources is comparable. The incompatible lithophile trace element concentrations (e.g., Ba, Rb, Th, U, Nb, Ta, Zr, Hf, and REE) of the CE-5 basalts are moderately high and their pattern mimics high-K KREEP. The pattern of these trace elements with K, Th, U, Nb, and Ta anomalies of the CE-5 basalts cannot be explained by the partial melting and crystallization of olivine, pyroxene, and plagioclase. Thus, the mantle source of the CE-5 landing site mare basalt could have contained KREEP components, likely as trapped interstitial melts. To reconcile these observations with the initial unradiogenic Sr and radiogenic Nd isotopic compositions of the CE-5 basalts, clinopyroxene characterized by low Rb/Sr and high Sm/Nd ratios could be one of the main minerals in the KREEP-bearing mantle source. Consequently, we propose that the CE-5 landing site mare basalts very likely originated from partial melting of a shallow and clinopyroxene-rich (relative to olivine and orthopyroxene) upper mantle cumulate with a small fraction (about 1–1.5 %) of KREEP-like materials.
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Forty-five years after the Apollo and Luna missions returned lunar samples, China's Chang'E-5 (CE-5) mission collected new samples from the mid-latitude region in the northeastern Oceanus Procellarum of the Moon. Our study shows that 95% of CE-5 lunar soil sizes are found to be within the range of 1.40-9.35 μm, while 95% of the soils by mass are within the size range of 4.84-432.27 μm. The bulk density, true density and specific surface area of CE-5 soils are 1.2387 g/cm3, 3.1952 g/cm3 and 0.56 m2/g, respectively. Fragments from the CE-5 regolith are classified into igneous clasts (mostly basalt), agglutinate and glass. A few breccias were also found. The minerals and compositions of CE-5 soils are consistent with mare basalts and can be classified as low-Ti/low-Al/low-K type with lower rare-earth-element contents than materials rich in potassium, rare earth element and phosphorus. CE-5 soils have high FeO and low Mg index, which could represent a new class of basalt.
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The Moon has a magmatic and thermal history distinct from those of the terrestrial planets1. Radioisotope dating of lunar samples suggests that most lunar basaltic magmatism ceased by ca. 2.9–2.8 Ga (billion years ago)2,3, although younger basalts between 3 and 1 Ga have been suggested by crater-counting chronology, which has large uncertainties owing to the lack of returned samples for calibration4,5. Here, we report a precise Pb-Pb age of 2,030 ± 4 Ma (million years ago) for basalt clasts returned by the Chang’E-5 mission, and a 238U/204Pb ratio (µ value)6 of ~680 for a source that evolved through two stages of differentiation. This is the youngest crystallisation age ever reported for lunar basalts by radiometric method, extending the duration of lunar volcanism by ~800–900 million years. The µ value of the Chang’E-5 basalt mantle source is within the range of low-Ti and high-Ti basalts from Apollo sites (µ = ~300–1,000), but strikingly lower than those of KREEP (K, rare earth elements, and P) and high-Al basalts7 (µ = ~2,600–3,700), indicating that the Chang’E-5 basalts were produced by melting of a KREEP-poor source. The new age provides a pivotal calibration point for crater-counting chronology in the inner Solar System and sheds new light on the volcanic and thermal history of the Moon.
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Lunar mare basalts provide a probe to study the magmatic and thermal evolution of the Moon. The Chang'e-5 (CE-5) mission returned samples from a young and hitherto unsampled mare terrain, providing fresh opportunities to understand lunar volcanic history. A detailed petrologic survey was conducted in this study on basalt fragments and glasses from the returned CE-5 soil samples. Relatively large-sized (100–400 μm) basaltic fragments were hand-picked and examined for texture, mineral assemblage and mineral chemistries. Basaltic fragments exhibit dominantly subophitic textures and are phenocryst-free, with low to intermediate-Ti (2.1–5.5 wt%) and low Mg# (Mg/(Mg + Fe) × 100, 19–47, with an average whole-rock Mg# of 33) consistent with olivine-melt equilibrium calculation (Mg# = 34). A range of highly evolved basaltic materials have been identified, in which abundant fayalitic olivine, symplectitic intergrowths, and Si + K-rich mesostasis co-exist were found resulting from late-stage silicate liquid immiscibility. Basaltic glass compositions largely overlap with basaltic fragment compositions suggesting they are locally derived. The CE-5 basalts have a relatively limited range of eruption temperatures of 1150–1230 °C. Based on their petrographic and geochemical characteristics, some CE-5 mare basalts are highly evolved and some of the resultant basaltic melt products underwent high crystallization. Thermodynamic modeling using MELTS suggests highly evolved basaltic magma was produced by a low-pressure and simple fractional crystallization under reduced conditions. This may have occurred at the surface in the inflated Em4/P58 flow with a thickness of ~50 m. The low degree of partial melting mantle source of the parental melts is the late-stage lunar magma ocean cumulates in a similar manner to some evolved low-Ti mare basalt meteorites, although the source of CE-5 basalts may have been slightly more Ti-rich.
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China's Chang'E-5 mission returned new samples from the Moon and has extended the eruption ages of lunar volcanism ca. 800 million years younger than previous determinations. This finding challenges our past perceptions of the lunar thermal and magmatic evolution and has attracted great attention. Since the lunar basalts show a wide compositional range, it is essential to classify them carefully in order to define their origin and evolution. However, whether the Chang'E-5 basalts are classified as high-Ti or low-Ti type remains debatable because the basalt clasts picked from the Chang'E-5 soil samples are so tiny that their bulk composition estimations involve large uncertainties. Instead of using bulk composition, this study employs Ti in olivine to track the crystallization sequence of the Chang'E-5 basalts and then to classify them. In the Chang'E-5 olivines, Ti contents first increase and then decrease with a continuous decrease of forsterite values. Such a compositional variation reveals a magma differentiation series from early ilmenite unsaturation to ilmenite saturation during the late stage. Furthermore, the TiO2 content of the hypothesized parental magma that corresponds to the most primitive olivine is estimated to be ~4.4 wt%. These results confirm that the Chang'E-5 basalts originated from a low-Ti primary magma. This study shows that olivine can be used as a robust mineral indicator to distinguish between high-Ti and low-Ti mare basalts.
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