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Ordovician tephrochronology, geochronology, and global tephra distribution
Abstract
The study of Ordovician tephras yields a wealth of valuable information about regional tectonism, sedimentation, stratigraphic correlation, and process rates. As such, these layers are prized by geologists and are the subject of a rich literature. Ordovician tephra studies were pioneering, particularly in development of chemical fingerprinting, to improve precision in tephrochronology. Modern radioisotope geochronology utilizes zircons and other phenocrysts from these layers to generate eruption ages with uncertainty on the order of a hundred thousand years. When integrated with biostratigraphy, chemostratigraphy and astrochronology, tephra ages provide unparalleled opportunity to constrain process rates. Fifty such Ordovician tephra ages have been published over the last decade from CA-IDTIMS U-Pb analysis of individual zircon phenocrysts, providing geochronological coverage across all stages of the Ordovician. Laurentia dominates this coverage (24) followed by the Baltic Basin (12), North Gondwana (11), Cuyania (4) and the Siberian Tungus Basin (1). Future tephra studies should seek to fill the numerous remaining gaps in the Ordovician time scale.
... The Ordovician was characterized by an initially warm but steadily cooling climate (Trotter et al., 2008;Finnegan et al., 2011;Jin et al., 2018;Goldberg et al., 2021), high global sea level with approximately 86% of the Earth's surface underwater, rapidly moving plates (Miller et al., 2005;Scotese, 2023), elevated volcanic activity and possible superplumes (Lefebvre et al., 2010;McLaughlin et al., 2023), and a typical calcite sea despite the occurrence of exceptional aragonitic 1 Ó 2024 International Association of Sedimentologists. ...
Middle Ordovician iron ooids in the Upper Yangtze region of South China are composed mainly of hematite and/or chamosite, found in mixed siliciclastic and carbonate successions, with hematitic ooids occurring in the west, and predominantly chamositic ooids in the east of the study area. In the three iron ooid‐bearing Middle–Upper Ordovician successions, 19 microfacies are recognized and grouped into eight facies associations, representing a shallow‐water mosaic comprising restricted and semi‐restricted lagoons, and open marine subtidal deposits interfingering with tidal flat and shoal facies. Hematitic ooids with well‐sorted and well‐rounded quartz grains formed in the transgressive shoal setting when the depositional environments changed from restricted lagoon to bioclast–quartz shoal and open marine subtidal. Episodic stasis and erosional intervals during transgression controlled the formation of hematite‐rich and mixed hematite–chamosite laminae within the cortices of hematitic ooids. In contrast, chamositic ooids formed in a semi‐restricted lagoonal environment, under long‐term transgressive condensation. Alternating episodes of relatively oxic conditions with thriving organisms and eutrophication‐driven anoxia resulted in the alternation of porous and dense laminae consisting mainly of chamosite in chamositic ooids. The stromatolite‐like cauliflower structures associated with chamositic ooids suggest microbial activity that promoted iron concentration, similar to the origin of approximately coeval iron‐rich oncoids in South China. Various iron ooid types demonstrate that these coated grains could form in a range of depositional setting and palaeooceanographic conditions on a generally shallow‐marine platform during the Ordovician.
... 135 Some carbonate beds in the 'orthoceratite limestone' contain abundant zircon, and the crystal characteristics and U-Pb age data of the grains indicate a volcanic origin Liao et al. 2020). Thus, the zircon-rich beds arguably represent 'crypto-tephra ' (McLaughlin et al., 2023). ...
The 'Likhall' zircon bed is a rare case of a single-age zircon population from a carbonate rock, which in this case is contextualised with remarkable biotic and environmental changes as well as meteorite bombardment of Earth after an asteroid breakup in space. Published chemical-abrasion, high-precision isotope-dilution, thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb age estimates disagree at the typical precision of <0.1% for a 206 Pb/ 238 U date, which has led to discrepancies in the interpretation of the timing of events and their possible cause-effect relationships. We evaluate here the relative strengths and weaknesses, and discrepancies in the so far published datasets, propose strategies to overcome them and present a new U-Pb dataset with improved precision and accuracy. Ultimately, we find that domains of residual Pb-loss are a significant source of age-offset between previously published data, amplified by differences in data evaluation strategies. Our new dataset benefits from an improved chemical abrasion protocol resulting in a more complete mitigation of decay-damage induced grain portions, and points to a weighted mean age estimate of 466.37±0.14/0.18/0.53 Ma for the 'Likhall' zircon population. This age is intermediate between previous estimates, but outside of analytical uncertainty, and provides a firm tie point for the Ordovician timescale.
The Ordovician was a key period in the history of the Earth. “A Global Synthesis of the Ordovician System” is presented in two volumes of the Geological Society Special Publications series. The first volume (SP 532) covers general aspects of the Ordovician and includes the syntheses of the Ordovician successions of Europe. To provide a comprehensive global overview, this second volume (SP 533) represents a journey through the Ordovician System around the World. Reviews of the Ordovician of North America include syntheses of Alaska, Greenland, Canada, the USA and Mexico, whereas the South American Ordovician is summarized in a specific chapter related to Argentina and neighbouring countries. The Ordovician System of Africa is presented in chapters covering the North and the South of the continent where significant Ordovician successions occur. Australia and New Zealand, as well as Antarctica, are visited in separate chapters. Asia provides the most complex Ordovician successions reviewed in chapters covering Turkey and the Levant region, the Middle East, Central Asia, Kazakhstan, India, South-East Asia, China, Korea, and Japan. Our journey covers a great number of locations, but with many successions still to be fully described, the knowledge of the Ordovician of the World remains incomplete.
The Ordovician was a key period in the biological and geological history of the planet. ‘A Global Synthesis of the Ordovician System’ is presented in two volumes of The Geological Society, Special Publications . This first volume (SP532) charts the history of the Ordovician System and explores significant advances in our understanding of the period's biostratigraphy, including more precise calibration of its timescale with tephra chronology and regional alignments using astrochronology and cyclostratigraphy. Changes in the world's oceans, their shifting currents and sea levels, the biogeography of their biotas and the ambient climate are described and discussed against a background of changing palaeogeography. This first volume also includes syntheses of Ordovician geology of most European countries, including historical key areas, such as the British Isles, Baltoscandia and Bohemia.
Cyclostratigraphy is an important tool for understanding astronomical climate forcing and reconstructing geological time in sedimentary sequences, provided that an imprint of insolation variations caused by Earth's orbital eccentricity, obliquity and precession is preserved (Milankovitch forcing). Understanding astronomical climate forcing has proven fundamental for the study of Cenozoic climate systems and the construction of high-resolution continuous time scales (astrochronologies). Pre-Cenozoic astrochronologies face several challenges:(1) uncertainties in the deep-time astronomical solutions and parameters; (2) less-complete and less-well-preserved strata; and (3) the sparsity of geochronologic anchor points. Consequently, Palaeozoic astrochronologies are typically based on identification of the stable 405-kyr eccentricity cycle instead of shorter astronomical cycles. Here, a state-of-the-art review of Ordovician cyclostratigraphy and astrochronology is presented, as well as suggestions on their robust application in an Ordovician context. Ordovician astronomically driven climate dynamics are suggested to have influenced processes like glacial dynamics, sea-level variations and changes in biodiversity. Ordovician cyclostratigraphic studies can help to construct high-resolution numerical time scales, ideally in combination with high-quality radio-isotopic dating. As such, cyclostratigraphy is becoming an increasingly important part of an integrated stratigraphic approach to help disentangle Ordovician stratigraphy and palaeoenviromental changes.
Cyclostratigraphy is an important tool for understanding astronomical climate forcing and reconstructing geological time in sedimentary sequences, provided that an imprint of insolation variations caused by Earth's orbital eccentricity, obliquity and precession is preserved (Milankovitch forcing). Understanding astronomical climate forcing has proven fundamental for the study of Cenozoic climate systems and the construction of high-resolution continuous time scales (astrochronologies). Pre-Cenozoic astrochronologies face several challenges:(1) uncertainties in the deep-time astronomical solutions and parameters; (2) less-complete and less-well-preserved strata; and (3) the sparsity of geochronologic anchor points. Consequently, Palaeozoic astrochronologies are typically based on identification of the stable 405-kyr eccentricity cycle instead of shorter astronomical cycles. Here, a state-of-the-art review of Ordovician cyclostratigraphy and astrochronology is presented, as well as suggestions on their robust application in an Ordovician context. Ordovician astronomically driven climate dynamics are suggested to have influenced processes like glacial dynamics, sea-level variations and changes in biodiversity. Ordovician cyclostratigraphic studies can help to construct high-resolution numerical time scales, ideally in combination with high-quality radio-isotopic dating. As such, cyclostratigraphy is becoming an increasingly important part of an integrated stratigraphic approach to help disentangle Ordovician stratigraphy and palaeoenviromental changes.
The Ordovician saw major diversification in marine life abruptly terminated by the Late Ordovician mass extinction (LOME). Around 85% of species were eliminated in two pulses 1 m.y. apart. The first pulse, in the basal Hirnantian, has been linked to cooling and Gondwanan glaciation. The second pulse, later in the Hirnantian, is attributed to warming and anoxia. Previously reported mercury (Hg) spikes in Nevada (USA), South China, and Poland implicate an unknown large igneous province (LIP) in the crisis, but the timing of Hg loading has led to different interpretations of the LIP-extinction scenario in which volcanism causes cooling, warming, or both. We report close correspondence between Hg, Mo, and U anomalies, declines in enrichment factors of productivity proxies, and the two LOME pulses at the Ordovician-Silurian boundary stratotype (Dob’s Linn, Scotland). These support an extinction scenario in which volcanogenic greenhouse gases caused warming around the Katian-Hirnantian boundary that led to expansion of a preexisting deepwater oxygen minimum zone, productivity collapse, and the first LOME pulse. Renewed volcanism in the Hirnantian stimulated further warming and anoxia and the second LOME pulse. Rather than being the odd-one-out of the “Big Five” extinctions with origins in cooling, the LOME is similar to the others in being caused by volcanism, warming, and anoxia.
We applied tandem U-Pb dating of detrital zircon (DZ) to redefine the Tonto Group in the Grand Canyon region (Arizona, USA) and to modify the Cambrian time scale. Maximum depositional ages (MDAs) based upon youngest isotope-dilution DZ ages for the Tapeats Sandstone are ≤508.19 ± 0.39 Ma in eastern Grand Canyon, ≤507.68 ± 0.36 Ma in Nevada, and ≤506.64 ± 0.32 Ma in central Arizona. The Sixtymile Formation, locally conformable below the Tapeats Sandstone, has a similar MDA (≤508.6 ± 0.8 Ma) and is here added to the Tonto Group. We combined these precise MDAs with biostratigraphy of trilobite biozones in the Tonto Group. The Tapeats Sandstone is ca. 508–507 Ma; the Bright Angel Formation contains Olenellus, Glossopleura, and Ehmaniella biozones and is ca. 507–502 Ma; and the Muav Formation contains Bolaspidella and Cedaria biozones and is ca. 502–499 Ma. The Frenchman Mountain Dolostone is conformable above the Muav Formation and part of the same transgression; it replaces McKee’s Undifferentiated Dolomite as part of the Tonto Group; it contains the Crepicephalus Biozone and is 498–497 Ma. The Tonto Group thickens east to west, from 250 m to 830 m, due to ∼300 m of westward thickening of carbonates plus ∼300 m of eastward beveling beneath the sub-Devonian disconformity. The trilobite genus Olenellus occurs in western but not eastern Grand Canyon; it has its last appearance datum (LAD) in the Bright Angel Formation ∼45 m above the ≤507.68 Ma horizon. This extinction event is estimated to be ca. 506.5 Ma and is two biozones below the Series 2–Miaolingian Epoch boundary, which we estimate to be ca. 506 Ma. Continued tandem dating of detrital grains in stratigraphic context, combined with trilobite biostratigraphy, offers rich potential to recalibrate the tempo and dynamics of Cambrian Earth systems.
The end Ordovician mass extinction (EOME) was the second most severe biotic crisis in Phanerozoic, and has been widely linked to a major glaciation. However, robust geochronology of this interval is still lacking. Here we present four successive high-precision zircon U–Pb dates by isotope dilution thermal ionization mass spectrometry (ID-TIMS) for biostratigraphically well-constrained K-bentonites of a continuous Ordovician-Silurian boundary section at Wanhe, SW China. They include 444.65 ± 0.22 Ma (middle Dicellograptus complexus Biozone), 444.06 ± 0.20 Ma (lower Paraorthograptus pacificus Biozone), 443.81 ± 0.24 Ma (upper Tangyagraptus typicus Subzone), and 442.99 ± 0.17 Ma (upper Metabolograptus extraordinarius Biozone). Calculations based on sedimentation rates suggest a duration of 0.47 ± 0.34 Ma for the Hirnantian Stage, which is much shorter than previously thought (1.4 ± 2.05 Ma in the International Chronostratigraphic Chart ver. 2019/05). The new data also constrain the Hirnantian glacial maximum to ∼0.2 Ma, supporting that its brevity and intensity probably triggered the EOME. Keywords: ID-TIMS, K-bentonite, End Ordovician mass extinction (EOME), Hirnantian stage
The present sub-permil precision of single zircon chemical abrasion, isotope-dilution, thermal ionisation mass spectrometry (CA-ID-TIMS) UePb dates often reveals age dispersions that are outside of analytical uncertainty. Interpreting these complex age distributions requires the ability to distinguish between protracted crystallization of zircon over a few 100 kyr, age bias due to radiation damage induced Pb-loss, and analytical artefacts. This is a particularly critical issue when a number of these factors occur together. To ensure geologically meaningful
results, the complete eradication of Pb-loss is of paramount importance. The impact of Pb-loss can be removed by chemical abrasion (CA) applied prior to the dissolution of zircon.
However, CA is an empirical approach that is used without a detailed understanding of how the temperature applied during the annealing step, or the temperature and duration of the partial dissolution step affect the radiation-damaged zones. In addition, the conditions of the CA procedures differ between laboratories making comparisons of age data problematic. This study presents an experimental approach to quantify how chemical abrasion affects the crystal structure
and the chemical composition of zircon as well as its UePb age. For this experiment, we have chosen the Plešovice reference zircon, because of its known variation in trace element concentrations and especially the presence of domains rich in actinides. We performed CA experiments under different temperature-time conditions on fragmented Plešovice crystals. These were compared in respect to the changes in trace element concentration, lattice order and UePb date. The most reliable UePb results are obtained by chemically abrading
Plešovice fragments at 210 °C for 12 h. Additionally, we demonstrate that the Plešovice zircon cannot be considered homogenous at the current level of precision achieved by CA-ID-TIMS dating due to a natural age variation at the ~900 kyr scale.
During the Late Ordovician, large explosive volcanic eruptions deposited worldwide K-bentonites, including the Millbrig and Deicke K-bentonites in North America and the Kinnekulle K-bentonite in Scandinavia. We have studied a classical locality in Oslo containing one of the most complete sections of K-bentonites in Europe. In a 53 m section of Sandbian age, we discovered 33 individual K-bentonite beds, the most notable beds being the Kinnekulle and the upper Grimstorp K-bentonite. Magnetic susceptibility (MS) measurements on two intervals show significant periodicity peaks interpreted as Milankovitch cycles and thus astronomically forced changes in sediment supply and composition. These cycles fit remarkably well with both the expected Milankovitch periodicities for the Ordovician as well as the radiometric ages presented in this study and may represent one of the most convincing demonstrations of Milankovitch cycles from the lower Paleozoic so far. Five of the K-bentonites have been dated by high-precision chemical abrasion-thermal ionization mass spectrometry (CA-TIMS) U-Pb zircon geochronology, where the Kinnekulle K-bentonite gives an age of 454.06 ± 0.43 Ma. We have integrated the new data and calculated an age model showing the sedimentation rates through the section and thereby the ages of each of the 33 K-bentonites. Using the age model, we further present a new age for the Sandbian-Katian stage boundary. The section in Oslo provides the highest resolution window into the Upper Ordovician K-bentonite succession so far and helps shed more light on the chronology of one of the most intense volcanic periods of the Paleozoic and the relationship with the global carbon cycle changes that followed.
Ordovician strata of the Mohawk Valley and Taconic allochthon of New York and the Humber margin of Newfoundland record multiple magmatic and basin-forming episodes associated with the Taconic orogeny. Here we present new U-Pb zircon geochronology and whole rock geochemistry and neodymium isotopes from Early Paleozoic volcanic ashes and siliciclastic units on the northern Appalachian margin of Laurentia. Volcanic ashes in the Table Point Formation of Newfoundland and the Indian River Formation of the Taconic allochthon in New York yield dates between 466.16 ± 0.12 and 464.20 ± 0.13 Ma. Red, bioturbated slate of the Indian River Formation record a shift to more juvenile neodymium isotope values suggesting sedimentary contributions from the Taconic arc-system by 466 Ma. Eight ashes within the Trenton Group in the Mohawk Valley were dated between 452.63 ± 0.06 and 450.68 ± 0.12 Ma. These ashes contain zircon with Late Ordovician magmatic rims and 1.4 to 1.0 Ga xenocrystic cores that were inherited from Grenville basement, suggesting that the parent magmas erupted through the Laurentian margin. The new geochronological and geochemical data are integrated with a subsidence model and data from the hinterland to refine the tectonic model of the Taconic orogeny. Closure of the Iapetus Ocean by 475 Ma via collision of the peri-Gondwanan Moretown terrane with hyperextended distal fragments of the Laurentian margin is not clearly manifested on the autochthon or the Taconic allochthon other than an increase in sediment accumulation. Pro-foreland basins formed during the Middle Ordovician when these terranes were obducted onto the Laurentian margin. 466 to 464 Ma ashes on the Laurentian margin coincide with a late pulse of magmatism in both the Notre Dame arc in Newfoundland and the Shelburne Falls arc of New England that is potentially related to break-off of an east-dipping slab. Following slab reversal, by 455 Ma, the Bronson Hill arc was established on the new composite Laurentian margin. Thus, we conclude that Late Ordovician strata in the Mohawk Valley and Taconic allochthon of New York and on the Humber margin of Newfoundland were deposited in retro-foreland basins.
The catastrophic disruption of the L chondrite parent body in the asteroid belt c. 470 Ma initiated a prolonged meteorite bombardment of Earth that started in the Ordovician and continues today. Abundant L chondrite meteorites in Middle Ordovician strata have been interpreted to be the consequence of the asteroid breakup event. Here we report a zircon U-Pb date of 467.50±0.28 Ma from a distinct bed within the meteorite-bearing interval of southern Sweden that, combined with published cosmic-ray exposure ages of co-occurring meteoritic material, provides a precise age for the L chondrite breakup at 468.0±0.3 Ma. The new zircon date requires significant revision of the Ordovician timescale that has implications for the understanding of the astrogeobiologic development during this period. It has been suggested that the Middle Ordovician meteorite bombardment played a crucial role in the Great Ordovician Biodiversification Event, but this study shows that the two phenomena were unrelated.
Accurate and precise dating of individual volcanogenic beds that spread across multiple sedimentary successions is a powerful tool to untangle stratigraphic age contradictions, since these horizons are deposited synchronously. In this study, we show that combining apatite chemistry with zircon age, Th/U ratio, and Hf isotope composition leads to reliable lateral correlation of volcanic horizons across sections representing disparate biological, chemical, and physical paleoenvironments. We correlate two volcanogenic horizons across six sedimentary sections straddling the Permian-Triassic boundary (PTB) in the Nanpanjiang Basin (South China), including the last Permian bed below the unconformity in shallow-water sections of the Luolou Platform. We place the PTB in our sections at the marked lithological change in order to avoid the difficulties that arise from the diachronism of the index conodont Hindeodus parvus, the first occurrence of which defines the PTB at the Global Stratotype Section and Point at Meishan. Our new data demonstrate that these volcanogenic beds are contemporaneous and cogenetic, allowing us to pool high-precision U-Pb zircon ages from the same horizon across several sections, and dating the last Permian volcanic event in this basin at 252.048 ± 0.033 Ma. We show that the mineral chemistry of apatite and zircon of intra- and interbasin-wide volcanogenic beds provides tie points against which biozones, carbon isotopes, astronomic cycles, and geomagnetic polarity time series can be stringently tested.
Pyroclastic material in the form of altered volcanic ash or tephra has been reported and described from one or more stratigraphic
units from the Proterozoic to the Tertiary. This altered tephra, variously called bentonite or K-bentonite or tonstein depending
on the degree of alteration and chemical composition, is often linked to large explosive volcanic eruptions that have occurred
repeatedly in the past. K-bentonite and bentonite layers are the key components of a larger group of altered tephras that
are useful for stratigraphic correlation and for interpreting the geodynamic evolution of our planet. Bentonites generally
form by diagenetic or hydrothermal alteration under the influence of fluids with high-Mg content and that leach alkali elements.
Smectite composition is partly controlled by parent rock chemistry. Studies have shown that K-bentonites often display variations
in layer charge and mixed-layer clay ratios and that these correlate with physical properties and diagenetic history. The
following is a review of known K-bentonite and related occurrences of altered tephra throughout the timescale from Precambrian
to Cenozoic.
Ordovician K-bentonite beds have a long history of investigation all around the world. They have been reported from Gondwana, the Argentine Precordillera, the Yangtze Platform, Laurentia, Baltica, and numerous terrains between Gondwana and Baltica, which now constitute a part of Europe. In recent years several K-bentonite beds have also been discovered in the Upper Ordovician of the Siberian Platform. This discovery is significant not only for their value in local and regional chronostratigraphic correlation but also for global geochronology, paleogeography, paleotectonic and paleoclimatic reconstructions. All in all, eight individual K-bentonite beds have been identified in the Baksian, Dolborian and Burian regional stages, which correspond roughly to the Upper Sandbian–Katian Global Stages. Zircon crystals from the uppermost K-bentonite bed within the Baksian regional stage provide a 206Pb/238U age of 450.58 ± 0.27 Ma. We will present preliminary results of the study of the three lowermost beds from the Baksian Regional Stage and suggest that the Taconic–Enisej (also spelled Yenisei or Yenisey) volcanic arc was continuous along the western margin of Siberia.
The early Late Ordovician sedimentary rocks of eastern North America contain a relatively large number (>100) of widespread heavily altered tephra layers (K-bentonites). These beds represent an intense period of subaerial volcanism that occurred from ca. 455 to 449 Ma. The sedimentary rocks that contain these K-bentonites display complex regional lithostratigraphic relationships ranging from clastic foreland basin facies to cratonic carbonate platform facies. Accurate correlation of these ancient ash-fall beds is essential for testing chronostratigraphic hypotheses that attempt to connect these different tectono-sedimentary provinces. Despite the relatively thorough study of a few of these K-bentonites over the past several decades, the full stratigraphic potential of these beds has yet to be realized. To test the utility of the apatite trace-element K-bentonite correlation method on a larger scale, we studied over 200 K-bentonite samples from the Mohawkian Stage of eastern North America and statistically compared our results with previous studies on the same suites of K-bentonites. Electron microprobe (EPMA) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) results show that apatite trace-element data provide unique bed discriminators. Each of the K-bentonite layers exhibits unique and reproducible trends in Mg, Cl, Mn, Fe, Ce, Y, and other trace-element concentrations in apatite. Statistical evaluation of results from our apatite analyses suggests correlations for 12 K-bentonite beds, providing a significant improvement in stratigraphic resolution. The stratigraphic relations indicated by these new K-bentonite fingerprints provide a rigorous means by which to evaluate some previous interpretations of biostratigraphic, chemostratigraphic, and sequence stratigraphic studies in eastern North America.
Altered volcanic ash interbeds (bentonites) in the upper Katian of Baltoscandia indicate significant volcanic activity in neighbouring tectonically active areas. Katian bentonites in the East Baltic can be reliably correlated using sanidine phenocryst composition. Ratios of immobile trace elements TiO
2
, Nb, Zr and Th to Al
2
O
3
enable extension of the correlations to Scandinavia, where late diagenetic alterations could have caused recrystallization of sanidine phenocrysts. At least seven volcanic eruptions were recognized in Baltoscandian sections. Several bentonites found in deep-sea sediments are absent in shallow-sea sediments, indicating extensive breaks in sedimentation and erosion during late Katian and Hirnantian times. The areal distribution pattern of Katian bentonites in Baltoscandia indicates a volcanic source from the north or northwest (present-day orientation) from the margins of the Iapetus Palaeo-Ocean. Signatures of ultra-high-pressure metamorphism in the Seve Nappe (Central Sweden) and intrusions in the Helgeland Nappe Complex in Central Norway have been proposed as potential sources of the magmas that generated the volcanic ashes deposited in the East Baltic in Katian times. Geochemical similarities between Baltoscandian and Dob's Linn bentonites from southern Scotland suggest a common volcanic source in Katian times.
Middle Ordovician bentonites in the central and southeastern United
States have been correlated on the basis of rare-earth element (REE)
concentrations of primary apatite phenocrysts. Ratios of light to heavy
REE, such as La/Tb or Ce/Yb, produce the best separation of the four
studied bentonites. The Deicke bentonite has been correlated over a
distance of more than 1000 km, from southern Minnesota to central
Tennessee, and the Millbrig bentonite has been correlated over 750 km,
from central Minnesota to central Missouri. The successful
discrimination of closely spaced bentonites over a long distance
demonstrates that apatite chemistry is a powerful correlation tool on a
continental scale.
North American Ordovician strata record a large shift in their neodymium isotopic composition ( ) at around Nd period before orogenic sources became dominant. We conclude from this that, superimposed on a general westward regional shift in sediment sources with time, there were also complex local effects involving multiple (unmixed) sediment sources that persisted long after the initial pulse of orogenic material arrived. The combined "simultaneous" nature of the isotopic shift, an Ordovician sea-level high stand, and the emergence of the Appalachian-Taconian- Caledonian orogenic belt as a primary sediment source, leads us to conclude that by 450 Ma, seafloor south of North America was being supplied by well-mixed, isotopically homogeneous sediment delivered from uplifted fold-thrust belts and foreland basins of the Appalachian Taconian highlands. U-Pb detrital zircon ages from bracketing sandstone units reinforce the Nd evidence for a complete changeover in provenance between 465 Ma (abundant Archean-age zircons) and 440 Ma (no Archean-age zircons) in the Ouachita region.
Biotite phenocryst compositions in three thick, widespread Ordovician K-bentonites, the Deicke and Millbrig from Big Ridge, Alabama, and the Kinnekulle from Mossen, V¨asterg¨otland, Sweden, fall into three distinct groups, and so the proposed intercontinental correlation of the Millbrig and the Kinnekulle is suspect. Because the biotites are nearly pristine compositionally, electron microprobe analyses provide a precise geochemical fingerprint of each bed. Millbrig and Kinnekulle biotites contain more FeO* and MnO and less MgO and TiO2 than do Deicke biotites. Millbrig biotites contain more MgO and less TiO2 than Kinnekulle biotites, and Kinnekulle biotites contain appreciably more Al2O3 than either Deicke or Millbrig biotites. Each of these tephras was unmistakably the product of a gigantic explosive volcanic eruption, but the differences in phenocryst chemistry point to derivation from three compositionally different magma batches.
Indicates that they originated from a major volcanic system. The Nd and Sr isotopic data and the U-Pb age data are consistent with the generation of the volcanic ash by anatexis of evolved continental crust. -from Authors
As the largest oil-bearing basin in northwest China, the Tarim basin records multiple major tectonic-sedimentary transitions during the Early Paleozoic, which play an important role in understanding assembly processes of Gondwana. An important transition from the Middle to Late Ordovician was development of important unconformity T74, the end of a unified carbonate platform, and development of turbidites in eastern basin. However, due to unobvious terrigenous clastic record, there is still a lack of understanding of driving mechanism of the tectonic transition. Marine carbonate red beds (MCRBs) with detritus components are developed in the Tumuxiuke/Kanling Formation at the bottom of the Upper Ordovician. By detailed field observation, zircon U-Pb dating and Hf-isotope analyses, provenance and the tectonic implication of the MCRBs are studied. New zircon U-Pb dating results constrain the depositional age of the MCRBs at ca. 454Ma. Provenance tracing shows the Precambrian detrital zircons were mainly sourced from the basement of the Tarim block, and the early Late Ordovician detrital zircons were probably derived from ash from the Altyun Tagh orogenic belt. Based on syn-depositional magmatic zircon records and the magmatic-metamorphic records in the Altyn Tagh orogenic belt, the closure age of North Altyn Ocean, one branch of Proto-Tethys Ocean, can be constrained to the latest Middle Ordovician (~ca. 460 Ma). The collison of the Tarim block with the Central Altyn terrane occurred (ca. 460 Ma - 454 Ma), leading to the major tectonic-sedimentary transition in the Tarim block. The U-Pb age spectrum of detrital zircons also indicates that the Tarim block is closely related to the North Indian block in Gondwana. This study shows that carbonate rocks with low clastic flux can be applied as provenance research objects.
Volcanism had been an important factor in several geological events, usually recorded by volcanic ash layers (bentonites). However, most volcanic eruption materials were dispersed and mixed with sediments as cryptotephra (invisible volcanic ash layers), unrecognisable by the naked eye, making the role of volcanism in major geological events obscure. Via analysis and correlation of the sources, diagenetic processes, and geochemical features of bentonites, this study established a set of new geochemical fingerprints for cryptotephra identification within shales, reconstructed the volcanic activities in the Lower Yangtze region during the O/S transition, and discussed the impact of volcanism on the Late Ordovician mass extinction (LOME) and related climate events. The main findings are: (1) Zr, Hf, Zr/Cr, Zr/Al2O3, Cr/Al2O3, V/Al2O3, Ni/Al2O3, SiO2/Al2O3, and K2O/Rb were relatively reliable geochemical fingerprints of volcanic material input within shales, and useful in reconstructing the volcanic activities in the Lower Yangtze region during the O/S transition. (2) The prolonged volcanic eruptions were sustained between the visible volcanic ash layers and characterised by two stages namely intensive volcanism, during the middle–late Katian and at the Hirnantian/Rhuddanian transition, and much weaker volcanism, during the very late Katian to early Hirnantian. (3) The intensive volcanism identified in middle–late Katian was tightly coupled with rapid biodiversity decline, and the prolonged (3–4 Ma) volcanic activities could have continuously affected the ecosystem, ultimately causing the first pulse of the LOME. In addition, the identified strong volcanic activities at the Hirnantian/Rhuddanian boundary were coincident with the second pulse of the LOME. The relationship between intensive volcanism and the two pulses of the LOME further supports a volcanic stressor for the biotic crises. (4) Volcanism was not only an important factor for marine productivity in geological history but also a nonnegligible mechanism for the Hirnantian glaciation. The methods and the geochemical fingerprints proposed in this study can serve as references for volcanism reconstruction and its environmental implications in other geological periods.
Tandem in situ and isotope dilution U-Pb analysis of zircons from pyroclastic volcanic rocks and both glacial and non-glacial sedimentary strata of the Pocatello Formation (Idaho, northwestern USA) provides new age constraints on Cryogenian glaciation in the North American Cordillera. Two dacitic tuffs sampled within glacigenic strata of the lower diamictite interval of the Scout Mountain Member yield high-precision chemical abrasion isotope dilution U-Pb zircon eruption and depositional ages of 696.43 ± 0.21 and 695.17 ± 0.20 Ma. When supplemented by a new high-precision detrital zircon maximum depositional age of ≤670 Ma for shoreface and offshore sandstones unconformably overlying the lower diamictite, these data are consistent with correlation of the lower diamictite to the early Cryogenian (ca. 717–660 Ma) Sturtian glaciation. These 670–675 Ma zircons persist in beds above the upper diamictite and cap dolostone units, up to and including a purported “reworked fallout tuff,” which we instead conclude provides only a maximum depositional age of ≤673 Ma from epiclastic volcanic detritus. Rare detrital zircons as young as 658 Ma provide a maximum depositional age for the upper diamictite and overlying cap dolostone units. This new geochronological framework supports litho- and chemostratigraphic correlations of the lower and upper diamictite intervals of the Scout Mountain Member of the Pocatello Formation with the Sturtian (716–660 Ma) and Marinoan (≤650–635 Ma) low-latitude glaciations, respectively. The Pocatello Formation thus contains a more complete record of Cryogenian glaciations than previously postulated.
We evaluate competing hypotheses regarding tectonic models of the early Taconic Orogeny in the Southern Appalachians during the Blountian tectophase with new geochemical data obtained from analyses of apatite and zircon phenocrysts, and melt and mineral inclusions therein, from the Ordovician Deicke K-bentonite (453.35 ± 0.10 Ma). Apatite geochemistry confirms that samples from different locations represent the same eruptive event, and zircon geochemistry and UPb geochronology (including several Grenville-age inherited detrital cores) confirm an evolved magma of continental-arc composition, with the trace-metal geochemistry of magmatic Taconic-age rims on Deicke zircons pointing to a provenance of continental crustal igneous rock melts, specifically a granitic melt with a high level of differentiation, rather than a melt that was mantle-derived, or strongly mantle-influenced. Melt inclusions within Deicke phenocrysts are dacitic (apatite) to rhyolitic (zircon), differences that imply an evolving Deicke magma during its eruption.
Our data 1) indicate multiple crustal events, and 2) are tectono-chemical evidence supporting an arc-trench subduction system where subducting preexisting sedimentary rocks were subsequently incorporated into the melt during or prior to collision. Indonesia provides modern analogs: the Banda Arc system, where Australian continental crust is jamming the subduction zone in association with the development of a foreland basin and a sedimentary wedge; the New Guinea – western Melanesian region, with its orogenic highlands and associated foredeep; and the Sumatra –Toba system, where subduction-related explosive volcanism has generated enormous caldera-forming eruptions above continental crust basement. Thus, a model for closure of the Iapetus Ocean involving subduction of older passive margin sediments as part of an island-arc collision with the Laurentian passive margin is acceptable, but models based on a back-arc basin are not compatible with our data.
The Ordovician-Silurian siliciclastic units of the Table Mountain Group (TMG; Cape Supergroup) of the Cape Fold Belt (CFB) are classically considered to signify a period of long-lived sedimentation along the southern margin of southern Africa. Despite its vast, prominent outcrop, meaningful interpretations regarding the provenance of the TMG, based on a representative number of Usingle bondPb detrital zircon age fractions, remains lacking. Within southern Gondwana, the TMG succession is considered broadly time-correlative to the Sierra del Volcan and Balcarce formations of the Sierras Tandilia and lowermost successions of the Ventana Group of the Sierras Australes in Argentina and the Port Stephens Formation of the West Falkland Group (WFG) in the Falkland/Malvinas Islands and Natal Group (South Africa). Usingle bondPb detrital zircon ages have previously been reported for the Balcarce Formation and Ventana and West Falkland groups. However, their age fractions have not necessarily been compared to the broadly time –equivalent units of the TMG. In addition to the overall scarcity of detrital zircon age data on the TMG, the validity of using conventional, qualitative probability density diagrams to display and interpret such data sets have come into question, with some authors arguing for a quantitative approach for comparing detrital zircon age data sets. A total of 1521 concordant Usingle bondPb detrital zircon ages and some 330 Lusingle bondHf isotope analysis for the Peninsula- and Skurweberg formations (TMG) are therefore contributed, from samples obtained throughout the CFB, along with detrital zircon age fractions for the Balcarce, Providencia and Port Stephens formations. A qualitative as well as quantitative approach to compare the Usingle bondPb detrital zircon age fractions measured for these units were adapted. Noticeable similarities among detrital zircon age fractions of the Peninsula- and Skurweberg formations throughout the western to south-eastern reaches of the CFB could be confirmed by quantitative pairwise comparisons. These point towards very little change in sediment source during the deposition of the lower to upper formations of the TMG during the Ordovician-Silurian. Pairwise comparisons of the TMG zircon age fractions to those of the Balcarce-, Providencia and Port Stephens formations revealed that they all have major late Neoproterozoic to Cambrian and a late Mesoproterozoic to early Neoproterozoic age fractions in common, with some minor contributions from Ordovician-Silurian sources. Due to the overlap in prevalent detrital zircon age fractions as well as Hf-isotope signature of these units, it is difficult to assign a specific provenance area for them with a fair amount of confidence, even if dominant palaeocurrent directions are considered. A quantitative pairwise comparison among data sets of the same or time-equivalent formation did not necessarily allow for age fractions from different source areas to be sufficiently distinguished from each other. In contrast to the classically inferred Namaqua-Natal Metamorphic Complex (NNMC) as source major proto-source for the TMG, it is argued that the sediment sources were located much further to the north such as the Damara and Mozambique belts, given that parts of the NNMC were likely denudated and covered by the sediments such as those of the Nama and Vanrhynsdorp Groups during the Ordovician-Silurian. Older sedimentary successions such as the Nama Group, were likely recycled during the deposition of the TMG: a scenario which also provides a feasible explanation for the noticeable lack of Archean ages among the detrital zircon age fractions. The ages of the youngest detrital zircon fraction conforms to the maximum age of deposition as proposed in literature, although the newly reported ages does not allow for more stringent cross-basin correlations. Regions within Patagonia, considered to have been in relatively close proximity to the relevant depositories, and possibly the Famatinian Belt (Argentina), are considered the source of the youngest Ordovician-Silurian detrital zircons.
Radioisotope geochronology provides a numerical age framework for the geologic time scale, and within its geologic context is integral to the practice of time scale construction. This chapter highlights the past decade of evolution in practice and interpretation of the U–Pb, ⁴⁰Ar/³⁹Ar, and Re–Os radiogenic isotope geochronometers as applied to time scale construction and calibration. Topics include innovations in instrumental analysis and experimental design, the intercalibration of these geochronometers to each other as well as to astrochronology, and progress in the statistical integration of radioisotope geochronology and stratigraphy for age model construction.
The Ordovician Period (486.9–443.1 Ma) encompasses two extraordinary biological events in the history of life on the Earth. The first, the “Great Ordovician Biodiversification Event,” is a great evolutionary radiation of marine life and the second is a catastrophic Late Ordovician extinction. Understanding the duration, rate, and magnitude of these events requires an increasingly precise time scale. The Ordovician time scale is based on the subdivision of a Lower Paleozoic CONOP9 composite graptolite range chart derived from 837 stratigraphic sections and 2651 graptolite taxa with interpolated radioisotopic dates. Thirty-seven new radioisotope dates are used in the scaling of the new Ordovician time scale. The base of the Ordovician Period is defined at the level of the first appearance of the conodont Iapetognathus fluctivagus at the Green Point Newfoundland section. Its top, the base of the Silurian Period, is set as the level of the first appearance of the graptolite Akidograptus ascensus at Dob’s Linn, Scotland. For the first time an independently time-scaled CONOP9 composite conodont range chart is presented to facilitate the application of the time scale to carbonate facies sections.
New palaeogeographical reconstructions for the earlier Ordovician (480 Ma), and later Ordovician (450 Ma) integrate revised longitude-calibrated palaeomagnetic reconstructions and the inclusion of synthetic plate margins within the now-vanished oceanic areas. There are substantial published differences from the previous placing of some of the continents and terranes in Asia; for example, Siberia and Gondwana have previously been placed at varied distances and relative positions in relation to the Kazakh terranes, South and North China, and Tarim. But there are only minor changes for most of the world, particularly in the North American and European areas. The global distributions of benthic trilobites and brachiopods within faunal provinces and their changes through the Ordovician are plotted, including the new term Cathay-Tasman Province for some pan-equatorial brachiopod faunas from China and Australia, and key sites and provinces are shown on the revised maps. The 30 Myrs from 470 to 440 Ma (mid Ordovician to early Silurian) saw some of the most varied and changeable climates of the whole Phanerozoic culminating in the 'Hirnantian' ice age. Those changes in turn much affected the rates of evolution of many benthic and pelagic animal groups which were driven by both biological and environmental causes. Global cooling during the Ordovician was a prime factor by reducing sea surface temperatures which challenged life to evolve faster and more substantially than before. That cooling was driven by decreasing atmospheric CO 2 , for reasons that are not fully resolved, but probably included reduced sourcing (re-duced continental arc activity) combined with increased silicate weathering due to the advent of land plants and perhaps the progressive exhumation of low-latitude collisional arcs. Since long-term CO 2 sinks are largely controlled by palaeogeography, the general increase in the concentration of continents in the tropics during the Ordovician increased the overall global weathering.
Perturbations to the global carbon cycle as recorded in the isotopic compositions of marine deposits have been commonly associated with major shifts in the climate and/or biologic activity, including mass extinctions. The Late Ordovician Guttenberg isotopic carbon excursion (GICE) is a large, globally correlative positive shift (∼3‰) in the carbon isotopic composition of marine carbonates (δ13Ccarb), but its driving mechanism(s) remains ambiguous. This is in large part due to uncertain correlations among Late Ordovician records, as well as complex and poorly constrained temporal relationships of abundant K-bentonite (altered volcanic ash) marker beds deposited in this time interval. Here, we provide new, high-precision U-Pb zircon geochronology by chemical-abrasion−isotope-dilution−thermal ionization mass spectrometry for K-bentonites bounding the GICE in the North American Midcontinent, including robust 206Pb/238U ages (reported with 2σ analytical uncertainty) for two important regional markers: the Deicke (453.35 ± 0.10 Ma) and Millbrig (453.36 ± 0.14 Ma) K-bentonites. The new data from these K-bentonites directly constrain the duration of the GICE to less than 400 k.y. at two well-studied locations in eastern Missouri, United States. The abruptness of the GICE precludes relatively gradual tectonic mechanisms as possible drivers of the excursion and suggests more rapid environmental drivers, such as changes in eustatic sea level associated with pre-Hirnantian glacial activity.
The breakup of the L-chondrite parent body (LCPB) in the mid-Ordovician is the largest documented asteroid breakup event during the past 3 Gyr. It affected Earth by a dramatic increase in the flux of L-chondritic material and left prominent traces in both meteorite and sedimentary records. A precise constraint on the timing of the LCPB breakup is important when evaluating the terrestrial biotic and climatic effects of the event, as well as for global stratigraphic correlations. Direct dating using heavily shocked L chondrites is hampered by both incomplete initial K-Ar degassing and isotopic resetting by later impact events. In order to better constrain the absolute age of this event we carried out high-precision U–Pb dating of zircons from three limestone beds recording discrete volcanic ash fallouts within mid-Ordovician strata in southern Sweden. These strata are rich in fossilized L-chondritic meteorites (1-20 cm large) that arrived on Earth shortly after the breakup event. Zircons from the ash-bearing layers provide stratigraphically consistent depositional ages that range from 464.22 ± 0.37 Ma to 465.01 ± 0.26 Ma. Combined with recently published ³He profiles that pinpoint the arrival on Earth of the first dust from the breakup, and sedimentation rates constrained by cosmogenic ²¹Ne in the fossil meteorites, the LCPB breakup is estimated to have occurred at 465.76 ± 0.30 Ma. This provides the presently most precise absolute dating of the LCPB breakup, enabling a robust global stratigraphic correlation of bounding strata. Based on our new U–Pb data for the ash-bearing beds, the absolute ages for the boundaries of biozones and Dapingian–Floian stages overlap within error with those given by the 2012 Geological Timescale and require no modification.
Three stages of carbonate-platform development are preserved in the upper Turinian – lower Chatfieldian succession of the Ottawa Group in the Ottawa Embayment and represent deposition along the Late Ordovician Taconic foreland interior of paleo-southern Laurentia. Compared with contemporary stratigraphy in the adjacent northern Appalachian (southern Ontario, New York state) and western Quebec basins, the intermediate Stage 2 succession, which brackets the Turinian–Chatfieldian boundary, preserves embayment-specific stratigraphic patterns. These include: (i) dramatic west-to-east thickening of the upper Turinian Watertown Formation that defines differential subsidence along the present axis of the embayment, (ii) post- Watertown base-level fall defined by appearance of shoreface siliciclastics, (iii) early Chatfieldian marine transgression represented by the proposed L’Orignal Formation that is coeval with but lithologically distinct from the Selby Formation in the northern Appalachian Basin, and (iv) platform segmentation that resulted in a depositional mosaic of shallow banks (Rockland Formation) and equivalent deeper water mico-seaways (lower Hull Formation). The latter event immediately follows accumulation of the Millbrig bentonite, here dated at 453.36 ± 0.38 Ma. Bracketing these local stratigraphic patterns are the bounding stages (1 and 3) represented by the upper Turinian Lowville Formation and middle Chatfieldian Hull Formation, respectively, that contain facies attributes in common with the adjacent basins and characterize inter-regional depositional systems of first warm, then cooler oceanographic conditions. Stage 2 identifies a structurally controlled transition between these end-member stages: a far-field response in the foreland interior, localized along the axis of a late Precambrian fault system, to contemporary change in subsidence rates and tectonomagmatic events along the Laurentian margin.
A continuously cored section of more than 300 m through the Nambeet Formation and the basal part of the conformably overlying Willara Formation in the Olympic 1 petroleum well, drilled in the Canning Basin of northern Western Australia, yields valuable information that increases by more than 40% the number of precise isotopic ages available to constrain the Ordovician Period. New CA-IDTIMS U–Pb zircon ages for seven bentonite layers in the Olympic 1 core are integrated into a new conodont biostratigraphic framework for the Early Ordovician comprising four biozones recognised in this well. The weighted mean U–Pb dates range from 479.37 ± 0.16 Ma within the late Tremadocian Paroistodus proteus conodont Biozone, to 470.18 ± 0.13 Ma near the boundary between the Floian and Dapingian stages within the Jumudontus gananda conodont Biozone. The intervening Prioniodus oepiki–Serratognathus bilobatus conodont Biozone (early Floian) and succeeding Oepikodus communis conodont Biozone (middle Floian) are similarly well constrained by isotopic dates centred on ca 477 Ma for the early Floian and by three ages of 473–471 Ma for the middle Floian. The seven new isotopic dates significantly increase the precision of dating for the Early Ordovician, where previously only two ages with limited or imprecise biostratigraphic control were known globally.
The Earth's climate cooled through the Ordovician Period leading up to the Hirnantian glaciation. Increased weatherability of silicate rocks associated with topography generated on the Appalachian margin during the Taconic orogeny has been proposed as a mechanism for Ordovician cooling. However, paleogeographic reconstructions typically place the Appalachian margin within the arid subtropics, outside of the warm and wet tropics where chemical weathering rates are highest. In this study, we reanalyze the paleomagnetic database and conclude that Ordovician constraints from cratonic Laurentia are not robust. Instead, we use paleomagnetic data from well-dated volcanic rocks in the accreting terranes to constrain Laurentia's position given that the Appalachian margin was at, or equatorward of, the paleolatitude of these terranes. To satisfy these allochthonous data, Laurentia must have moved toward the equator during the Ordovician such that the Appalachian margin was within 10° of the equator by 465 Ma. This movement into the tropics coincided with the collision and exhumation of the Taconic arc system, recorded by a shift in neodymium isotope data from shale on the Appalachian margin to more juvenile values. This inflection in detrital neodymium isotope values precedes a major downturn in global seawater strontium isotopic values by more than one million years, as would be predicted from a change in weathering input and the relatively long residence time of strontium in the ocean. These data are consistent with an increase in global weatherability associated with the tropical weathering of mafic and ultramafic lithologies exhumed during the Taconic arc-continent collision. A Taconic related increase in weatherability is a viable mechanism for lowering atmospheric CO2 levels through silicate weathering contributing to long-term Ordovician cooling.
This study uses detrital zircon U-Pb geochronology from shallow-water carbonates of the Bighorn Dolomite in Wyoming,
USA, to provide robust evidence for long-distance eolian sediment transport during the Ordovician. The Bighorn Dolomite
was deposited in a shallow-water carbonate platform that developed approximately 107 south of the Ordovician paleoequator
on the western edge of Laurentia. The ages and textures of detrital zircons from the Bighorn indicate that the grains
were transported by winds through saltation and suspension from the paleo east where rocks of the Paleoproterozoic Trans-
Hudson orogenic belt were exposed in present-day Manitoba and Saskatchewan. Our interpretation of long-distance eolian
transport is consistent with the paleogeography of Laurentia and expected prevailing wind directions and draws on modern
analogs where Saharan sediment is transported by trade winds for distances of more than 3000 km.
High-precision geochronological techniques have improved in the past decade to the point where volcanic ash beds interstratified with fossil-bearing rocks can be dated to a precision of 0.1% or better. The integration of high-precision U-Pb zircon geochronology with bio/chemo-stratigraphic data brings about new opportunities and challenges toward constructing a fully calibrated time scale for the geologic record, which is necessary for a thorough understanding of the distribution of time and life in Earth history. Successful implementation of geochronology as an integral tool for the paleontologist relies on a basic knowledge of its technical aspects, as well as an ability to properly evaluate and compare geochronologic results from different methods. This paper summarizes the methodology and new improvements in U-Pb zircon geochronology by isotope dilution thermal ionization mass spectrometry, specifically focused on its application to the stratigraphic record.
We have determined 238U/235U ratios for a suite of commonly used natural (CRM 112a, SRM 950a, and HU-1) and synthetic (IRMM 184 and CRM U500) uranium reference materials by thermal ionisation mass-spectrometry (TIMS) using the IRMM 3636 233U–236U double spike to accurately correct for mass fractionation. Total uncertainty on the 238U/235U determinations is estimated to be <0.02% (2σ). These natural 238U/235U values are different from the widely used ‘consensus’ value (137.88), with each standard having lower 238U/235U values by up to 0.08%. The 238U/235U ratio determined for CRM U500 and IRMM 184 are within error of their certified values; however, the total uncertainty for CRM U500 is substantially reduced (from 0.1% to 0.02%). These reference materials are commonly used to assess mass-spectrometer performance and accuracy, calibrate isotope tracers employed in U, U–Th and U–Pb isotopic studies, and as a reference for terrestrial and meteoritic 238U/235U variations. These new 238U/235U values will thus provide greater accuracy and reduced uncertainty for a wide variety of isotopic determinations.
Biotites from thermally undisturbed bentonites from the interval of North American Mid-continent Conodont Faunas 7 and 8, corresponding to an age of Blackriveran to early Kirkfieldian, have been analyzed by 40Ar/39Ar age spectrum techniques. A mean age for the above-mentioned biostratigraphic interval of approx 454Ma is obtained. Biotites that have individual temperature steps with apparent K/Ca ratios above approx 50 tend to define age plateaus, whereas temperature steps with apparent K/Ca ratios below approx 50 tend to yield discordant ages. Comparison of plateau ages with their corresponding total gas ages suggest that conventional K/Ar dating of these biotites would generally yield only minimum age estimates for these bentonites.-from Authors
Explosive eruptions from volcanoes are recorded in the stratigraphic record throughout the Phanerozoic, but evidence of these eruptions in the form of preserved tephra layers appears to be concentrated at times of active plate collision and concomitant high stands of sea level. The products of volcanic eruptions are lavas, tephra, and gases. Basaltic magmas (low-silica content) are usually erupted in the form of lava flows, whereas rhyolitic magmas (high-silica content) are commonly explosively erupted as plinian and ultraplinian plumes, and associated pyroclastic flows. Fallout tephras are preserved in ancient sedimentary sequences as tonsteins, bentonites, and K-bentonites. Middle Ordovician K-bentonites represent some of the largest known fallout ash deposits in the Phanerozoic Era. They cover minimally 2.2 × 106 km2 in eastern North America and 6.9 × 10 5 km2 in central and northwestern Europe as a result of explosive volcanism, which affected both Laurentia and Baltica during the closure of the Iapetus Ocean. The three most widespread beds are the Deicke and Millbrig K-bentonites in North America and the Kinnekulle K-bentonite in northwestern Europe. Similar successions are well known in South America and China. Sedimentation rates of volcanic ejecta range from meters per year locally to ∼1 mm/1000 yr in the deep sea. Volcanogenic sediments react with seawater to produce secondary phases such as zeolites and clay minerals. Studies of recent ashfall behavior suggest that the preservation potential in the stratigraphic record can be viewed as somewhat remarkable in that such sudden events are preserved at all, much less produce such a wealth of valuable geologic information.
U-Pb zircon geochronology and field relations provide insights into metavolcanic and associated rocks in the Central Appalachian Piedmont of Maryland and northern Virginia. Ordovician ages were determined for volcanic-arc rocks of the James Run Formation (Churchville Gneiss Member, 458 ± 4 Ma; Carroll Gneiss Member, 462 ± 4 Ma), Relay Felsite (458 ±4 Ma), Chopawamsic Formation (453 ± 4 Ma), and a Quantico Formation volcaniclastic layer (448 ± 4 Ma). A previously dated first phase of volcanism in the Chopawamsic Formation was followed by the second phase dated here. The latter suggests a possible source for contemporaneous volcanic-ash beds throughout eastern NorthAmerica. Dates from the Chopawamsic and Quantico Formations constrain the transition fromarc volcanism to successor-basin sedimentation. Ordovician metatonalites of the Franklinville (462 ± 5 Ma) and Perry Hall (461 ± 5 Ma) plutons are contemporaneous with the James Run Formation, whereas granitoids of the Bynum Run (434 ± 4 Ma) and Prince William Forest (434 ± 8 Ma) plutons indicate an Early Silurian plutonic event. The Popes Head Formation yielded Mesoproterozoic (1.0-1.25Ga, 1.5-1.8 Ga) detrital zircons, and metamorphosed sedimentary mélange of the Sykesville Formation yielded Mesoproterozoic (1.0-1.8 Ga) detrital zircons plus a minor Archean (2.6 Ga) component. A few euhedral zircons (ca. 479 Ma) in the Sykesville Formation may be from granitic seams related to the Dalecarlia Intrusive Suite. A Potomac orogenyin the Central Appalachian Piedmont is not required, but the earliest Taconic orogenesis remains poorly constrained.
Stratal patterns of the Middle Ordovician Hagan K-bentonite complex and associated rocks show that the Black River-Trenton unconformity in the North American midcontinent formed through the complex interplay of eustasy, sediment accumulation rates, siliciclastic influx, bathymetry, seawater chemistry, and perhaps local tectonic uplift. The unconformity is diachronous and is an amalgamated surface that resulted from local late Turinian lowstand exposure followed by regional early Chatfieldian transgressive drowning and sediment starvation. The duration of the unconformity is greatest in southern Wisconsin, northern Illinois, and northern Indiana, where the Deicke and Millbrig K-bentonite Beds converge at the unconformity. On the basis of published isotopic ages for the Deicke and Millbrig beds, it is possible that in these regions erosion and non-deposition spanned a period of as much as 3.2 m.y. Two broad coeval depositional settings are recognized within the North American midcontinent during early Chatfieldian time. 1) An inner shelf, subtidal facies of fossiliferous shale (Spechts Ferry Shale Member and Ion Shale Member of the Decorah Formation) and argillaceous lime mudstone and skeletal wackestone (Guttenberg and Kings Lake Limestone Members) extended from the Canadian shield and Transcontinental arch southeastward through Minnesota, Wisconsin, Iowa, and Missouri. 2) A seaward, relatively deep subtidal, sediment-starved, middle shelf extended eastward from the Mississippi Valley region to the Taconian foreland basins in the central and southern Appalachians and southward through the pericratonic Arkoma and Black Warrior basins. In the inner shelf region, the Black River-Trenton unconformity is a composite of at least two prominent hardground omission surfaces, one at the top of the Castlewood and Carimona Limestone Members and the other at the top of the Guttenberg and Kings Lake Limestone Members, both merging to a single surface in the middle shelf region. The inner and middle shelves redeveloped later in approximately the same regions during Devonian and Mississippian time.
The Ordovician Millbrig K-bentonite of North America and the Kinnekulle "Big Bed" of Scandinavia have been considered correlative, thus representing one of the largest volcanic eruptions of the Phanerozoic. Whether these two K-bentonites correlate has implications for the paleogeographic reconstructions of Laurentia and Baltica, transoceanic biostratigraphic correlations of graptolites and conodonts, and the possibly global occurrence of the Guttenberg carbon isotope excursion. Trace element analyses of apatite phenocrysts have proven to be good discriminators for other Ordovician K-bentonites and it is shown here, on the basis of significantly different Mg, Cl, Mn, Fe, Ce, and Y concentrations in apatite phenocrysts from the Kinnekulle and Millbrig K-bentonites, that the beds must be viewed as representing two or more different eruptions. Vertical subsampling of several layers from each bed suggests that both beds are likely composed of multiple components, but none of the components coincide with one another. These results indicate that the Millbrig and Kinnekulle beds cannot both be derived from a single ultra-Plinian eruption, as previously proposed.
The Late Ordovician Taconic orogeny was associated with volcanic eruptions along the subduction zones of the Iapetus Ocean One of these eruptions, which led to the deposition of the Deicke K-bentomte Bed, is believed to hale been larger than the largest recent and subrecent volcanic eruptions (e g, Toba, Pinatubo) The Deicke eruption has been proposed to have led to a cooling event and associated faunal turnover during the Sandbian-Katian of Laurentia based in part on the observed lowering of global surface temperature after recent mega-eruptions We tested for a geologically resolvable climatic perturbation associated with the Deicke eruption by estimating changes in ocean temperatures from the oxygen isotope ratios of single-species separates of conodont apatite from a section of the Carimona Member of the Platteville Formation in southeastern Minnesota, United States, that includes the Deicke K-bentonite In contrast to predictions of models invoking more or less direct volcanic forcing for Ordovician climate trends, we found no obvious or consistent change in temperature at or above the bentonite, but did see evidence of cooling (similar to 4 degrees C) among presumed nekto-benthic taxa in the 0 7 meters of the section below the bentonite Thus, at least for the study area, there is no evidence that the Deicke eruption Induced a significant cooling event
Two of the largest known eruptions in the Phanerozoic produced the Ordovician Millbrig K-bentonite of North America and the Kinnekulle K-bentonite of Scandinavia, which have been previously suggested to be coeval. The Millbrig K-bentonite from Kentucky, USA and the Kinnekulle K-bentonite from Bornholm, Denmark yielded chemical abrasion thermal ionization mass spectrometry U–Pb zircon dates of 452.86 ± 0.29 and 454.41 ± 0.17 Ma (2σ analytical uncertainty), respectively, thus showing significant age differences contrary to what is generally held. These data and four additional newly dated K-bentonites directly establish the first radioisotopic age constraints for the Ordovician Katian–Sandbian global stage boundary, refine global stratigraphic correlations, date associated chemostratigraphic events, and suggest an alternative volcanic–climate hypothesis for the Late Ordovician.
Supplementary material
U–Pb radioisotopic data table and analytical methods are available at www.geolsoc.org.uk/SUP18636 .
Two different approaches to deconvolving mixed age populations resolve SIMS ages within the TEMORA reference zircon into a small slightly older group and a large group that is well fitted within the calculated age uncertainties. We discard the older group as spurious rather than increase the uncertainties to try to obtain a (statistically) single propulation. This approach minimizes errors in the sample component ages and allows more reliable detection of potentially real age differences. The R33 reference zircon was run to give an explicit measure of accuracy relative to TEMORA but results are indecisive owing to probable Pb loss. Zircons from four tuff horizons within the lower Palaeozoic British stratotypes were re-dated using SIMS to explore the possible presence of slightly older detrital zircons. Two tuff horizons, the Llyfnant Flags (Floian) and Serw Formation (Darriwilian), have single age components, and the Pont-y-Ceunant Ash (Katian) and Birkhill Shale (lower Llandovery) have two components interpreted to be volcanic and slightly older inherited zircons. These and previous SHRIMP ages referenced to the SL13 standard confirm that isotope dilution ages for the same tuffs need revision.
Fresh volcanic glasses in the form of melt inclusions within quartz phenocrysts are commonly present in Paleozoic K-bentonites from New York State, Iowa, Kentucky, Pennsylvania, Newfoundland, and Quebec. Because these glasses are compositionally distinct from one layerto another, their geochemistry can be used to define chronostratigraphic horizons. In New York State, the K-bentonites occur within flat-lying, calcareous black shales of the Middle Ordovician Utica Formation. This glass has survived (1) because it has been sealed within a host crystal that is stable under most diagenetic conditions, and (2) because of the modest burial depths the Ordovician strata in this region. To demonstrate the potential of these volcanic glasses for stratigraphic correlations, isochronous surfaces have been established among three localities separated by 35 km. The immaculate preservation of these Ordovician glasses bodes well for the general application of this approach to younger, and perhaps even older, strata where geologic conditions have favored the survival of glass inclusions.
Strata of the Champlainian (Middle Ordovician) Decorah Subgroup in the
upper Mississippi Valley region have been correlated on the basis of the
chemical composition of K-bentonite beds in widely distributed outcrops
and cores. The four principal K-bentonite beds in the Decorah—the
Deicke, Millbrig, Elkport, and Dickeyville—can be differentiated
by their unique chemical fingerprints, which were established using a
linear discriminant function analysis. The elements that served as the
best discriminators of differences between beds were, in order of atomic
number, Na, Sc, Ti, Zr, Sm, Eu, Tb, Dy, Yb, Lu, Hf, Ta, and Th. Although
no one element serves to delineate a K-bentonite bed completely from
others, a combination of elements can do so. The chemical signatures of
the Deicke and Millbrig K-bentonite Beds, the two thickest and most
widespread K-bentonites in the Mississippi Valley, were recognized in
outcrop and subsurface from southern Minnesota to southeastern Missouri,
a distance of about 900 km. The Elkport and the Dickeyville K-bentonites
were chemically identified in a limited area in northern Illinois,
southwestern Wisconsin, and northern Iowa. The Decorah consists of
widespread lithologic units that are approximately parallel to
K-bentonite beds in some areas, but in other areas lateral gradation of
lithologies, as shown by K-bentonite correlations, indicates
contemporaneity of Decorah lithofacies.