The theory of the inverse optoacoustic effect for a two-level gas is given. For molecules, a model is constructed based on the harmonic oscillator. Experiments were done on gases (CO, CHâ, SFâ, COâ, CâHâ, CâHâ) to test the temperature dependence of the acoustic signals. The mechanism for sound production in gases at high concentrations is next considered. The range of the theory is extended into
... [Show full abstract] the regime where analyte concentrations are high and heat conduction becomes important. Heat conduction effects in optoacoustic spectroscopy are next considered. Sall's equation is solved, and experiments were done. Isotope effects in the Hâ-Clâ and Dâ-Clâ reactions were measured using the optoacoustic effect. Results show that the effect permits studies of slight changes in parameters on a time scale fast compared with the reaction. (DLC)