Thomas Vasileiadis

Adam Mickiewicz University | UAM · Faculty of Physics

We study monolayer WSe2 using ultrafast electron diffraction. We introduce an approach to quantitatively extract atomic-site-specific information, providing an element-specific view of incoherent atomic vibrations following femtosecond excitation. Via differences between W and Se vibrations, we identify stages in the nonthermal evolution of the lat...

Translationally symmetric nanostructures, termed phononic crystals (PnCs), offer control over the propagation of acoustic phonons in the gigahertz (GHz) range for signal-processing applications and thermal management at sub-Kelvin temperatures. In this work, we utilize Brillouin light scattering to investigate the impact of symmetry breaking on GHz...

Localized surface plasmon resonance (LSPRs) shown by gold nanorods (AuNRs) has several applications in photocatalysis, sensing, and biomedicine. The combination of AuNRs with Polydopamine (PDA) shells results in a strong photo‐thermal effect, making them appealing nanomaterials for biomedical applications. However, the precise roles and relative co...

Silk fibroin is an important biomaterial for photonic devices in wearable systems. The functionality of such devices is inherently influenced by the stimulation from elastic deformations, which are mutually coupled through photo-elasticity. Here, we investigate the photo-elasticity of silk fibroin employing optical whispering gallery mode resonatio...

Observation of Fano resonances in various physical phenomena is usually ascribed to the coupling of discrete states with background continuum, as it has already been reported for various physical phenomena. Here, we report on Fano lineshapes of nonthermal GHz phonons generated and observed with pumped Brillouin light scattering in gold-silicon thin...

Hybrid plasmonic devices involve a nanostructured metal supporting localized surface plasmons to amplify light‐matter interaction, and a non‐plasmonic material to functionalize charge excitations. Application‐relevant epitaxial heterostructures, however, give rise to ballistic ultrafast dynamics that challenge the conventional semiclassical underst...

Plasmonic coupling between adjacent metallic nanoparticles can be exploited for acousto-plasmonics, single-molecule sensing, and photochemistry. Light absorption or electron probes can be used to study plasmons and their interactions, but their use is challenging for disordered systems and colloids dispersed in insulating matrices. Here, we investi...

Hybrid plasmonic devices involve a nanostructured metal supporting localized surface plasmons to amplify light-matter interaction, and a non-plasmonic material to functionalize charge excitations. Application-relevant epitaxial heterostructures, however, give rise to ballistic ultrafast dynamics that challenge the conventional semiclassical underst...

Revealing the bonding and time-evolving atomic dynamics in functional materials with complex lattice structures can update the fundamental knowledge on rich physics therein, and also help to manipulate the material properties as desired. As the most prototypical chalcogenide phase change material, Ge2Sb2Te5 has been widely used in optical data stor...

Silk fibroin is an important biomaterial for photonic devices in wearable systems. The functionality of such devices is inherently influenced by the stimulation from elastic deformations, which are mutually coupled through photo-elasticity. Here, we investigate the photo-elasticity of silk fibroin employing optical whispering gallery mode resonatio...

The microscopic arrangement of atoms and molecules is the determining factor in how materials behave and perform; i.e., the structure determines the property, a traditional paradigm in materials science. Photoexcitation-driven manipulation of the crystal structure and associated electronic properties in quantum materials provides opportunities for...

Transport of heat and hypersound with gigahertz (GHz) to terahertz (THz) phonons is crucial for heat management in electronics, mediating signal processing with microwave radiation, thermoelectrics, and various types of sensors based on nanomechanical resonators. Efficient control of heat and sound transport requires new materials, novel experiment...

Attosecond core-level soft X-ray spectroscopy is shown to image the energy conversion pathways between photons, charge carriers and lattice in real time in graphite.

We use attosecond core-level X-ray spectroscopy to disentangle the spectral and dynamical signatures of energy conversion pathways between photons, charge carriers and the lattice in graphite with attosecond precision and across a picosecond range.

Attosecond core-level soft X-ray spectroscopy iidentifies the energy conversion pathways between photons, charge carriers and lattice in real time in graphite.

We perform femtosecond electron diffuse scattering measurements on black phosphorus. We reproduce the non-equilibrium structural dynamics using ultrafast dynamics simulations based on the time-dependent Boltzmann formalism and calculations of the all-phonon structure factor.

Detection of the energy conversion pathways between photons, charge carriers, and the lattice is of fundamental importance to understand fundamental physics and to advance materials and devices. Yet, such insight remains incomplete due to experimental challenges in disentangling the various signatures on overlapping timescales. Here, we show that a...

The actuation of micro- and nanostructures controlled by external stimuli remains one of the exciting challenges in nanotechnology due to the wealth of fundamental questions and potential applications in energy harvesting, robotics, sensing, biomedicine, and tunable metamaterials. Photoactuation utilizes the conversion of light into motion through...

Detection of the energy conversion pathways, between photons, charge carriers, and the lattice is of fundamental importance to understand fundamental physics and to advance materials and devices. Yet, such insight remains incomplete due to experimental challenges in disentangling the various signatures on overlapping time scales. Here, we show that...

Revealing the bonding and time-evolving atomic dynamics in functional materials with complex lattice structures can update the fundamental knowledge on rich physics therein, and also help to manipulate the material properties as desired. As the most prototypical chalcogenide phase change material, Ge2Sb2Te5 has been widely used in optical data stor...

We combine ultrafast electron diffuse scattering experiments and first-principles calculations of the coupled electron-phonon dynamics to provide a detailed momentum-resolved picture of lattice thermalization in black phosphorus. The measurements reveal the emergence of highly anisotropic nonthermal phonon populations persisting for several picosec...

Monolayer graphene is stronger than bulk graphite: the elastic properties of graphene are such that it could hypothetically withstand an elephant balancing on a pencil. A contactless optical technique, reported by Bartlomiej Graczykowski and co-workers in article number 2008614 now shows that this is not the case for MoSe2, an attractive semiconduc...

Singlet exciton fission (SEF) is a key process for developing efficient optoelectronic devices. An aspect rarely probed directly, yet with tremendous impact on SEF properties, is the nuclear structure and dynamics involved in this process. Here, we directly observe the nuclear dynamics accompanying the SEF process in single crystal pentacene using...

Manipulating crystal structure and the corresponding electronic properties in topological quantum materials provides opportunities for the exploration of exotic physics and practical applications. As prototypical topological materials, the bulk MoTe2 and WTe2 are identified to be Weyl semimetals and higher-order topological insulators. The non-cent...

Few‐layer van der Waals (vdW) materials have been extensively investigated in terms of their exceptional electronic, optoelectronic, optical, and thermal properties. Simultaneously, a complete evaluation of their mechanical properties remains an undeniable challenge due to the small lateral sizes of samples and the limitations of experimental tools...

Phononic crystals (PnCs) control the transport of sound and heat similar to the control of electric currents by semiconductors and metals or light by photonic crystals. Basic and applied research on PnCs spans the entire phononic spectrum, from seismic waves and audible sound to gigahertz phononics for telecommunications and thermal transport in th...

The ultrafast dynamics of magnetic order in a ferromagnet are governed by the interplay between electronic, magnetic, and lattice degrees of freedom. In order to obtain a microscopic understanding of ultrafast demagnetization, information on the response of all three subsystems is required. A consistent description of demagnetization and microscopi...

Telecommunication devices exploit hypersonic gigahertz acoustic phonons to mediate signal processing with microwave radiation, and charge carriers to operate various microelectronic components. Potential interactions of hypersound with charge carriers can be revealed through frequency- and momentum-resolved studies of acoustic phonons in photoexcit...

Singlet exciton fission (SEF) is a key process in the development of efficient opto-electronic devices. An aspect that is rarely probed directly, and yet has a tremendous impact on SEF properties, is the nuclear structure and dynamics involved in this process. Here we directly observe the nuclear dynamics accompanying the SEF process in single crys...

The ultrafast dynamics of magnetic order in a ferromagnet are governed by the interplay between electronic, magnetic and lattice degrees of freedom. In order to obtain a microscopic understanding of ultrafast demagnetization, information on the response of all three subsystems is required. A consistent description of demagnetization and microscopic...

Microscopic scattering processes in solids are governed by the symmetry and anisotropy of the electronic and phononic structures. Femtosecond electron inelastic scattering experiments reveal a momentum-resolved picture of transient anisotropic phonon populations in photoexcited black phosphorus. Based on many-body calculations of the electron-phono...

Black phosphorus has recently attracted significant attention for its highly anisotropic properties. A variety of ultrafast optical spectroscopies has been applied to probe the carrier response to photoexcitation, but the complementary lattice response has remained unaddressed. Here we employ femtosecond electron diffraction to explore how the stru...

Black phosphorus has recently attracted significant attention for its highly anisotropic properties. A variety of ultrafast optical spectroscopies has been applied to probe the carrier response to photoexcitation, but the complementary lattice response has remained unaddressed. Here we employ femtosecond electron diffraction to explore how the stru...

We investigate the structural dynamics accompanying singlet fission in pen-tacene single crystals with femtosecond electron diffraction. The data reveal incoherent and coherent contributions to the structural dynamics. We discuss the implications for singlet fission properties.

We demonstrate a simple and cost-effective method for the synthesis of elemental Se and Te nanoparticles. The method employs irradiation of bulk Se and Te by visible light, continuous wave sources and results in uniform deposition of nanoparticles on various substrates. The process is fast and avoids the steps of pre- and post-treatment involved in...

In crystals, microscopic energy flow is governed by electronic and vibrational excitations. In nanoscale materials, however, translations and rotations of entire nanoparticles represent additional fundamental excitations. The observation of such motions is elusive as most ultrafast techniques are insensitive to motions of the phonons’ frame of refe...

Compression of electron pulses with terahertz radiation offers short pulse durations and intrinsic subcycle stability in time. We report the generation of 12-fs (rms), 28-fs (FWHM) electron pulses at a kinetic energy of 75 keV by using single-cycle terahertz radiation and a simple planar mirror. The mirror interface provides transverse velocity mat...

We study the ultrafast structural dynamics, in response to electronic excitations, in heterostructures composed of Au$_{923}$ nanoclusters on thin-film substrates with the use of femtosecond electron diffraction. Various forms of atomic motion, such as thermal vibrations, thermal expansion and lattice disordering, manifest as distinct and quantifia...

We investigate the interactions of photoexcited carriers with lattice vibrations in thin films of the layered transition metal dichalcogenide (TMDC) WSe$_2$. Employing femtosecond electron diffraction with monocrystalline samples and first principle density functional theory calculations, we obtain a momentum-resolved picture of the energy-transfer...

We investigate the excitation of phonons in photoexcited antimony and demonstrate that the entire electron-lattice interactions, in particular coherent and incoherent electron-phonon coupling, can be probed simultaneously. Using femtosecond electron diffraction (FED) with high temporal resolution, we observe the coherent excitation of the fully sym...

A novel method for the laser-assisted, template-free and surfactant-free fabrication of low-dimensional nanomaterials, i.e. nanotubes, nanowires, nanospheres, of elemental Te, hybrid Te/TeO2and GeTe structures is presented. Owing to the high light absorption at visible wavelengths and the low melting points of chalcogen-based materials, simple cw l...

Temperature-dependent Raman spectroscopy was used for studying few-nanometers-thick epitaxial Fe3O4(111) films grown on Pt(111) and Ru(0001) single crystal supports. The changes in position, intensity and full width at half maximum of the magnetite's A(1g) peak, corresponding to symmetric stretching of oxygen atoms along Fe-O bonds, were monitored...

Controlled photo-induced oxidation and amorphization of elemental trigonal tellurium are achieved by laser irradiation at optical wavelengths. These processes are monitored in situ by time-resolved Raman scattering and ex situ by electron microscopies. Ultrathin TeO2 films form on Te surfaces, as a result of irradiation, with an interface layer of...

We experimentally demonstrate a novel method which allows deposition of solution-based soft-glass films (chalcogenide) inside the holes of commercially available solid and hollow core photonic crystal fiber (PCF). The transmission spectra are recorded using a supercontinuum source indicating ARROW type guidance in the solid core PCFs while initial...

One dimensional (1D) nanostructures of semiconducting oxides and elemental chalcogens culminate over the last decade in nanotechnology owing to their unique properties exploitable in several applications sectors. Whereas several synthetic strategies have been established for rational design of 1D materials using solution chemistry and high temperat...

Supplementary Information

New CCD four-color light curves of TY Boo made on eight nights over 2010-2011 were analyzed in comparison with historical light curves obtained from 1969 through 2011. The light curves could all be represented by a unique geometry and by wavelength consistent phototometric parameters of a two-spot model on either stellar component. It is confirmed...

The atomic structure and electronic and vibrational properties of glassy Ga11Ge11Te78 have been studied by combining density functional (DF) simulations with x-ray (XRD) and neutron diffraction (ND), extended x-ray absorption fine structure (EXAFS), and Raman spectroscopies. The final DF structure (540 atoms) was refined using reverse Monte Carlo m...