ChemInform Abstract: Ag(I)F as One Electron Oxidant for Promoting Sequential Double Desilylation: An Ideal Approach to Non-Stabilized Azomethine Ylides for the Rapid Construction of 1-Azabicyclo(m.3.0)alkanes.
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Abstract
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A novel methodology for effecting sequential double desilylation by Ag(I)F for the generation of non-stabilized azomethine ylide and its application for the synthesis of 1-azabicyclo(m.3.0) alkane systems are described.