Beryllium metal and other beryllium-containing compounds are known for their unusual combination of properties, which includes low atomic number, low density, high stiffness, and high thermal conductivity. These attributes account for the long-standing interest in these materials since the 1930s.
Important fields of application for beryllium metal and its compounds include acoustics, aerospace structures, x-ray transmission, motion control, fission test reactors, fusion energy research, laser-based optical systems, high-energy particle physics research, high-performance automotive applications, and thermal management. Beryllium-containing alloys (which typically contain less than 2% Be) are used extensively in commercial electronics, telecommunications infrastructure, automotive electronics, oil and gas equipment, tooling for plastic molding, and medical equipment applications.
Thanks to its low atomic number, beryllium has very high x-ray transmissivity, coupled with a low absorption and high scattering cross-section-to-neutrons-and-so-is-one-of-the-most-important-and-vital elements in the nuclear field. Especially, the superior neutron multiplication performance of beryllium via the (n,2n) reaction is essential in nuclear fusion technology. This chapter of Comprehensive Nuclear Materials is organized as follows:
• Section 2: Background and status of recent research, including the need for R&D into beryllium intermetallic compounds (beryllides).
• Section 3: Fabrication technology for both beryllium and beryllides in the form of pebbles, which will be needed due performance requirements for neutron multipliers.
• Section 4: Physical, chemical, thermal, and mechanical properties, as well as retention properties in unirradiated material.
• Section 5: Neutron irradiation effects: swelling, impact on mechanical properties, tritium release, and microstructure evolution.
• Section 6: First principles modeling, including simulation methods, bulk properties, self-interstitial defects, transmutation gaseous atoms, effects of other impurities, absorption and desorption of hydrogen, second-phase precipitates, and beryllides.
• Section 7: handling and safety issues, including health effects of beryllium materials, an overview of standards and regulations, and risks specific to fusion applications.
• Section 8: summary and conclusion.