Optical wavelength sensing interrogator based on hydrogen cyanide (HCN) gas absorption cell and tunable fiber laser are researched, besides, high performance simultaneous sampling card is used in the system to acquire sensing signals of six channels simultaneously. The absorption wavelengths of HCN spectrum are identified followed by the recognizing two absorption wavelengths with maximum spacing, thus high-resolution and real-time calibration of sweep-wavelength can be achieved, which can eliminate the fiber Fabry-Pérot tunable filter (FFP-TFs) disadvantages such as non linearity and poor repeatability. Experimental results show that the resolution of the system is 1.6 pm and the long-term repeatability is 3.4 pm for fiber Bragg grating measurement, which means that high resolution wavelength demodulation can be achieved with the scheme.