... They produce scenic landscapes and morphological features on the Earth's surface, such as gryphons, mud and scoria cones, salses, springs and fire columns [3][4][5][6]. However, the release of toxic and radioactive elements (arsenic, As; barium, Ba; copper, Cu; strontium, Sr; uranium, U; zinc, Zn, etc.) and (a) biogenic gases (e.g., methane, CH 4 and minor carbon dioxide, CO 2 ) during the active and dormant periods of volcanoes can impact the chemistry of local surface water, groundwater, interstitial solutions and sediments, as well as the Earth's atmospheric gas budget [7][8][9][10][11][12][13][14][15][16]. In many places, mud volcanic activity is triggered by the rapid subsidence of soft, fine-grained sediments rich in water and organic matter in a compressive tectonic setting, which promotes the generation of hydrocarbons and, subsequently, the formation The widespread, active and passive mud volcano systems located onshore in East Azerbaijan are relatively well documented with respect to their fluid and solid ejects [4,11,[26][27][28]. ...