Process monitoring is becoming increasingly important to maintain reliable and safe process operation. Among the most important applications of process safety are those related to environmental and chemical processes. A critical fault in a chemical or a petrochemical process may not only cause a degradation in the process performance or lower its product quality, but it can also result in catastrophes that may lead to fatal accidents and substantial economic losses. Therefore, detecting anomalies in chemical processes is vital for their safe and proper operations. Also, abnormal atmospheric pollution levels negatively affect the public health, animals, plants, climate, and damage the natural resources.
Therefore, monitoring air quality is also crucial for the safety of humans and the
environment. Thus, the main aim of this study is to develop enhanced fault detection
methods than can improve air quality monitoring and the operation of chemical processes.
When a model of the monitored process is available, model-based monitoring methods
rely on comparing the process measured variables with the information obtained from
the available model. Unfortunately, accurate models may not be available, especially for
complex chemical and environmental processes. In the absence of a process model, latent variable models, such principal component analysis (PCA) and partial least squares
(PLS), have been successfully used in monitoring processes with highly correlated process variables. When a process model is available, on the other hand, statistical hypothesis testing methods, such as the generalized likelihood ratio test (GLRT), have shown good fault detection abilities. In this thesis, extensions using nonlinear models and input latent variable regression techniques (such as PCA) are made to achieve further improvements and widen the applicability of the developed methods in practice. Also, kernel PCA is used to deal process nonlinearities. Unfortunately, PCA and kernel PCA models are batch and then they demand the availability of the process data before building the model. In most situations, however, fault detection is required online, i.e., as the data are collected from the process. Therefore, recursive PCA and kPCA-based statistical hypothesis testing, so recursive PCA and kernel PCA techniques will be developed in order to extend the advantages of the developed techniques to online processes. The third objective of this work is to utilize the developed fault detection methods to enhance monitoring various chemical and environmental processes. The developed fault detection techniques are used to enhance monitoring the concentration levels of various air pollutants, such as ozone, nitrogen oxides, sulfur oxides, dust, and others. Real air pollution data from France are used in this important application. The developed fault detection methods are also utilized to enhance monitoring of various chemical processes such as continuous stirred-tank reactor (CSTR) and Tennessee Eastman process (TEP).