Petrographic and geochemical analyses (δ¹⁸O, δ¹³C, ⁸⁷Sr/⁸⁶Sr, clumped isotopes, and elemental composition) coupled with field structural data of synkinematic calcite veins, fault rocks, and host rocks are used to reconstruct the episodic evolution of an outstanding exposed thrust zone in the Southern Pyrenees and to evaluate the fault behavior as a conduit or barrier to fluid migration. The selected thrust displaces the steeply dipping southern limb of the Sant Corneli-Bóixols anticline, juxtaposing a Cenomanian-Turonian carbonate unit against a Coniacian carbonate sequence. Successive deformation events are recorded by distinct fracture systems and related calcite veins, highlighting (i) an episodic evolution of the thrust zone, resulting from an upward migration of the fault tip (process zone development) before growth of the fault (thrust slip plane propagation), and (ii) compartmentalization of the thrust fault zone, leading to different structural and fluid flow histories in the footwall and hanging wall. Fractures within the footwall comprise three systematically oriented fracture sets (F1, F2, and F3), each sealed by a separate generation calcite cement, and a randomly oriented fracture system (mosaic to chaotic breccia), cemented by the same cements as fracture sets F1 and F2. The formation of fractures F1 and F2 and the mosaic to chaotic breccia is consistent with dilatant fracturing within the process zone (around the fault tip) during initial fault growth, whereas the formation of the latest fracture system points to hybrid shear-dilational failure during propagation of the fault. The continuous formation of different fracture systems and related calcite cementation phases evidences that the structural permeability in the footwall was transient and that the fluid pathways and regime evolved due to successive events of fracture opening and calcite cementation. Clumped isotopes evidence a progressive increase in precipitation temperatures from around 50°C to 117°C approximately, interpreted as burial increase linked to thrust sheet emplacement. During this period, the source of fluid changed from meteoric fluids to evolved meteoric fluids due to the water-rock interaction at increasing depths and temperatures. Contrary to the footwall, within the hanging wall, only randomly oriented fractures are recognized and the resulting crackle proto-breccia is sealed by a later and different calcite cement, which is also observed in the main fault plane and in the fault core. This cement precipitated from formation fluids, at around 95°C, that circulated along the fault core and in the hanging wall block, again supporting the interpretation of compartmentalization of the thrust structure. The integration of these data reveals that the studied thrust fault acted as a transverse barrier, dividing the thrust zone into two separate fluid compartments, and a longitudinal drain for migration of fluids. This study also highlights the similarity in deformation processes and mechanisms linked to the evolution of fault zones in compressional and extensional regimes involving carbonate rocks.
1. Introduction
The study of outcrop analogues in fractured carbonate reservoirs is important to better understand the characteristics and evolution of synkinematic fracture systems and their control on fluid migration during crustal deformation [1–4]. In areas undergoing compressional regimes, the largest fluid fluxes, mass transfer, and heat transport commonly occur along the main thrust faults and related fracture networks because of the loading induced by thrust sheet emplacement [5–7]. By contrast, fluid flow rates in adjacent rock-matrix and poorly connected synkinematic fractures are commonly very low and fluid composition are often rock-buffered [6, 8]. In some cases, the development of thrust systems may also inhibit vertical fluid transport inducing fluid overpressure [9–11] leading to hydraulic fracturing [12–14]. Whether a fault zone will constitute either a conduit or barrier to fluid migration depends, among other factors, on the architecture of the fault zone and the permeability associated with the developed structures [15, 16]. Since the fault zone consists of a fault core, which is usually formed of low-permeability fault rocks, and a damage zone, which mainly includes extensional fractures and faults, overall permeability of the fault is conditioned by the amount, the spatial distribution, and the internal composition of these two fault zone elements [15, 17]. Besides, such structural permeability is dynamic and may vary spatially and temporally across the fault zone due to successive episodes of fracture opening and cementation [18, 19].
Although numerous studies based primarily on structural and numerical data have provided conceptual and analytical models on the architecture, mechanical properties, and fluid flow along fault zones [7, 15, 20], there exist only a few studies coupling field data and geochemistry of synkinematic minerals filling fractures that characterize the fluid migration through a thrust zone [21–25] and its spatial behavior as a conduit or barrier system [26, 27]. An outstanding exposed thrust in the Southern Pyrenees was chosen as a case study to evaluate qualitatively the fault-related permeability and its control on the fluid flow within and around the fault zone. Here, we combine structural, petrological, and geochemical data of calcite veins and host rocks present in the studied thrust zone. Therefore, the main objectives of this paper are (i) to determine the origin, composition, and temperature of the vein-forming fluids and the timing of fluid migration in relation to the fracturing events and (ii) to discern the fluid pathways, the extent of fluid-rock interaction, and the transfer of fluids across a fault zone during thrusting. The field and lab results are then compared with other studies reporting fluid flow within fault zones in other geological settings to generalize our conclusions to fault zones in carbonate settings.
2. Geological Setting
The Pyrenees constitute an asymmetrical and doubly verging orogenic belt that resulted from the Alpine convergence between the Iberian and European plates from Late Cretaceous to Oligocene, causing the inversion of previous Mesozoic rift basins and their incorporation into the thrust system [28–32]. The Pyrenean structure consists of a central antiformal stack of basement-involved thrust sheets from the axial zone [30], flanked by two oppositely vergent fold-and-thrust belts and their related Cenozoic Aquitaine and Ebro foreland basins [30, 33] (Figure 1(a)).
(a)