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A seismogenic zone in the deep crust indicated by pseudotachylytes and ultramylonites in granulite-facies rocks of Calabria (Southern Italy)

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Pseudotachylyte veins frequently associated with mylonites and ultramylonites occur within migmatitic paragneisses, metamonzodiorites, as well as felsic and mafic granulites at the base of the section of the Hercynian lower crust exposed in Calabria (Southern Italy). The crustal section is tectonically superposed on lower grade units. Ultramylonites and pseudotachylytes are particularly well developed in migmatitic paragneisses, whereas sparse fault-related pseudotachylytes and thin mylonite/ultramylonite bands occur in granulite-facies rocks. The presence of sillimanite and clinopyroxene in ultramylonites and mylonites indicates that relatively high-temperature conditions preceded the formation of pseudotachylytes. We have analysed pseudotachylytes from different rock types to ascertain their deep crustal origin and to better understand the relationships between brittle and ductile processes during deformation of the deeper crust. Different protoliths were selected to test how lithology controls pseudotachylyte composition and textures. In migmatites and felsic granulites, euhedral or cauliflower-shaped garnets directly crystallized from pseudotachylyte melts of near andesitic composition. This indicates that pseudotachylytes originated at deep crustal conditions (>0.75 GPa). In mafic protoliths, quenched needle-to-feather-shaped high-alumina orthopyroxene occurs in contact with newly crystallized plagioclase. The pyroxene crystallizes in garnet-free and garnet-bearing veins. The simultaneous growth of orthopyroxene and plagioclase as well as almandine, suggests lower crustal origin, with pressures in excess of 0.85 GPa. The existence of melts of different composition in the same vein indicates the stepwise, non-equilibrium conditions of frictional melting. Melt formed and intruded into pre-existing anisotropies. In mafic granulites, brittle faulting is localized in a previously formed thin high-temperature mylonite bands. migmatitic gneisses are deformed into ultramylonite domains characterized by s-c fabric. Small grain size and fluids lowered the effective stress on the c planes favouring a seismic event and the consequent melt generation. Microstructures and ductile deformation of pseudotachylytes suggest continuous ductile flow punctuated by episodes of high-strain rate, leading to seismic events and melting.
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ORIGINAL PAPER
A seismogenic zone in the deep crust indicated
by pseudotachylytes and ultramylonites in granulite-facies
rocks of Calabria (Southern Italy)
U. Altenberger
G. Prosser
A. Grande
C. Gu
¨
nter
A. Langone
Received: 10 September 2012 / Accepted: 5 June 2013
Ó Springer-Verlag Berlin Heidelberg 2013
Abstract Pseudotachylyte veins frequently associated
with mylonites and ultramylonites occur within migmatitic
paragneisses, metamonzodiorites, as well as felsic and
mafic granulites at the base of the section of the Hercynian
lower crust exposed in Calabria (Southern Italy). The
crustal section is tectonically superposed on lower grade
units. Ultramylonites and pseudotachylytes are particularly
well developed in migmatitic paragneisses, whereas sparse
fault-related pseudotachylytes and thin mylonite/ultramyl-
onite bands occur in granulite-facies rocks. The presence of
sillimanite and clinopyroxene in ultramylonites and myl-
onites indicates that relatively high-temperature conditions
preceded the formation of pseudotachylytes. We have
analysed pseudotachylytes from different rock types to
ascertain their deep crustal origin and to better understand
the relationships between brittle and ductile processes
during deformation of the deeper crust. Different protoliths
were selected to test how lithology controls pseudotachy-
lyte composition and textures. In migmatites and felsic
granulites, euhedral or cauliflower-shaped garnets directly
crystallized from pseudotachylyte melts of near andesitic
composition. This indicates that pseudotachylytes origi-
nated at deep crustal conditions ([0.75 GPa). In mafic
protoliths, quenched needle-to-feather-shaped high-alu-
mina orthopyroxene occurs in contact with newly crystal-
lized plagioclase. The pyroxene crystallizes in garnet-free
and garnet-bearing veins. The simultaneous growth of
orthopyroxene and plagioclase as well as almandine, sug-
gests lower crustal origin, with pressures in excess of
0.85 GPa. The existence of melts of different composition
in the same vein indicates the stepwise, non-equilibrium
conditions of frictional melting. Melt formed and intruded
into pre-existing anisotropies. In mafic granulites, brittle
faulting is localized in a previously formed thin high-
temperature mylonite bands. migmatitic gneisses are
deformed into ultramylonite domains characterized by s-c
fabric. Small grain size and fluids lowered the effective
stress on the c planes favouring a seismic event and the
consequent melt generation. Microstructures and ductile
deformation of pseudotachylytes suggest continuous duc-
tile flow punctuated by episodes of high-strain rate, leading
to seismic events and melting.
Keywords Pseudotachylyte Calabria Lower crust
Palaeo-seismicity
Introduction
Fault-related pseudotachylytes record ancient hypocentres,
usually located at upper crustal depths (e.g. Hetzel et al.
1996; Sibson and Toy 2006; Lin 2008a). However,
Communicated by G.Moore.
U. Altenberger (&) C. Gu
¨
nter
Institute of Earth and Environmental Sciences,
University of Potsdam, Karl-Liebknecht-Str. 24,
14476 Potsdam-Golm, Germany
e-mail: uwe@geo.uni-potsdam.de
G. Prosser
Dipartimento di Scienze, Universita
´
della Basilicata,
Via dell’Ateneo Lucano, 10, 85100 Potenza, Italy
e-mail: giacomo.prosser@unibas.it
A. Grande
Istituto di Geoscienze e Georisorse-CNR, Via Moruzzi 1,
56124 Pisa, Italy
A. Langone
Istituto di Geoscienze e Georisorse-CNR, Via Ferrata 1,
27100 Pavia, Italy
123
Contrib Mineral Petrol
DOI 10.1007/s00410-013-0904-3
evidence derived from both present seismicity and fossil
earthquake sources indicates that the lower continental
crust may also be a site where seismic events can be
generated (Clarke and Norman 1993; Austrheim and Bo-
undy 1994; Jackson 2002; Lin 2008b; Altenberger et al.
2011). Generally, pseudotachylytes formed below
12-15 km, that is, below the classical seismogenic brittle
upper part of the crust, are intimately associated with
mylonites and ultramylonites (Passchier 1982; White 1996;
Pennacchioni and Cesare 1997; Pittarello et al. 2010).
Particularly, mutual overprinting relationships between
pseudotachylytes and ultramylonites in upper and middle
crust indicate that a long-lasting creep regime was inter-
rupted by episodic rapid slip events (Handy and Brun
2004). This association of fault rocks, apparently con-
nected to strongly different strain rates and rheology, has
been interpreted to represent a number of processes such
as: (i) alternating brittle faulting and ductile shearing along
a fault developed across the brittle-ductile transition
(Takagi et al. 2000); (ii) downward propagation along
mylonites of a fault nucleated at higher crustal levels
(Sibson 1980; Lin et al. 2003, 2005 Lin 2008b; Moecher
and Steltenpohl 2009; Pittarello et al. 2012); (iii) stress
concentration at stronger lensoid-shaped bodies (Sibson
1980); (iv) stress concentrations around or within the more
competent layers (Fagereng 2010); (v) plastic instabilities
during ductile flow leading to seismic events (Hobbs et al.
1986). The last process is more likely activated during
high-strength crystal-plastic deformation in a fluid-defi-
cient environment (White 1996). The concurrent formation
of mylonites and pseudotachylytes has been confirmed also
by recent experiments carried out at seismic slip rates on
halite gouge (Kim et al. 2010). Summarizing, high stress
and strain rates, at low fluid pressures, may lead to con-
ditions for instabilities during high-strength flow (White
1996). This process may produce rapid sliding and fric-
tional heating in mylonites or ultramylonites, if deforma-
tion rate suddenly increases. Alternatively, pre-existing
anisotropies, such as thin mylonite bands, may localize the
propagation of a fault into a region where intermittent
brittle deformation occurs.
The presence of pseudotachylytes in high-grade rocks is
not a proof that they formed at lower crustal depths, since
seismic events can generate during exhumation of origi-
nally deep units (Techmer et al. 1992; Pittarello et al.
2012). Seismic instabilities are thought to occur when
exhumation rate slows down after a faster exhumation
episode (Zechmeister et al. 2007). However, a deep origin
for pseudotachylytes can be proven by mineral composi-
tion of newly crystallized microlites (Austrheim et al.
1996; Austrheim and Andersen 2004; Altenberger et al.
2011) or from the recrystallization products developed
during a subsequent mylonitic overprint (White 1996).
In this paper, we will describe pseudotachylytes devel-
oped in a kilometre-thick zone of migmatitic paragneisses,
felsic, intermediate and mafic granulites exposed in Cala-
bria (Southern Italy). One sample of a pseudotachylyte
within a felsic protolith has already been described in detail
by Altenberger et al. (2011) and its lower crustal origin has
been assessed from the occurrence of garnets with cauli-
flower and euhedral shapes directly crystallized from the
pseudotachylyte melt. Starting from this early finding, we
present new analyses of pseudotachylytes from a wide area
of the Calabria high-grade basement (Fig. 1), where dif-
ferent rock types can be recognized and give some evi-
dence for localization mechanisms. This significantly
expands the earlier observations carried out by Altenberger
et al. (2011), since the present work reports microstructures
and mineral assemblages of pseudotachylytes from mark-
edly different protoliths, improving our knowledge on
faulting in the deep crust. Our analyses have been carried
out on eight samples collected in felsic and in mafic
granulites as well as in migmatitic paragneisses and met-
amonzodiorites (Table 1). We performed detailed micro-
structural and chemical analyses with optical and SEM
microscopy as well as by X-ray maps and electron
microprobe. Pressure and temperature operating during
pseudotachylyte formation have been estimated from
microstructural evidence and from the occurrence of
peculiar minerals. This information has been used to doc-
ument the textures of deep crustal pseudotachylytes, the
relative timing between ductile and brittle deformation and
the evidence of strain localization along faults at deeper
crustal levels.
Geological setting
The Calabria Terrane represents an exotic block, mostly
consisting of Palaeozoic basement, which strongly differs
from the Southern Apennines and the Sicilian Maghre-
bides, where sedimentary rocks of Mesozoic to Cenozoic
age are widespread (Bonardi et al. 2001; Fig. 1). Fault-
related pseudotachylytes mainly occur in high-grade rocks
and mylonites at the hanging wall of a main tectonic
contact of Alpine age, separating nappes of Hercynian
basement rocks. The main metamorphism in the Calabria
basement occurred at 299–304 Ma, during the late stages
of the Hercynian orogeny (Graessner et al. 2000; Langone
et al. 2010). The present tectonic setting of the late
Hercynian high-grade rocks is related to the evolution of
the Alpine-Apenninic orogen that mainly took place in the
Cretaceous (?) late Tertiary time interval. During the
early evolutionary stages, the Calabria basement underwent
internal shortening and was thrusted above ophiolitic units
belonging to the Tethyan oceanic domain (Rossetti et al.
Contrib Mineral Petrol
123
2001). Afterwards, starting from the Oligocene time, the
Calabria basement was affected by extensional tectonics
and rapid exhumation (Thomson 1994; Grande et al. 2009),
connected to a general tilting towards the SE. This allowed
the exposure of the deeper part of the Calabria basement.
Finally, from the late Miocene onwards, the Calabria ter-
rane drifted to the SE, reaching the present position in the
Apennine chain in connection with the opening of the
Tyrrhenian Sea (Rosenbaum and Lister 2004).
In the Serre Massif, a nearly complete section of the late
Hercynian continental crust, showing an overall thickness
of 20–25 km (Schenk 1990), makes up the upper nappe of
the Alpine tectonic edifice (Fig. 1). The base mostly con-
sists of felsic and mafic granulites, grading upwards to
migmatitic metapelites, whereas in the intermediate and
upper parts thick sheets of granitoids covered by medium-
to low-grade phyllites and schists are present. In the upper
nappe, the late Hercynian fabric is generally well
Iacurso
ma
erts
a
lli
P
Girifalco
Curinga
y
e
l
laV
an
i
r
r
uT
S. Pietro
a Maida
Curinga-Girifalco Line
Bosco
Vosina
Turrina
quarry
CALAB0a
CALAB01
CALAB02
CM73
Calab03
Calab2009
Calab04
DR5
Inferred tectonic contact
Normal fault
Tectonic contact with undefined kinematics
Main thrust contact
Felsic granulites, metagabbros, mafic
granulites and peridotites (Upper Nappe)
Pliocene-pleistocene clays, sandstones
and conglomerates
Schists and orthogneisses (Intermediate
Nappe)
Phyllites (Lower Nappe)
N
1 km
Granitoids
Paleozoic
metamorphic rocks
Mesozoic to
Quaternary rocks
Sila
Tyrrhenian
sea
Ionian sea
0
20
40
km
39°
17°
39°
16°
38°
S
e
r
r
e
Aspromonte
17°
Curinga
N
16° E 18’
16° E 20’
16° E 22’
16° E 24’
38° N 49’
30”
38° N 50’
38° N 50’
30”
38° N 51’
38° N 51’
30”
Fig. 1 a Schematic geology of the Calabria Terrane; inset shows the
location of the Calabria Terrane in the Apennine-Maghrebian chain.
b Simplified geological map of the Curinga-Girifalco area. Modified
following Paglionico and Piccarreta (1976), Langone et al. (2006) and
Altenberger et al. (2011)
Table 1 Sample description (opaques: iron sulphides and other not clearly identifiable opaque phases)
Host rock Pseudotachylyte
Sample Rock type Composition Microlites
Calab 2009 Felsic granulite Kfs (20), Pl (20), Qtz (30), Grt (10), Sil (10), Bt (10), Rt Kfs, Pl, Qtz, Grt, Sil, Bt, opaques
Calab 0a Migmatitic paragneiss,
layered
Kfs (30), Pl (10), Qtz (20), Bt (10), Grt (10), Rt Pl, Bt, Sil, Qtz Grt, Rt, opaques
Calab 01 Migmatitic paragneiss,
layered
Light layers: Kfs (25), Qtz (70), Bt (5); dark layers: Bt (35),
Sil (30) Grt (10), Pl (15), Qtz (10), Rt
Pl, Bt, Sil, Qtz, Grt, Rt, opaques
Calab 02 Migmatitic paragneiss,
layered
Light layers: Kfs (20), Qtz (75), Bt (5); dark layers: Bt (35),
Sil (35) Grt (10), Pl (10), Qtz (10), Rt
Pl, Bt, Sil, Qtz, Grt, Rt, opaques
Calab 03 Metamonzodiorite Pl (antiperthitic, 40), Opx (30), Kfs (perthitic, 30), opaques Opx, Pl, Kfs, Rt, opaques
Calab 04 Mafic granulite Pl (50), Cpx (20), Hbl (brown, 20), Opx (10), opaques Cpx, Opx, Pl, Grt, Rt (?), opaques
CM73 Mafic granulite Pl (50), Cpx (20), Hbl (brown,15), Opx (15), opaques Cpx, Pl, Grt, Rt (?), Ilm, opaques
DR 5 Felsic granulite Kfs (25), Pl (20), Qtz (30), Grt (10), Bt (10), Opx (5), opaques Kfs, Pl, Qtz (?), Grt, Bt, opaques
Mineral abbreviations according to Kretz (1983). Sample Calab 2009 following Altenberger et al. (2011). Numbers in brackets are roughly
estimated volume % of the major constituents
Contrib Mineral Petrol
123
preserved. Altenberger and Kruhl (2000) document the
presence of a high-temperature shear zone (about 800 °C/
700 MPa) within granulite-facies metapelites, connected to
top-to-the-NW shearing during the Hercynian orogeny.
The upper nappe is located above an intermediate and a
lower nappe consisting of medium- to low-grade Hercynian
basement rocks, respectively. Nappe stacking has been
referred to the Alpine orogeny (Amodio-Morelli et al.
1976; Langone et al. 2006). The main tectonic contact
separating the upper and the intermediate nappe has been
identified as the Curinga-Girifalco line (Schenk 1980;
Fig. 1). It represents the tectonic contact between high-
grade hanging wall rocks and medium-grade footwall
rocks, mostly consisting of orthogneisses and schists. In the
eastern part of the area (Girifalco area; Fig. 1), normal
faulting of Oligocene-early Miocene age (15–30 Ma)
reworked the Curinga-Girifalco line under brittle condi-
tions (Thomson 1998; Langone et al. 2006). However, an
older deformation history, probably related to Alpine
thrusting, can be recognized both in the footwall and in the
hanging wall rocks (Spiegel 2003; Langone et al. 2006). In
the footwall block, thick layers of mylonites are mainly
derived from granitoid orthogneisses. The only age deter-
mination of these mylonites provided by Rb–Sr method on
biotites suggests an age of about 43 ± 1 Ma (Schenk
1980). This determination is in agreement with other
Alpine Ar/Ar ages obtained in different portions of the
Calabria basement (Heymes et al. 2010). Thermobaro-
metric estimates indicate that these mylonites formed at
relatively high pressures (0.75–0.9 GPa), within the epi-
dote–amphibolite facies (Langone et al. 2006). Within the
hanging wall, deformation is partitioned into a 100–150-m
thick belt of mylonites, ultramylonites and pseudotachy-
lytes in the migmatitic paragneisses. This is particularly
evident in the Bosco Vosina outcrop (Fig. 1), where
pseudotachylytes form some centimetre-thick veins nearly
parallel or at low angle with the mylonitic foliation. Here,
the generation surfaces are difficult to identify, since they
are almost parallel to the foliation of the mylonites/ultra-
mylonites. Locally, some injection veins or pull-apart
structures cutting the foliation of the host ultramylonite can
be observed. No data on the age of deformation have been
obtained from these rocks up to now; however, they are
generally referred to as the mylonites of the Curinga-Gi-
rifalco line (Spiegel 2003).
Mylonites in both the hanging wall and the footwall
show SE- to SSE-plunging stretching lineations on a
shallow-dipping foliation. This is also evident in the Bosco
Vosina outcrop (Fig. 2a), where kinematic indicators in
mylonites and ultramylonites are mostly consistent with
SE-directed shearing (Langone et al. 2006). This shear
sense, probably related to Alpine thrusting, now shows an
apparent normal movement after Oligocene tilting of the
whole Calabria basement (Thomson 1994).
In the western part of the area (Curinga area; Fig. 1), the
Curinga-Girifalco line is interrupted by a younger
N-trending fault. Here, the high-grade basement consists of
felsic granulites containing bodies of granulite-facies
metagabbros, fine-grained spinel peridotites and granulites
with a monzodioritic or dioritic composition. Layering of
high-grade rocks dips mostly to the S or SW with variable
dip angles. In the main outcrop located in the Turrina
quarry (Fig. 1), granulite-facies metagabbros form a huge
body within felsic granulites.
In the Curinga area, pseudotachylyte veins and patches
developed in decimetre-thick ultramylonite bands
(Fig. 2a), occurring mostly within felsic granulites. Pseu-
dotachylytes may form either foliation parallel millimetre-
thick veins (Fig. 2b), or millimetre- to centimetre-thick
injection veins crosscutting the mylonitic foliation. Orien-
tations of foliation and lineation in ultramylonite bands can
be compared with those measured in the mylonites of the
Girifalco area (Fig. 2b). Lineations, occurring on SSE
dipping foliation planes, mostly plunge towards N140°-
N160°.
In mafic and felsic granulite-facies rocks, pseudotachy-
lyte-bearing faults can also be observed. Fault planes dip
mostly towards the S-SE with variable inclinations
(Fig. 2c). Lineations have been rarely observed on fault
planes; normally, they plunge towards the S or SE. Kine-
matics has been detected in rare cases from the presence of
about 2 cm wide and 1-cm thick pull-apart structures; they
mostly point to top to the S-SE-directed faulting, that
appear extensional in the present-day attitude. Fault planes
are nearly parallel or intersect at low angles to the layering
of the granulites that dip towards the S and SW (Fig. 2d).
Analytical methods
Concentrations of major and some minor elements in
minerals were analysed with wavelength dispersive spec-
trometry using a Jeol JXA 8200 electron microprobe.
Acceleration voltage of 15 kV and a beam current of
20 nA for quantitative analyses and 35 nA for element
maps have been used. Backscattered electron images and
areal bulk composition analyses of the pseudotachylyte
matrix were obtained with an SEM JEOL JSM-6510
combined with an Oxford Instruments Incax-act analytical
EDX system in Potsdam and with a Philips XL-30 ESEM
in Potenza. Mineral detection like sillimanite in the fine-
grained pseudotachylyte matrix and in ultramylonites has
been confirmed by means of X-ray diffraction (XRD) with
a Siemens D 5005 X-ray diffractometer.
Contrib Mineral Petrol
123
Petrography of the protoliths of the pseudotachylytes
Lower crustal protoliths of the studied fault rocks show
significant variations in composition and mineral assem-
blage, as summarized in Table 1. We have selected
different protoliths in order to investigate how lithology
controls the pseudotachylyte composition and textures.
In the eastern part of the area (Girifalco, Figs. 1, 3a,b,
Table 2), pseudotachylytes and ultramylonites formed
mostly within migmatitic paragneisses, showing a late
N=59
N=63
N=27
N=29
N
N
NN
A
B
C
D
Fig. 2 Equal area projection
(lower hemisphere) of structural
data obtained in the Curinga-
Girifalco area. In diagrams A, B
and D, poles to the foliation
planes have been represented
with filled circles and related
contour lines (1 % area contour;
contour intervals = 2.0/1 %
area). a Poles to the foliation
planes and stretching lineations
(filled triangles)of
ultramylonites from the eastern
part of the area (Girifalco).
b Poles to the foliation planes
and stretching lineations (filled
triangles) of ultramylonites
from the western part of the area
(Curinga). c Fault planes (great
circle) and related slickenside
striations (filled circles). d Poles
to the high-temperature layering
of the granulites from the
Curinga area
Fig. 3 a Pseudotachylyte patches and veins (Girifalco) c clast. b Contact of pseudotachylyte and ultramylonite, hand specimen (Girifalco).
Foliation is indicated by white lines
Contrib Mineral Petrol
123
Hercynian mineral assemblage consisting of quartz ?
garnet ? sillimanite ? biotite ± K-feldspar and ± pla-
gioclase, developed under upper amphibolite- to granulite-
facies conditions. A relict banded fabric formed by alter-
nating quartz-feldspar-rich and biotite-sillimanite-rich
layers is preserved in the less deformed portions (Table 1).
The ultramylonites reveal s-c fabrics in the classical sense
of Berthe
´
et al. (1979). They are formed preferentially in
the sillimanite—and biotite—rich layers, but occur also in
quartz-rich layers as thin bands of dynamically recrystal-
lized grains. The pseudotachylytes preferentially formed
parallel or subparallel to the c planes and intruded into the s
planes (Fig. 4a).
In the western part of the area (Curinga, Fig. 1,
Table 2), pseudotachylytes formed within different types
of granulite-facies rocks of mafic, intermediate and felsic
composition. Among them, metagabbros are medium
to coarse-grained rocks consisting of plagioclase ? ortho-
pyroxene ? clinopyroxene ± amphibole ± garnet. They
show alternating pyroxene or amphibole-rich and plagio-
clase-rich levels, interpreted as reflecting a primary mag-
matic layering (Moresi et al. 1979). Towards the contact
with the felsic granulites, mafic rocks show garnet por-
phyroblasts almost replaced by spectacular radial sim-
plectites, composed of orthopyroxene ? amphibole ?
plagioclase (Acquafredda et al. 2008). Locally, this rock
type grades to intermediate- to fine-grained granulites with
a monzodioritic composition, consisting of plagioclase ?
K-feldspar ? orthopyroxene ± clinopyroxene ± amphibole.
In the mafic granulites from Curinga outcrop (Fig. 1),
small-scale ductile shear zones show grain-size reduction
by dynamic recrystallization of clinopyroxene and plagio-
clase, pointing out to minimum temperatures of about
600 °C (Kruhl and Huntemann 1991; Passchier and Trouw
1996). In the studied sample, a ductile shear zone is
crosscut at low angle by a pseudotachylyte vein.
Felsic granulites make up most of the high-grade base-
ment. The most common rock type consists of quartz ?
K-feldspar ? plagioclase ? garnet ? sillimanite ± biotite
with accessory zircon and rutile. They show a banded
fabric, outlined by alternating garnet-sillimanite-rich and
feldspar-rich layers. More rarely, orthopyroxene-bearing
and sillimanite-free granulites also occur. Shear zones
mostly consist of ultramylonites characterized by syntec-
tonic sillimanite and dynamic recrystallization of quartz,
biotite and feldspar.
According to Schenk (1984), maximum pressures
recorded by the mafic granulites are about 0.75 GPa, at
temperatures of 800 °C. More recent analyses carried out
by Acquafredda et al. (2008) on mafic granulites from the
Turrina quarry resulted in significant higher P–T conditions
of 1.1 GPa and 900 °C, respectively. The presence of
corona textures around garnet allowed to reconstruct the
retrograde path that shows decompression and cooling up
to pressure conditions of 0.7–0.8 GPa and temperatures of
750–650 ° C.
Microstructures of pseudotachylytes
Rock fragments in pseudotachylyte veins
The pseudotachylyte veins contain clasts of the host rock in
different size, quantities and composition. Monomineralic
as well as polymineralic clasts occur. The size of the clasts
is mostly smaller than 1 cm and correlates positively with
the thickness of the pseudotachylyte and often with the
distance to the pseudotachylyte margin (Fig. 4b). In one
case, a folded or fold-shaped rock fragment occurs
(Fig. 4c). This clast shows internal s-c fabric, probably
preserved from the ultramylonitic country rock and con-
tains stretched quartz grains in the outer part.
In another sample, a quartz-dominated clast is dis-
membered by a pseudotachylyte vein network arranged
into an s-c-like fabric (Fig. 4d, e). Within the pseudot-
achylyte vein, a disrupted quartz sigma clast, enclosed
within a biotite-rich matrix, occurs (Fig. 4f). These
important microstructures will be used to interpret the
relative timing and the formation mechanisms of pseudot-
achylytes in the Calabria lower crust. Few veins have small
zones at the margin to the country rock in which cataclastic
deformation prevails.
In felsic granulites and migmatitic paragneisses, the
pseudotachylytes show a dominance of quartz and silli-
manite clasts as well as rock fragments composed of
quartz, sillimanite and plagioclase (Fig. 5a, b). Monomi-
neralic plagioclase has a limited grain size between 450
and 500 lm. Grains smaller than 450 lm are very rare or
missing. K-feldspar rarely survived frictional melting.
Clasts of biotite, which is a prominent phase in the country
rocks, and opaques are not commonly preserved.
Table 2 Geographical coordinates of the studied samples
Sample no. Coordinates
Calab 2009 38°49
0
22
00
16°18
0
33
00
Calab 0a 38°49
0
11
00
16°24
0
09
00
Calab 01 38°49
0
10
00
16°24
0
09
00
Calab 02 38°49
0
09
00
16°24
0
08
00
Calab 03 38°49
0
22
00
16°17
0
51
00
Calab 04 38°50
0
34
00
16°19
0
02
00
CM73 38°50
0
34
00
16°19
0
02
00
Dr5 38°49
0
21
00
16°17
0
43
00
Contrib Mineral Petrol
123
Quartz fragments are rounded, elongate to lens shaped
and range in sizes from a few lm to 500 lm, rarely up to
1,000 lm. Few grains show euhedral to subhedral shapes,
due to a probable later overgrowth in the pseudotachylyte
melt (Fig. 4a). The minerals often show evidence of
internal deformation like subgrains and dynamically re-
crystallized grains, comparable to those of the country rock
nearby. Two generations of dynamically recrystallized
grains of significantly different grain size are preserved in
clasts and in the wall rock adjacent to the pseudotachylyte
Fig. 4 a s-c fabrics, shown by quartz, biotite and garnet with thin
pseudotachylyte (white line, pseudotachylyte proven by SEM anal-
ysis) parallel to the c plane. Sample Calab 02, migmatitic paragneiss.
b Chilled margin at the border of a pseudotachylyte vein at the border
with an ultramylonite. Size of clasts increases discontinuously
towards the centre of the pseudotachylyte vein, to the left of the
figure. c Folded rock clast of ultramylonite from migmatitic
paragneisses with internal s-c fabric (thick arrow) enclosed in a
pseudotachylyte; at the clast margin and in the matrix lens-shaped
quartz clasts also occur (thin arrows). d s-c-like structure in a quartz-
bearing rock clast in pseudotachylyte matrix. Arrow points to fine-
grained recrystallized quartz. Migmatitic paragneisses. e Backscat-
tered image (BSE) of the s-c-like structure of c. Square refers to
Fig. 4f). Disrupted sigma clast of quartz in pseudotachylyte matrix
(see box in e). Spaces are filled by biotite (light, arrow). At the top
tree-like garnet, microlites are clearly visible. Photomicrographs with
crossed nicols: ad; backscattered SEM image (BSE): ef
Contrib Mineral Petrol
123
Contrib Mineral Petrol
123
(Fig. 5c). The very fine grains of the second generation,
often affecting the first generation grains, are up to
5–10 lm in size. Some larger quartz grains show fractures
and open cracks filled by pseudotachylyte containing
rounded quartz fragments embedded in a matrix enriched
in biotite or in biotite-plagioclase (Fig. 4d,e,f).
Monomineralic sillimanite clasts reach sizes of up to
200 lm, although clasts with a size smaller than 5 lm are
more frequent, as shown by SEM analyses. Some crystals
show embayed grain boundaries, which are typical for
clast-melt reaction (Fig. 5a,b).
Scarce monomineralic garnet clasts occur in the felsic
pseudotachylytes. The presence of subhedral and fractured
monazite suggests that this mineral underwent only brittle
deformation without melting during pseudotachylyte
formation.
In pseudotachylytes formed in mafic wall rocks, clasts
are dominated by plagioclase, orthopyroxene and minor
hornblende. Plagioclase shows rough bimodal grain-size
distributions with clasts smaller than 40 lm and clasts
around 400 lm. In mafic granulites, where ductile shear
zone is crosscut at low angle by a pseudotachylyte vein,
clasts of plagioclase and clinopyroxene show dynamic re-
crystallized grains of the same size as those occurring in
the shear zone (Fig. 5e,f). On the other hand, rare clasts
composed of recrystallized hornblende do not have an
equivalent in the wall rock of the pseudotachylyte.
Summarizing, embayed grain boundaries in clasts of
sillimanite and quartz and the lack of biotite clasts indicate
that these minerals were involved in melting processes.
Matrix and newly crystallized phases
This section provides the petrological and textural evidence
for a melt origin of the pseudotachylytes. Detailed
descriptions of newly formed phases are necessary for the
interpretation of the veins in terms of pressure (i.e. for-
mation depth), temperature and fluid composition during
melt generation and cooling.
Most samples are fully crystallized with no evidence of
preserved glass, even though the grain size is often at the
limit of high resolution of the used SEM (ca. 0.5 lm). As
pointed out by Altenberger et al. (2011), optically isotropic
spheres, composed of fine-grained Ca–Na-rich and K–Mg–
Fe-rich phases, may occur in the chilled margin of injection
veins in felsic rocks of the study area. There, biotite-rich
zones often transect these spheres. All pseudotachylytes
show chilled margins, where the mean grain size of the
microlites is reduced to up to one-tenth of the size in the
vein centre (Fig. 4b). Matrix and newly crystallized phases
in pseudotachylytes formed in different protoliths show
significant variations in composition and fabric. The
pseudotachylyte veins often show zoning by fabric and
composition. Some pseudotachylytes show obvious com-
positional layering and folds formed by flow processes
(Fig. 6a).
All minerals forming the granulite-facies country rocks
are also present as newly crystallized phases in the pseu-
dotachylyte, except monazite, zircon and hornblende. In
one domain of the mafic pseudotachylyte, irregular cloud-
like mineral aggregates formed by clinopyroxene and pla-
gioclase (± opaques) can be observed (Fig. 6b.). They do
not represent pseudomorphs since they are in direct contact
with typically rounded clasts, mainly consisting of
hornblende.
Orthopyroxene
In a pseudotachylyte in mafic host rocks, new orthopy-
roxene was generated (Fig. 6c,d). Orthopyroxene is up to
20 or 50 lm long and 3 lm thick. Growth often starts near
orthopyroxene clasts and show needle- or feather-shaped
grains radiating around the clast. However, in most cases,
there is no direct contact to the clast. More fine-grained
orthopyroxene shows skeletal growth (Fig. 6d). Domains
of clasts with surrounding needle- and feather-shaped
orthopyroxene alternate with domains of skeletal growth
with subordinate single orthopyroxene needles embedded
in a rim of plagioclase. The shapes of new orthopyroxene
are typical for rapid cooling. These features are very sim-
ilar to the clinopyroxenes described by Austrheim and
Andersen (2004) in subduction-related pseudotachylytes
from Corsica.
Sillimanite
Newly generated sillimanite, in pseudotachylyte of felsic
host rocks, forms small needles with length between 3 and
Fig. 5 Images A to D have been obtained in pseudotachylytes in
migmatitic paragneisses. a Element maps of a pseudotachylyte with
anhedral and subhedral sillimanite (Sil) and quartz (Qtz) reflecting
mineral growth in the melt by straight grain boundaries (arrows).
Quartz shows also small corrosion (?) embayment. b Element map of
Si shows broken sillimanite, partially with embayed grain boundaries
(arrow) indicating corrosion by the melt. The BSE image below
shows biotite (Bt) between the sillimanite clasts (light). c Quartz-rich
layer in the host rock with two generations of recrystallized quartz.
Black arrows indicate very fine-grained recrystallized grains. The
distance to the pseudotachylyte is ca. 0.25 mm (direction indicated by
white arrow). Sample Calab 03, migmatitic paragneisses. d BSE
image and element maps of Ca and Ti of cauliflower garnet, showing
straight grain boundaries on the right (arrow) and clear Ca zoning. Ti-
rich inclusions (rutile) are preferentially concentrated in the inner
parts of the grain. e Dynamic recrystallization of clinopyroxene (Cpx)
and plagioclase in the wall rock at the margin to a pseudotachylyte
(dark) from a mafic protolith. f Clast with dynamically recrystallized
plagioclase and clinopyroxene in the pseudotachylyte of Fig. 4e. a
d Electron microprobe element maps and BSE images; c,e,f photo-
micrographs with crossed nicols
b
Contrib Mineral Petrol
123
5 lm often containing tiny inclusions of probable quartz
(Fig. 7a). Sillimanite as the Al
2
SiO
5
phase has been proven
by XRD. Some significant nearly euhedral larger grains are
probably due to the overgrowth of sillimanite clasts
(Fig. 4a). Sillimanite needles show no obvious preferred
shape orientation. In some samples, they occur as tiny
euhedral inclusions in newly formed garnet.
Garnet
Garnet is present in all pseudotachylytes from felsic
protoliths and in some pseudotachylytes from mafic pro-
toliths. It reaches sizes of up to 50 lm. Most grains show
cauliflower, fern- or tree-like and euhedral shapes (Fig.
4f). Some garnets show the clear development of crys-
tallographically controlled surfaces in parts of the cauli-
flower-shaped grains (Fig. 5D). This phenomenon is
primarily present in the central parts of the veins, whereas
in injection veins or ‘melt’’-filled intra-crystalline cracks,
garnet shows simple cauliflower- or fern-like shapes
(Fig. 4f). The grain size of garnet increases from chilled
margins to the centre of the veins. This indicates that
garnet grew directly from a melt, as described earlier by
Altenberger et al. (2011). In some garnets, inclusions of
different compositions can be observed. The cores show
either no inclusions or probable tiny biotites or rutiles
(Fig. 7b), whereas the volume-dominating rim encloses
quartz, sulphide droplets or sillimanite clasts (Fig. 7b).
This probably indicates either an older core, originated
from a clast, surrounded by garnet crystallization from the
melt or a cauliflower-shaped garnet with a younger
metamorphic overgrowth.
In addition, in some samples, garnet cores have slightly
lower Ca concentrations compared to the cauliflower-
shaped outer rims. The Ca concentration of the cores lies
between host rock garnet composition and rim (Fig. 5d,
Table 4). This is another, albeit weak, indication that clasts
act as a nuclei.
Fig. 6 a Element map of Mg shows flow fold in a pseudotachylyte.
Dark layers plagioclase rich; light clinopyroxene-rich layers. This
shows a heterogeneous melt that was being mingled by stretching and
folding. Mafic wall rock (sample CM73). b Light domain composed
of very fine-grained clinopyroxene-dominated clinopyroxene-plagio-
clase intergrowth in a matrix of plagioclase-dominated
clinopyroxene-plagioclase intergrowth (CM73, see Table 4). c Euhe-
dral and skeletal orthopyroxene microlites, partially nucleating at
orthopyroxene clast. Orthopyroxene is embedded in plagioclase
(dark) (sample) C73). d Skeletal growth of orthopyroxene microlites
(sample Calab 04, mafic granulite). ad BSE images
Contrib Mineral Petrol
123
Quartz
Although quartz is the dominant clast in pseudotachylytes of
quartz-bearing host rocks, there is also evidence of the
growth of new quartz. In some samples, quartz clearly shows
the generation of new faces at clasts that are in part fractured
or melted (Fig. 5a). In other samples, quartz nucleates on
sillimanite clasts, or forms tiny euhedral needles.
Fig. 7 a Growth of new sillimanite laths with tiny plagioclase
inclusions and biotite (light) around quartz (dark). Sample Calab 0a,
migmatitic paragneiss. b Cauliflower-like garnet, with inclusion-poor
core. Rim with plagioclase and iron-sulphide (light) inclusions.
Sample Calab 0a, migmatitic paragneiss. c Clinopyroxene-plagioclase
matrix (neoliths) with rounded hornblende clast (Hbl); pseudotachy-
lyte in a mafic wall rock. Sample Calab 04, mafic granulite. d Oblique
foliations indicated by the preferred orientation of biotite in a
pseudotachylyte. Note biotite in the pressure shadow of plagioclase
clast (arrow). Sample DR 5, felsic granulite. e Growth of skeletal
ilmenite (light) near to large ilmenite grain. Margin of pseudotachy-
lyte. Sample CM73, mafic granulite. f Oblique foliations (//white
line). Sample C73. ae BSE images; f photomicrograph
Contrib Mineral Petrol
123
Hornblende
Although in some mafic samples the wall rocks either
contain significant amounts of hornblende or hornblende
could be present as small clasts in the pseudotachylyte
(Fig. 7c), there is a lack of amphibole microlites.
Clinopyroxene
Newly crystallized clinopyroxene microlites are restricted
to the mafic pseudotachylytes. They occur as anhedral to
lath-shaped intergrowth with plagioclase in the matrix of
the pseudotachylyte (Fig. 7c). The grain size is smaller
than 8 lm. In addition, clinopyroxene is an essential
component of the irregular cloud-like plagioclase-clin-
opyroxene domains (Fig. 6b).
Feldspars
Plagioclase often forms the fine-grained matrix of the
pseudotachylytes, together with biotite or clinopyroxene. It
occurs as an anhedral to rarely euhedral crystal in the mafic
pseudotachylytes and as subhedral to euhedral laths in the
felsic types. Grain size is always below 10 lm. It is
noteworthy that newly formed orthopyroxene is always
rimmed or embedded in newly formed plagioclase.
K-feldspar occurs as fine-grained intergrowth with pla-
gioclase and biotite in pseudotachylytes from meta-mon-
zodioritic rocks. Grain size of the anhedral crystals is
mostly below 5 lm.
Biotite
Newly formed biotite is present in all pseudotachylytes
from felsic protoliths. Often it crystallized in pressure
shadows of quartz clasts. In addition, biotite fills the space
between broken and dismembered parts of clasts (Figs. 4f,
5b). In the case of the monzodioritic sample, biotite is part
of the intimate intergrowth in the matrix. In one sample,
the preferred orientation of biotite microlites defines a
strong fabric oblique to the vein margin (Fig. 7d) indicat-
ing plastic creep after pseudotachylyte generation.
Opaques
In some mafic rocks, new fern-shaped ilmenite crystallized
only very near and along the margin of pseudotachylytes
(Fig. 7e). Iron-sulphide droplets occur frequently in the
matrix or as inclusions in newly formed minerals (Fig. 7b).
In addition, anhedral rutile or magnetite is often included
in newly formed garnet (Fig. 5d).
Table 3 Composition of different domains in the pseudotachylyte matrix
Sample Calab 04 Calab 03 Calab 02 Calab 01
Rock type Mafic granulite Metamonzodiorite Migmatitic paragneiss Migmatitic paragneiss
Domain Protolith Pst; Matrix,
homogeneous
Cloudy, light
domain
Dark
domain
Protolith;
ultramylonitic
Matrix,
centre
Chilled
margin
Protolith;
ultramylonitic
Pst;
matrix
Protolith;
ultramylonitic
Pst;
matrix
Pst; matrix around
Grt microlite
wt %
SiO
2
53.80 53.02 53.14 53.6 56.96 58.76 58.83 75.96 62.82 73.36 62.12 62.82
TiO
2
0.26 1.45 1 1.71 1.67 1.93 1.94 0.89 1.41 0.17 1.32 1.19
Al
2
O
3
19.50 16.68 16.07 17.47 17.59 15.24 14.33 13.16 21.03 14.45 20.6 21.33
FeO 4.42 7.65 8.32 7.53 8.34 9.7 8.96 4.46 8.18 4.24 7.19 7.04
MgO 8.98 8.7 8.84 7.01 5.14 6.19 6.89 2.07 2.74 2.03 2.66 2.26
MnO u.d.l. 0.33 0.2 0.42 u.d.l. u.d.l. u.d.l. u.d.l. u.d.l. u.d.l. u.d.l. u.d.l.
CaO 9.91 10.53 10.61 10.6 4.72 3.2 3.62 0.97 0.2 1.01 0.64 0.74
NaO 3.49 1.55 1.58 1.97 4.79 3.37 3.54 1.2 0.8 2.38 2.1 2.13
K
2
O 0.20 0.09 0.11 0.15 0.9 1.61 1.88 1.3 3.07 2.62 3.59 3.03
pst pseudotachylyte, u.d.l. under detection limit
Contrib Mineral Petrol
123
Apatite
A band of multiple apatite grains is formed at a clast
margin in the pseudotachylyte of the mafic granulite sam-
ple. Apatite grains contain inclusions of tiny clinopyroxene
and plagioclase, proving the direct crystallization from the
pseudotachylyte melt.
Mineral and bulk chemistry of pseudotachylytes
Pseudotachylytes in quartz-bearing wall rocks have a
matrix composition, in the range of an andesite, that is,
significantly more basic than the protoliths (sample Calab
01 and 02, Table 3). This shift is due to the relative
enrichment of quartz in the clast fraction, pointing to dis-
equilibrium melting. In contrast, pseudotachylytes in mafic
and monzodioritic protoliths do not show a significant
difference in SiO
2
concentration with respect to the host
rocks, due to the absence of melt-resistant phases like
quartz. However, in these samples, a decrease in Al
2
O
3
and
a slight increase in Fe
2
O
3
and MgO point to a preferential
melting of hornblende (sample Calab 03) and/or orthopy-
roxene (sample 04, Table 3).
The analyses of the cloudy domains in the mafic pseu-
dotachylyte show a composition enriched in MgO and FeO
and depleted in Na
2
O in comparison to the surrounding
matrix (Calab 04, Table 3, Fig. 6b). This could be explained
by the higher amount of clinopyroxene and lower concen-
tration in plagioclase. However, these different domains are
probable indicators of two different portions of frictional
melts that in some places remained unmixed. Some biotite-
rich matrix layers indicate melts of near biotite composition,
reflecting previous non-equilibrium melting.
Table 4 Composition of garnet
Garnet
Calab 2009* Calab 0a Calab
01
Calab
02
Calab 04 Calab Dr5
Host rock Pseudotachylyte Host
rock
Pseudotachylyte Pst Pst Central
vein,
Chilled
margin
Pst Pst
Core Rim Core Rim Core Core Rim Core Core Core Core Core Rim
wt %
SiO
2
37.86 38.08 37.60 37.46 38.49 36.93 36.96 37.18 37.14 39.43 38.91 37.69 37.80
TiO
2
0.03 0.09 0.06 0.03 u.d.l. 0.32 0.58 0.09 0.58 0.05 0.09 0.04 0.23
Al
2
O
3
22.39 21.96 22.12 22.08 21.17 21.35 21.67 21.59 21.92 22.15 22.07 21.97 21.48
FeO 31.70 31.61 34.11 33.81 33.82 34.71 33.57 35.13 33.41 25.44 25.17 30.71 31.48
MgO 6.76 6.95 4.82 5.10 2.83 2.19 2.04 1.94 2.22 5.73 5.64 4.82 5.01
MnO 0.87 0.76 1.12 1.08 2.13 2.79 2.75 2.27 2.41 1.50 1.95 1.12 1.08
CaO 1.62 1.59 1.29 1.51 1.13 2.05 2.65 1.84 2.41 7.15 6.74 3.31 2.47
Sum 101.24 101.05 101.13 101.08 99.57 100.34 100.28 100.12 100.09 100.12 100.12 99.65 99.55
Cations
Si 5.85 5.91 5.91 5.88 6.16 5.95 5.94 5.99 5.95 6.03 6.01 6.06 6.10
Al 4.08 4.02 4.10 4.09 3.99 4.05 4.10 4.10 4.14 3.99 4.02 4.16 4.09
Fe
2?
3.91 3.94 4.42 4.29 4.53 4.68 4.51 4.74 4.47 3.25 3.25 4.13 4.25
Fe
3?
0.23 0.17 0.07 0.15 \0.1 \0.1 \0.1 \0.1 \0.1 \0.1 \0.1 \0.1 \0.1
Mn 0.11 0.10 0.15 0.14 0.29 0.38 0.37 0.31 0.33 0.19 0.26 0.66 0.68
Mg 1.56 1.61 1.13 1.20 0.68 0.53 0.49 0.46 0.53 1.31 1.30 0.27 0.26
Ca 0.27 0.27 0.22 0.25 0.19 0.35 0.46 0.32 0.41 1.17 1.12 0.57 0.43
Fe
2?/
Mg 2.51 2.45 3.90 3.59 6.70 8.88 9.24 10.19 8.44 2.49 2.50 15.33 16.29
mol %
Almandine 65.91 66.61 74.67 72.93 79.63 78.76 77.39 77.39 77.89 54.90 54.91 73.42 75.59
Pyrope 26.26 27.21 19.12 20.32 11.88 8.86 8.37 8.37 9.22 22.04 21.94 4.79 4.64
Grossular 0.00 0.27 1.89 0.49 5.08 6.41 6.41 6.41 5.69 19.73 18.85 10.02 7.45
Spessartine 1.92 1.69 2.52 2.43 3.41 5.97 7.83 7.83 7.04 3.28 4.31 11.66 12.18
Andradite 5.95 4.21 1.80 3.83 0.06 0.06 0.06 0.16 0.14 0.04 0.04 0.10 0.10
pst pseudotachylyte, u.d.l. under detection limit
* Following Altenberger et al. (2011)
Contrib Mineral Petrol
123
Newly formed garnets are FeO and MgO rich (Table 4).
In the pseudotachylytes, garnets are richer in FeO com-
pared to the wall rocks (Calab 2009, Calab 02, Calab 01,
Calab 04, Dr5). In the migmatites and felsic granulites, the
almandine concentration reaches up to 80 mol %, whereas
in the mafic sample almandine reaches only 55 mol %.
These differences are probably influenced by the host rock
composition. Garnet shows in some parts an outer, some-
times euhedral, rim, generally characterized by a higher Ca
content (Table 4, Fig. 5d).
The newly formed orthopyroxenes show high-alumina
concentrations with up to 8 wt % Al
2
O
3
(Table 5). Their
composition is significantly different compared to the low-
alumina orthopyroxenes of the granulite-facies wall rocks
and clasts.
It seems worth mentioning that biotite shows always
lower TiO
2
concentration in the pseudotachylyte compared
to the wall rocks (Table 6). Generally, TiO
2
is a rough
temperature-sensitive indicator. The temperature-sensitive
anorthite (CaO) concentration of plagioclase is higher in
the pseudotachylytes than in the host rock, pointing to
higher temperatures (Table 6).
Relative timing and PT conditions of frictional
melting during deep crustal faulting
PT conditions of frictional melting during deep crustal
faulting
There are several attempts to define the temperature and
pressure during melt generation. Frictional melting is
described as non-eutectic (e.g. Spray 1992). Therefore, the
melt composition, as displayed by the matrix of the
Table 5 Composition of pyroxenes
Orthopyroxene Clinopyroxene
Calab 03 Calab 04
Host rock Clast in pst Microlites pst Microlites pst
Core* Core Core Rim Core Core Core* Core* Core*
wt %
SiO
2
54.17 53.63 47.27 47.74 48.66 48.84 54.73 55.70 56.00
TiO
2
0.09 0.72 0.72 0.92 0.69 u.d.l. 0.13 u.d.l.
Al
2
O
3
1.58 1.94 7.76 7.84 6.76 5.40 4.73 1.24 2.16
FeO 20.92 19.87 25.79 26.05 24.88 26.29 6.01 5.99 5.23
MnO 0.36 0.53 0.54 0.53 0.60 u.d.l. u.d.l. 0.18
MgO 23.33 23.97 17.51 17.69 16.36 17.44 13.54 15.20 14.87
CaO 0.75 0.33 0.34 0.93 0.56 20.99 21.32 21.02
Na
2
O 0.11 0.02 0.02 0.40 0.11 u.d.l. 0.42 0.41
Cr
2
O
3
u.d.l. 0.01 0.01 u.d.l. u.d.l. u.d.l. u.d.l. u.d.l.
Sum 100.72 99.95 100.95 99.44 99.92 100.00 100.00 100.00
Cations
Si 1.95 1.95 1.81 1.80 1.84 1.86 1.98 2.03 2.03
Ti 0.01 0.00 0.03 0.03 0.03 0.02 0.00 0.00 0.00
Al 0.04 0.08 0.35 0.35 0.30 0.24 0.01 0.05 0.09
Fe
3?
0.03 0.02 0.06 0.12 0.07 0.03 0.01 0.01 0.01
Fe
2?
0.52 0.59 0.69 0.62 0.72 0.80 0.17 0.17 0.15
Mg 1.21 1.30 0.92 0.91 0.92 0.99 0.73 0.82 0.80
Ca 0.03 0.05 0.05 0.04 0.02 0.81 0.83 0.82
Mn 0.01 0.02 0.02 0.02 0.02 0.00 0.00 0.01
Na 0.01 0.06 0.06 0.03 0.01 0.00 0.03 0.03
Sum 3.98 3.98 3.98 3.96 3.96 3.99 3.91 3.95 3.94
Mean pressure (GPa)** 1.2 1.2 1.0 0.9
Minimum pressure (GPa) 1.0 1.0 0.8 0.7
Maximum pressure (GPa) 1.5 1.5 1.3 1.1
pst pseudotachylyte, u.d.l. under detection limit
* Analysed with EDX, ** estimated following Longhi et al. (1993,1999)
Contrib Mineral Petrol
123
pseudotachylyte, differs from the protolith in a way not
computable by equilibrium thermodynamics. A possible
albeit rough procedure for temperature estimation is based
on the composition of consumed or newly formed minerals
(Spray 1992; Austrheim et al. 1996). Very fast non-equi-
librium melting means that individual minerals do not
interact with one another to melt in eutectic reactions but
they melt individually in the order of melting point or
breakdown temperature. The studied Calabria pseudot-
achylytes indicate the complete or partial melting of bio-
tite, orthopyroxene, quartz, garnet, amphibole, feldspars,
sillimanite and opaques.
The melting point, or ‘‘breaking point’ in particular, for
(OH)-bearing minerals is significantly lower in frictional
melts than in static melting (Spray 1992), caused by
‘disequilibrium flash melting’’ of those minerals. Based on
the studies of Spray (1992), the biotite breakdown in
pseudotachylytes is at about 650 °C. The probable highest
temperature for the presented samples is the melting of b-
quartz. Although the melting point of b-quartz is 1,750 °C,
it is well known that rapid melting reduces the melting
point up to about 1,515 °C (Petzold and Hinz 1976). High-
pressure experiments show that fluid activity can reduce
melting point to about 1,100 ° C at pressures of 0.8 GPa
(Kennedy et al. 1962). In addition, the generation of sul-
phide droplets, although rarely occurring, indicates low
O-fugacity and immiscibility of the Fe-sulphide melt with
the silicate melt, suggesting minimum temperatures of ca.
1,200 °C (Magloughlin 2005). The roughly estimated
melting points for clinopyroxene and orthopyroxene under
friction condition are around 1,400 °C (Spray 1992).
Newly formed garnet occurs in nearly all analysed
samples. The grain-size increase in garnet from chilled
margins to the centre of the veins proves the rapid crys-
tallization from a melt (e.g. Austrheim and Boundy 1994,
Altenberger et al. 2011). In some cases, garnet core dis-
plays a possible relict nucleus derived from a clast. In
addition, the generation of sulphide droplets that are typical
for pseudotachylyte melts (Magloughlin 2005) is only
present in the cauliflower-shaped parts of the garnet and is
lacking in the cores. The presence of some straight grain
boundaries in some cauliflower garnets together with their
Table 6 Composition of feldspars and biotite
Plagioclase Alkali feldspar Biotite
Calab 04 Calab 02 Calab 03 Calab 04 Calab 03 Calab 2009** Calab 02
Host rock Pst Pst Pst Pst Pst Pst Host rock Pst Ultramylonite Pst
Core* Core Core* Core Core Core Core* Core Core Core** Core
wt % wt %
SiO
2
56.74 55.26 56.70 62.97 60.96 64.74 65.91 SiO
2
37.71 38.56 37.41 37.29
Al
2
O
3
27.65 26.98 26.34 23.51 23.47 18.74 19.03 TiO
2
4.67 2.05 3.20 2.88
FeO 0.52 0.53 0.50 0.88 0.46 Al
2
O
3
17.59 20.34 19.73 18.75
CaO 10.16 11.16 12.94 5.52 5.13 1.15 1.09 FeO 13.06 15.80 18.20 18.01
Na
2
O 5.45 5.04 3.45 8.00 8.41 1.88 2.19 MgO 14.81 9.96 10.82 12.44
K
2
O 0.17 0.04 0.71 11.66 11.31 MnO 0.00 1.92 u.d.l. u.d.l.
Sum 100.00 99.14 100.00 100.00 99.18 99.05 99.99 Na
2
O 0.08 u.d.l. u.d.l. u.d.l.
Cations K
2
O 9.85 8.86 8.40 7.31
Si 2.54 2.49 2.81 2.74 2.97 2.99 Sum 97.77 97.49 97.77 96.68
Al 1.46 1.44 1.24 1.22 1.01 1.02 Cations
Fe
2?
0.02 0.02 0.03 0.02 Si 2.67 2.76 2.77 2.74
Ca 0.49 0.54 0.26 0.24 0.06 0.05 Ti 0.25 0.11 0.18 0.16
Na 0.47 0.44 0.69 0.72 0.17 0.19 Al 1.47 1.72 1.72 1.63
K 0.01 u.d.l. 0.04 0.68 0.65 Fe
?2
0.41 0.64 1.13 1.11
Mn 0.12 0.00
mol % Mg 1.56 1.06 1.20 1.36
An 50.74 54.50 67.25 27.61 23.69 6.24 5.89 Na 0.01
Ab 49.26 44.52 32.49 72.39 72.25 18.45 21.40 K 0.89 0.81 0.79 0.69
Or 0.00 0.98 0.26 0.00 4.06 75.31 72.71 Fe
3?
0.36 0.30 0.00 0.18
pst pseudotachylyte, u.d.l. under detection limit
* Analysed with EDX, ** following Altenberger et al. 2011
Contrib Mineral Petrol
123
zoning pattern may suggest a later solid state growth
(Fig. 8). The studied garnets are rich in almandine com-
ponent (FeO). Experimental studies (Green and Ringwood
1968; Eggler and Burnham 1973; Allen et al. 1975; Conrad
et al. 1988; Green 1992) as well as analyses of natural
systems (Harangi et al. 2001; Barnes and Allen 2006)
established a lower pressure stability of almandine-rich
garnet in melts of andesitic to dacitic composition. Esti-
mated pressures only weakly correlate with temperature.
These works show that igneous garnets are formed under
minimum conditions of about 0.7–0.8 GPa, assuming
moderate H
2
O activity. The pseudotachylyte matrix, rep-
resenting the former melt, shows an andesitic composition
in most of the garnet-bearing pseudotachylytes. Therefore,
we conclude that the experiments can constrain the pres-
sure of garnet crystallization. In addition, crystallization of
garnets with cauliflower habit has been hitherto described
only in pseudotachylytes formed at greater depths (Austr-
heim and Boundy 1994; Lund and Austrheim 2003; Pitta-
rello et al. 2012).
To further constrain this interpretation, we compared
pseudotachylytes from Calabria with a pseudotachylyte
found in Archean lower crustal gneiss exposed in the
Mather Peninsula, Antarctica (Altenberger, in prep.). The
pseudotachylyte formed in a very similar sillimanite-garnet
protolith in association with brittle structures. This indi-
cates that pseudotachylytes from Antarctica formed when
the gneisses were already exhumed at upper crustal levels.
In addition, no further metamorphic overprint occurs. The
pseudotachylyte vein contains biotite and plagioclase
microlites as well as sulphide droplets. However, in con-
trast with the deep-seated Calabria pseudotachylytes, gar-
net occurs as angular clasts only (Fig. 8a).
According to a very simplified sketch (Fig. 8), the
probable evolution of garnets from analysed Calabrian
pseudotachylytes starts with clasts, comparable to those of
the Antarctica (Fig. 8a), forming the nuclei of the cauli-
flower garnets (Fig. 8b), and ends with the later meta-
morphic overgrowths (Fig. 8c). In the pseudotachylytes
from Antarctica (Fig. 8a), the early fragmentation stage is
observed, whereas in Calabria the complete evolution can
be recognized.
It is well known that the solubility of aluminium in
orthopyroxene increases with increasing pressure. Pyrox-
enes with high aluminium concentration are known from
Proterozoic anorthosites formed near the base of the lower
crust (HAOM; high-alumina orthopyroxene megacrysts,
for example, Emslie 1975; Longhi et al. 1993). Experi-
mental work of Fram and Longhi (1992) and Longhi et al.
(1993, 1999) displays that the alumina content of ortho-
pyroxenes in equilibrium with plagioclase in magmatic
systems is a function of pressure and it has been empiri-
cally calibrated as a geobarometer. The crystallization of
high-alumina orthopyroxenes in the pseudotachylytes of
the metamonzodiorites and mafic granulites (samples Ca-
lab 03 and Calab 04, Table 1) may indicate high pressures,
assuming crystallization from a melt and equilibrium
conditions. The Al-rich orthopyroxenes in the present study
are embedded in plagioclase and formed in garnet-free as
well as in garnet-bearing veins. However, in the latter case,
orthopyroxene is not in contact with garnet. Using the
composition of orthopyroxene for microlites crystallized in
pseudotachylytes from meta-monzodioritic and mafic
hosts, a mean pressure of 1.08 ± 0.23 GPa can be
obtained, pointing to a mean of about 35 km and a mini-
mum crystallization depth of about 31 km (calculated with
a mean crustal density: q = 2.85 g/cm
3
, Table 5). The
presence of almandine-rich garnets in the same pseudot-
achylytes further supports the interpretation of a deep
crustal growth of high-Al orthopyroxene.
Fig. 8 Simplified sketch of the probable evolution of the garnets.
a Cataclastic destruction of garnet of the protolith forming fragments.
b Cauliflower garnets are formed by rapid crystallization from the
melt around clast nuclei. c Later high-grade metamorphic overgrowth
forming euhedral crystals. All images are BSE images. Image A is
made from a pseudotachylyte in a garnet-sillimanite gneiss of the
Mather Peninsula, Antarctica. ac BSE images
Contrib Mineral Petrol
123
However, the problem of disequilibrium phenomenon
during rapid cooling makes these depth estimates some-
what uncertain. In addition, Xue and Morse (1994) describe
Al-rich orthopyroxene (up to 5.4 wt %) from an anorthosite
in Labrador to be rather the product of rapid crystallization
than of the depth of origin. It should be noted also that
Toyoshima (1990) describes upper crustal pseudotachy-
lytes containing orthopyroxene microlites with high-alu-
mina content. Therefore, pressure estimates based on the
aluminium content in orthopyroxene, although consistent
with direct garnet crystallization from the pseudotachylyte
melt, should be taken with some caution. However, the
coexistence of Al-rich orthopyroxene and plagioclase
indicates that plagioclase crystallization, as the main alu-
minium-consuming phase, was not delayed during rapid
crystallization, as described by Longhi et al. (1993). In
addition, the Al-poor orthopyroxenes described by Lund
and Austrheim (2003) in high-pressure pseudotachylytes
from mafic protholith are formed by metamorphic reactions
after olivine clasts and within the matrix.
According to the nearly anhydrous mineral assemblage
of the pseudotachylyte formed within a mafic protolith, we
could indicate that seismic events led to dehydration in a
water-deficient environment. The presence of newly
formed biotite in the felsic pseudotachylytes may be
derived from the water extracted by the melting of the
biotite in the host rock.
Relative timing of deep crustal pseudotachylyte
generation
The studied pseudotachylytes are associated with ultra-
mylonites or at least to thin mylonite zones (Fig. 4a). The
relationship between ductile deformation and pseudot-
achylyte generation is complex, since in our samples there
is evidence that frictional melt formed between two phases
of plastic creep. The second phase of ductile deformation is
indicated by the preferred orientation of biotite microlites
and clasts, discordant to the vein margin in a pseudot-
achylyte (Fig. 7d,f).
The wall rock of the mafic pseudotachylytes is charac-
terized by mylonites defined by grain-size reduction via
dynamically recrystallization of plagioclase and clinopy-
roxene (Fig. 5e,f). In addition, in the pseudotachylyte,
fragments of clasts very similar to these deformed rocks are
present. This suggests that localized dynamic recrystalli-
zation must have happened before the seismic event and
formation of the frictional melt.
Another strong argument is the s-c-like deformation
pattern in a quartz-rich rock clast (Fig. 4d). In pseudot-
achylyte-filled open space along a c plane, a sigma clast of
plastically deformed quartz occurs (Fig. 3c,e). This sigma
clast is disrupted in a fine-grained biotite-rich matrix
representing former melt. These structures show clearly the
pre-seismic ductile deformation of the rock and the sub-
sequent brittle disruption, connected with a seismic event.
In addition, fine-grained recrystallized quartz grains occur
directly in contact with the ‘melt-filled s-c planes’
(Fig. 4d).
In other samples, we can document sigmoidal fabrics or
s-c-like ultramylonites with very thin pseudotachylytes
preferentially located along or with small angle to the c
planes (Fig. 4a). However, the sigmoidal shape of quartz
derives from a ductile process and therefore the bending is
not due to a seismic event. The seismic-induced displace-
ment uses the previously formed c planes, whereas the melt
injection occurs also along s planes. The same samples
show also some deformed lens-shaped quartz grains in the
pseudotachylyte; they resemble in size and shape the
deformed quartz grains in the zones of ductile deformation
near the pseudotachylyte.
The very fine recrystallized quartz grains (approxi-
mately 5–10 lm, second generation; recrystallization by
bulging) in clasts within the pseudotachylytes and in the
wall rocks nearby point to high differential stress near the
pseudotachylyte veins. Using classical palaeo-piezometers
(Twiss 1977; Christie and Ord 1980), this would indicate a
high differential stress between 0.2 and 0.3 GPa. The
experimental and empirical work of Stipp and Tullis (2003)
and Stipp et al. (2010), based on different recrystallization
mechanisms indicates that this method gives reliable
results for the observed range of grain size.
In the case of the mafic sample (Calab 04 and CM73,
Table
1), the pseudotachylyte follows the thin zone of
dynamic recrystallization of plagioclase and clinopyroxene
and therefore a high-temperature ductile shear zone
(Fig. 5e,f). Here, the formation of the pseudotachylyte can
be interpreted either as following an inherited fabric
anisotropy or as the continuous evolution of the shear zone-
forming process. In contrast, other pseudotachylytes show
unambiguous evidence of oblique foliations, pointing to
ductile deformation after pseudotachylyte formation
(Fig. 7d,f).
Discussion and conclusions
The analysis of pseudotachylytes in different lithologies of
the Calabria high-grade metamorphic rocks reveals new
evidence on the depth of the fossil palaeo-seismic zone and
indications on the presence of fossil deep-seated seismic
events.
The matrix of the pseudotachylytes indicates melts of
different compositions: some biotite-rich matrix layers or
‘pressure shadows’ indicate melts of near biotite compo-
sition (Fig. 4f, 6a). Others with cloudy or drop-like
Contrib Mineral Petrol
123
domains show different evidence of unmixing (drops of
mingling) of frictional melts composition (Fig. 6b). The
existence of melts of different composition in the same
vein indicates the stepwise, non-equilibrium conditions of
frictional melting, as supposed by Spray (1992).
Our results provide new arguments for the formation
depth of the pseudotachylytes. Microstructures, together
with occurrence and composition of new minerals, indicate
that the studied pseudotachylytes formed at deeper crustal
levels (C0.85 GPa). This is also consistent with the pres-
sure estimates of 0.75-0.9 GPa previously obtained from
the mylonites located at the footwall of the Curinga-Gi-
rifalco line (Langone et al. 2006). Even higher pressure
estimates of about 1.1 GPa have been obtained also in
garnet-bearing metagabbros by Acquafredda et al. (2008).
They interpreted this pressure as reflecting peak conditions
for the granulite-facies rocks in the Calabrian lower crust.
The minimum formation depth of the studied pseudot-
achylytes is constrained by the growth of almandine garnet
in pseudotachylytes with andesitic (matrix) composition
([0.7–0.8 GPa) and the formation of Al-bearing orthopy-
roxene (C0.85 GPa). This suggests melt generation at a
minimum depth of about 31 km. Assuming a nearby hyp-
ocentre, these values are similar to earthquake foci in
active orogens like the Andes. Beneath the present back arc
basin (Western Sierra Pampeanas, Argentina), continental
crust above a flat-lying subduction slab is highly seismi-
cally active (Alvarado et al. 2005). Although hypocentres
along a nearly flat subduction are common, most of the
recent earthquakes have their foci at about 20 km of depth,
that is, in the middle to lower crust (Alvarado et al. 2005).
These earthquakes are due to reverse and thrust faults,
related to the interaction with the flat subduction. Closer to
the Andean mountain range, few earthquakes, resulting
from displacements at older terrane boundaries, happened
at around 26 km depth (Alvarado et al. 2005).
Summarizing, it can be concluded that pseudotachylyte
formation is timely framed between episodes of high-
temperature plastic deformation. This suggests intermittent
brittle deformation within an overall ductile environment.
However, some differences arise when different protoliths
are considered.
In mafic granulites, strong localization of deformation is
observed (Fig. 5e,f), since pseudotachylyte-bearing faults
occur only in millimetre-thick ductile shear zones defined by
dynamically recrystallized plagioclase and clinopyroxene.
These were able to drive fault nucleation and propagation.
Ductile to brittle processes took place in a water-deficient
environment, as shown by the absence of alteration in the
wall rock and by the formation and presence of anhydrous
microlites in the pseudotachylyte matrix. This feature is
particularly significant since an anhydrous assemblage has
been observed also when the wall rocks contain hydrous
phases, such as amphibole. In these cases, frictional heating
led to dehydration of the seismic plane.
A contrasting behaviour is observed in biotite rich
migmatitic paragneisses, where deformation is partitioned
in a thick horizon of pseudotachylytes, mylonites and ult-
ramylonites. In these rocks, pseudotachylyte veins are
almost parallel or at a very low angle to the foliation planes
of the ultramylonites or the c planes of s-c fabrics. In
addition, melt intruded into the s planes. Failure propaga-
tion along pre-existing anisotropies may have been assisted
by the presence of fluids (the so-called Terzaghi effect;
Terzaghi 1943; Hubbert and Ruby 1959), as described for
eclogite-facies pseudotachylytes by Lund and Austrheim
(2003). Fluids may originate from the breakdown of biotite
or may have been supplied externally. In addition, the
studied pseudotachylytes are preferentially located along
pre-existing fine-grained bands formed by ductile defor-
mation and dynamic recrystallization. Strain localization
on sites of smaller grain size is a common mechanism
(Altenberger 1997).
Interestingly, in s–c structures pervaded by pseudot-
achylyte melt, indicators of deformation occurring under
increasing strain rates can be documented. This is nicely
illustrated by the fragmentation of a stretched sigma clast
made up of recrystallized quartz within a foliated pseu-
dotachylyte (Fig. 4f). A continuous ductile flow, with
intermittent high-strain rate episodes, leading to seismic
events and related melting, is the most likely process able
to explain the observed microstructures.
Acknowledgments We would like to thank B. Fabian for her tire-
less and instructive help in graphics, C. Fischer for excellent thin
section preparation, A. Laurita for the assistance at the SEM in Pot-
enza and R. Oberha
¨
nsli for the easy access to the institute’s labs; H.
Austrheim, V. Toy and G. Pennacchioni for their constructive criti-
cism and discussions. We would like to express our gratitude to R.
Weinberg and anonymous referees for their very detailed, construc-
tive and fruitful reviews. The OSXStereonet software by N. Cardozo
has been used for plotting structural data. Funding by PRIN project
(year 2007) is acknowledged.
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... SEM Back-Scattered Electron (BSE) imaging highlights dendritic textures of the garnet, jadeite and omphacite intergrows sealing the breccia fragments (Fig. 4). These growth structures in metamorphic rocks suggest fast precipitation under disequilibrium conditions [52][53][54][55] . Cathodoluminescence (CL) imaging of euhedral jadeite and garnet in the matrix shows oscillatory zoning ( Fig. 2c and Supplementary Figs. ...
... Fluid inclusions and the presence of fluiddeposited graphitic carbon in the breccia matrix indicate that the fluid was aqueous and CH 4 and H 2 -rich. The matrix microstructures, including dendritic and cauliflower-like crystal growths, suggest fast sealing in plausible disequilibrium conditions [53][54][55] . The relationships between CH 4 -bearing fluid circulation and brecciation can be derived from the relative chronology of deformation and metamorphic events reconstructed in the natural samples, which here below are discussed starting from the oldest. ...
... Pseudotachylites were not identified due either to their absence or to the fact that they are easily altered and overprinted in geological settings rich in fluids, such as subduction zones 67 . Nonetheless, several authors related the cauliflower structure of garnet to fast growth and seismic activity 54,55 . Moreover, the brecciation of omphacite-rich, strong rock types at subduction zone high-pressure conditions has been in some cases associated with deep seismic ruptures and transiently high pore pressure 56,68,69 . ...
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Metamorphic fluids, faults, and shear zones are carriers of carbon from the deep Earth to shallower reservoirs. Some of these fluids are reduced and transport energy sources, like H2 and light hydrocarbons. Mechanisms and pathways capable of transporting these deep energy sources towards shallower reservoirs remain unidentified. Here we present geological evidence of failure of mechanically strong rocks due to the accumulation of CH4-H2-rich fluids at deep forearc depths, which ultimately reached supralithostatic pore fluid pressure. These fluids originated from adjacent reduction of carbonates by H2-rich fluids during serpentinization at eclogite-to-blueschist-facies conditions. Thermodynamic modeling predicts that the production and accumulation of CH4-H2-rich aqueous fluids can produce fluid overpressure more easily than carbon-poor and CO2-rich aqueous fluids. This study provides evidence for the migration of deep Earth energy sources along tectonic discontinuities, and suggests causal relationships with brittle failure of hard rock types that may trigger seismic activity at forearc depths.
... In addition, a relation exists between abundance of vesicles and depth of formation of pseudotachylytes (Swanson et al., 1992). Deeper crustal pseudotachylytes never contain vesicles (e.g., Altenberger et al., 2013). Upper crustal and near surface ones (e.g., related to the Alpine fault/New Zealand or to landslides like Tsergo Ri/Nepal and Köfels/Austria) contain up to 40 vol % vesicles (Mash et al., 1985;Maddock et al., 1987;Toy, 2008;Weidinger et al., 2014). ...
... The composite Pst-Ucc veins are not evenly distributed but, with few exceptions, occur in three distinct, up to 100 m wide stripes in the hanging wall of the MCT (Fig. 3), more than 1.5 km south of the thrust. Such distances of Pst locations to the thrust plane are quite common (Koch and Masch, 1992;Altenberger et al., 2013;Lin et al., 2013) and indicate that Pst does not necessarily emerge at the site of its formation. ...
Article
The occurrence of pseudotachylyte-ultracataclasite veins at the Main Central Thrust (central Nepal) is reported here for the first time. The veins are planar, mm-thin layers concordant to the main foliation and layering of the wallrock. They contain elongate domains with variable amount of glasses and µm to mm-sized angular to sub-angular fragments. The glasses indicate the presence of pseudotachylyte and its origin by frictional fusion and subsequent rapid cooling. Amoeboid and partly cuspate domain geometries with diffuse contacts result from simultaneous movement and mingling of pseudotachylyte and ultracataclasite materials during injection into opening foliation-parallel cracks. Frequency distributions of fragment sizes, distribution patterns of fragments, and lobate boundaries of mingled materials are quantified by fractal geometry methods. They follow various power laws on various scales and indicate repeated processes of fragmentation, injection of mobile material, flow, mingling, mixing, and solidification. The formation of composite pseudotachylyte-ultracataclasite veins correlates with thrusting along the Main Central Thrust, specifically with the reactivation of the thrust in the Late Miocene to Early Pliocene.
... Several authors reported the scarcity of garnet clasts in pseudotachylytes (Altenberger et al., 2013;Austrheim et al., 1996;Camacho et al., 1995;Pittarello et al., 2012) and the extreme comminution of garnet adjacent to pseudotachylyte veins (Austrheim et al., 2017;Hawemann et al., 2019;Papa et al., 2018;Petley-Ragan et al., 2019). Garnet comminution has been referred to seismic loading (Austrheim et al., 2017;Trepmann and Stöckhert, 2002), dynamic propagation of seismic rupture (Petley-Ragan et al., 2019), and thermal shock (Papa et al., 2018). ...
... The general scarcity of survival clasts can also explain the rarity of garnet microlites in many occurrences of deep-seated pseudotachylytes, where garnet should be stable. Although microlites do not necessarily grow around a clast of the same mineral (e.g., Sarkar and Chattopadhyay, 2020); garnet microlites (especially the so-called cauliflower garnet) commonly show relict clast nuclei at their cores (Altenberger et al., 2013;Pittarello et al., 2015). ...
Article
On-fault processes during earthquakes contribute to seismic rupture propagation and slip. Here we investigate clast fragmentation in an experimental pseudotachylyte (solidified seismic melt) produced with a rotary shear machine. We slid for 0.44 m (corresponding to Mw ≥ 6 earthquakes), at slip rates > 1 m/s, pre-cut samples of quartz + phyllosilicates + plagioclase + sillimanite + garnet -bearing ultramylonite, that hosts pseudotachylytes in nature. The ultramylonite minerals extensively preserved as clasts in the experimental pseudotachylyte are quartz, plagioclase, and sillimanite. Garnet is scarcely preserved, despite having a melting temperature similar to plagioclase, probably due to having low thermal shock resistance. This selective clast survival is identical to the one found in the natural pseudotachylytes. Based on these experimental observations and assuming non-equilibrium melting, the preservation of a mineral, as a clast, in the melt appears to be controlled by its thermal shock properties as well as by its melting temperature. Since the mechanical effects of rupture propagation in these experiments were negligible, we conclude that, for Mw ≥ 6 earthquakes, (i) frictional slip and heating of the slipping zone plus (ii) thermomechanical properties of minerals, rather than fault rupture processes, control mineral comminution and clast survival in frictional melts.
... Hot, dry rock comprising strong minerals such as lower crustal granulites offer an ideal environment to test and apply our predictions. There are many examples of exhumed dry lower crustal granulite facies rocks such as in the Lindås Nappe, Norway (e.g., Austrheim, 1987Austrheim, , 2013Jamtveit et al., 2019;Petley-Ragan et al., 2018;Putnis et al., 2017), the Athabasca granulite terrane (Orlandini et al., 2019;Regan et al., 2014), Lofoten, Norway (e.g., Campbell et al., 2020;Jamtveit et al., 2019;Menegon et al., 2021), the Musgraves Range, Australia (Camacho et al., 1995;Menegon et al., 2021), and the Calabria Terrane, Italy (Altenberger et al., 2013). These granulites all preserve pseudotachylites formed by brittle failure, indicating that these rocks were extremely strong and resistant to crystal plastic deformation. ...
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Mineral compositions are used to infer pressures, temperatures, and timescales of geological processes. The thermodynamic techniques underlying these inferences assume a uniform, constant pressure. Nonetheless, convergent margins generate significant non‐hydrostatic (unequal) stresses, violating the uniform pressure assumption and creating uncertainty. Materials scientists F. Larché and J. Cahn derived an equation suitable for non‐hydrostatically stressed geologic environments that links stress and equilibrium composition in elastic, multi‐component crystals. However, previous works have shown that for binary solid solutions with ideal mixing behavior, hundreds of MPa to GPa‐level stresses are required to shift mineral compositions by a few hundredths of a mole fraction, limiting the equation's applicability. Here, we apply Larché and Cahn's equation to garnet, clinopyroxene, and plagioclase solid solutions, incorporating for the first time non‐ideal mixing behavior and more than two endmembers. We show that non‐ideal mixing increases predicted stress‐induced composition changes by up to an order of magnitude. Further, incorporating additional solid solution endmembers changes the predicted stress‐induced composition shifts of the other endmembers being considered. Finally, we demonstrate that Larché and Cahn's approach yields positive entropy production, a requirement for any real process to occur. Our findings reveal that stresses between tens and a few hundred MPa can shift mineral compositions by several hundredths of a mole fraction. Consequently, mineral compositions could plausibly be used to infer stress states. We suggest that stress‐composition effects could develop via intracrystalline diffusion in any high‐grade metamorphic setting, but are most likely in hot, dry, and strong rocks such as lower crustal granulites.
... GPa and 525-570°C. Similar P-T estimates were obtained for the sheared pseudotachylyte veins and the ultramylonitic layers that affect the mylonitic lower crustal rocks of the Sila and Serre Unit near the tectonic contact with the Castagna Unit orthogneisses (Altenberger et al., 2011(Altenberger et al., , 2013. Later, (late Eocene?) early Oligoceneearly Miocene (30-15 Ma) extensional shearing and reactivation occurred along the CGL , with cataclasites and un-sheared pseudotachylyte veins that developed at T < 300°C (Thomson, 1998) in a brittle environment, in confinement to the tectonic contact (Langone et al., 2006;Spiegel, 2003). ...
Article
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High‐pressure (HP) mineral parageneses are usually poorly developed within metagranitoids, as these rocks are commonly affected by fluid‐deficient conditions when experiencing a metamorphic cycle. However, since ductile shear zones can act as preferential pathways for fluids in the Earth’s crust, if metagranitoids are involved in ductile shear under HP conditions, the presence of fluids during deformation can induce recrystallisation and equilibration in these rocks. With this in mind, we investigate the formation and evolution of mineral assemblages in the orthogneisses of the Castagna Unit from the northern Serre Massif (Calabria, southern Italy). During Alpine tectonics, the thrusting along the Curinga–Girifalco Line juxtaposed these rocks, representative of the Hercynian intermediate crust, below the lithologies of the Hercynian lower crust. A detailed microstructural study of the orthogneisses, sampled along a progressively increasing ductile deformation gradient, revealed a variation in the mineral assemblage between the weakly‐deformed orthogneisses and those in the shear zone. Phase diagram calculations in the MnNCKFMASHTO system indicate that the progressive replacement of relict minerals by new, Alpine minerals in the shear zone, was related to the presence of fluids during deformation. This allowed equilibration of the sheared orthogneisses up to metamorphic peak conditions of ~0.9–1.0 GPa and ~560–590 °C. Our integrated study highlights that both weakly‐deformed and mylonitic orthogneiss share the same peak metamorphic conditions, and that the new equilibrium mineral assemblage was stabilised in the mylonitic orthogneisses along a fluid‐conservative prograde path, where no fluid was added or lost. After metamorphic peak, the fluid was channelled towards the inner part of the shear zone, with fluid‐present conditions that were restricted to the mylonitic orthogneisses close to the tectonic contact. These mylonitic orthogneisses record cooling and exhumation to 0.6–0.7 GPa and 360–400 °C, showing an overall anticlockwise P–T path. By comparing our findings with existing structural studies, we highlight that the Castagna Unit was under‐thrusted to lower‐crustal depths during the Alpine orogeny, before the re‐activation of the Curinga–Girifalco Line during the Oligocene to Miocene extensional tectonic phase, that enabled the exhumation of this unit.
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To evaluate how the presence of pseudotachylytes affects the strength of crustal rocks, deformed pseudotachylytes and their relationship with pristine pseudotachylytes at the base of the Silvretta nappe are analyzed. Pseudotachylytes formed associated with high‐stress crystal plasticity (σd > 400 MPa), as indicated by twinned amphiboles in gneisses. Mylonitic quartz clasts enclosed within deformed pseudotachylytes and mylonitic vein‐quartz, hosting folded pseudotachylyte injection veins, reflect creep at lower stresses (ca. 100 MPa) after seismic rupturing. Deformed pseudotachylytes can be crosscut by pristine pseudotachylytes, indicating a second, independent stage of coseismic rupturing after creep. The evidence of dynamic dislocation creep of quartz and the presence of stilpnomelane and epidote associated with all fault rocks indicate similar ambient greenschist facies conditions during all deformation stages. Whereas the intermediate stage of creep is interpreted to represent deformation at large distance to the propagating thrust tip, the pristine pseudotachylytes represent the last stage of rupturing eventually leading to nappe decoupling from its basement. Gneiss clasts in an ultramylonitic matrix (i.e., deformed pseudotachylyte) reveal that pseudotachylytes have a lower strength during creep in relation to the hosting gneisses. In contrast, during coseismic high‐stress crystal plasticity, the coarse gneisses accumulate a higher amount of strain. This strength‐relationship explains that only those rocks rupture, which have not been previously deformed before. The study demonstrates the importance of different strengths of crustal rocks at specific stress‐ and strain‐rate conditions in dependence on the distance to the propagating fault tip.
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In the present study, we unveil the real significance of mylonitic reworking of the polymetamorphic crystalline basement in the Serre Massif of Calabria (Southern Italy). We use a multidisciplinary approach to comprehend the structural, microstructural and petrologic changes that occurred along a, so far, not much considered shear zone affecting the Variscan lower crustal rocks. It was never before studied in detail, although some late Cretaceous ages were reported for these mylonites, suggesting that this shear zone is of prime importance. Our observations reveal now that the formation of the new structural fabric within the shear zone was accompanied by changes in mineral assemblages, in a dominant compressive tectonic regime. During this tectono-metamorphic event, high-P mylonitic mineral assemblages were stabilized, consisting of chloritoid, kyanite, staurolite, garnet and paragonite, whereas plagioclase became unstable. Average peak P–T conditions of 1.26–1.1 GPa and 572–626 °C were obtained using THERMOCALC software. These data question (i) that the Serre Massif represents an undisturbed continuous section of the Variscan crust, as generally suggested in the literature, and (ii) highlight the role of (eo-)Alpine high-P tectonics in the Serre Massif, recorded within mylonite zones, where the Variscan basement was completely rejuvenated.
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The mechanisms of earthquake rupture in lower continental crust, below the usual frictional‐viscous transition, remain uncertain. In addressing this problem, the study of pseudotachylyte (quenched frictional melt produced during seismic fault slip) and related structures from deeply exhumed rocks can provide direct observational constraints. A felsic granulite from the Musgrave Ranges (central Australia) exceptionally preserves pristine microstructures spatially related to a pseudotachylyte. This sample remained dry, without introduction of hydrous fluids, during pseudotachylyte development and subsequent exhumation. It was therefore unaffected by alteration and metamorphic re‐equilibration. Fractures in the damage zone developed asymmetrically to either side of the pseudotachylyte and are marked by new, randomly oriented quartz, feldspar, and garnet grains. Pulverization of garnet occurred locally between intersecting fractures with powder injected into dilatant fractures in a quartz inclusion within the garnet host. Injection of pulverized material can explain the growth of new, compositionally different minerals (quartz, feldspar, kyanite, ilmenite, magnetite, and rutile) along dilatant fractures developed in a short‐lived seismic event. The pseudotachylyte contains only clasts of quartz, suggesting an unusually high melting temperature. The sequentially developed microstructures provide a time‐lapse record of thermomechanical processes during a single earthquake event, including initial rupture propagation with associated off‐fault damage and local pulverization during very dynamic fluctuations in the local stress field; frictional heating and eventual melting during fault slip; flow and injection of melt; and rapid solidification (quenching) and crystallization of new minerals. This occurred under lower continental crustal conditions of ca. 650°C and 1.2 GPa about 550 Myrs ago.
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Experimental data in the range of 1 bar to 13 kbar enable us to map the liquidus equilibria relevant to Proterozoic (massif) anorthosites and related mafic rocks. Massif anorthosites are widely believed to have formed by accumulation of plagioclase into high-Al basaltic liquids. Mantle-derived basaltic liquids, fractionating at pressures sufficiently high (10–13 kbar) to crystallize the highly aluminous orthopyroxene megacrysts typically observed in anorthosite massifs, reach plagioclase saturation at low normative silica contents. Peritectic-like equilibria (e.g. liq + opx → plag + cpx + sp) and a thermal divide on the plagioclase + pyroxene liquidus surface ensure that mantle–derived liquids become nepheline normative with further crystallization and crustal assimilation at depth. Such liquids cannot produce the full range of troctolitic–noritic to troctolitic–gabbroic mineral assemblages observed in anorthosite massifs without extensive low–pressure granite assimilation. Conversely, the array of plausible anorthosite parental liquids not only lies along the trace of the plagioclase + two-pyroxene cotectic from 10 to 13 kbar, but also straddles the thermal divide on the plagioclase + pyroxene liquidus surface. This condition requires mafic source regions, such as lower continental crust or foundered mafic plutons, for liquids parental to massif anorthosites and associated mafic intrusions.
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In the Serre of southern Calabria a major tectonic contact called Curinga-Girifalco Line separates a section of Variscan lower crustal rocks from the underlying amphibolite-facies rocks of the Castagna unit. The aim of this study was to reconstruct the evolution of the Curinga-Girifalco Line (CGL) in order to shed some light on the early processes of exhumation and nappe formation in southern Calabria. The protoliths of the CGL-mylonites were metapelitic rocks of the lower crustal section. They were metamorphosed at ∼ 700 °C and 5.5 kbar during Variscan times. The metamorphic conditions as well as the chemical compositions of garnet, biotite and cordierite suggest that prior to mylonitization the protolithes were situated at a high level of the lower crustal section. The formation of the CGL was related to the Mesozoic exhumation of the former lower crust. It can tentatively be placed between 195 and 110 Ma, which is much earlier than previously assumed. During that exhumation the rocks of the CGL achieved their present position at the bottom of the lower crustal section. The different lithologies of the underlying Castagna unit represent a tectonic mélange formed at the base of the exhuming lower crust. Mylonitization along the CGL took place at temperatures between 500 and 300 °C under water-deficient conditions. The pre-mylonitic mineral assemblage was completely preserved, but mylonitization caused grain size reduction, an incomplete recrystallization of quartz and feldspar and a partial chemical reequilibration between garnet, cordierite and biotite. Later Oligo-Miocene extensional tectonics reactivated the Mesozoic Curinga-Girifalco Line.
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Fission-track thermochronology applied to the nappe pile of the Calabrian Arc of southern Italy, particularly within the continental basement rocks, has provided important new constraints on the nature of some of the tectonic contacts. In southern Calabria an important phase of lower Miocene crustal extension is indicated. In northern Calabria no Oligocene or younger extension is seen. Here, the emplacement of continental basement rocks with Alpine metamorphism over ophiolitic rocks with little or no metamorphism is constrained as a thrust of lower to middle Miocene age related to collision of the Calabrian Arc with the Adria plate margin. It is proposed that reduction in the plate convergence velocity during collision of a retreating subduction zone with a continental margin is, at least partly, an explanation for the onset of extension in southern Calabria during the Miocene.
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This chapter provides a synthesis of the past and current state of the knowledge on geological structure and evolution of the Calabria-Peloritani terrane and the northern (N) Ionian Sea. A general introduction to the study area is followed by a brief overview of past interpretations, a description of its main tectono-stratigraphic units, and a new interpretation of its evolution in terms of terrane analysis and accretion history. The term Calabria-Peloritani Arc, traditionally found in the literature, is discontinued because it refers to the present-day morphological curvature of the terrane in map view, but it is confusing if geologically defined.