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Delayed Differentiation in Fertilizer Production: Deciphering Climate-Smart Miscible Products through Reverse Blending for Boosting Crop Production

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Abstract

Generalized crop-specific or regional blanket fertilizer recommendations are among the primary dilemmas for sustainable agriculture resulting in low fertilizer use efficiency, nutritional imbalance in crops, while raising economic and environmental concerns. Innovative fertilizer formulations with balanced nutrient ratios customized to the crop requirements with temporal release properties are needed to make sustainable agriculture practically possible. For an example, the demonstration of the advantages of delayed differentiation, through reverse blending (RB) in small blending units at the end user level may be useful to increase the sustainability of agriculture. This review discusses how to use innovative fertilizer procedures in the fertilizer supply chain to optimize the supply of crop nutrition to boost crop production and safeguard the environment from the drawbacks of blanket fertilizer applications. This review also aims to identify critical elements that influence fertilizer use efficiency and fertilizer customization to improve fertilizer recommendations for future (precision) agriculture, and to assess the role and suitability of RB in the production of customized fertilizers. We reviewed typical case studies and summarized the role of delayed differentiation in the production of field fertilizers through RB. Customized fertilizers could be produced by using smallest sets of canonical basic inputs (CBI). CBI acronym offers the smallest set of chemical composite materials that can be used as a blending input for the production of customized fertilizers. Reverse blending (RB) accelerates the attainment of large flows by decreasing those flows to discover chemically stable reactions for the creation of novel fertilizer formulations. RB drives the high flow massification to low by managing the flow from 100 to 1.57%. RB requires a minimum of 10–15 CBIs (± 0.05%) to meet out nutritional requirements of many crops. Delayed differentiation through RB will involve exploration of known percentage of CBI in terms of N, P, K, Zn, B2O3, and filler to achieve a desirable fertilizer. The tailored fertilizers used for basal application must be granular, with at least 90% of the content ranging between 1 and 4-mm IS sieve, with no more than 5% lying below 1 mm. Moisture content should not be present at more than 1.5%. The paper demonstrates RB as a quadratic model approach where blending is based on geographical area, enabling the crops to achieve target yields through customized fertilizer solution with higher agronomic (kg/ha of N, P, K, Zn, B2O3) applicability. We understand that innovative fertilizer strategies must be developed to significantly reduce unforeseen negative effects on the environment and human health caused by the improper use of fertilizers.
Vol.:(0123456789)
1 3
Journal of Soil Science and Plant Nutrition
https://doi.org/10.1007/s42729-022-01055-9
REVIEW
Delayed Differentiation inFertilizer Production:
DecipheringClimate‑Smart Miscible Products throughReverse
Blending forBoosting Crop Production
TahirSheikh1 · ZahoorBaba2· ZahoorA.Ganie3· BasharatHamid2· AliMohdYatoo4· AnsarulHaq5· SadafIqbal1·
FehimJ.Wani6· SivagamyKannan7· RoheelaAhmad8
Received: 3 December 2021 / Accepted: 2 November 2022
© The Author(s) under exclusive licence to Sociedad Chilena de la Ciencia del Suelo 2022
Abstract
Generalized crop-specific or regional blanket fertilizer recommendations are among the primary dilemmas for sustainable agri-
culture resulting in low fertilizer use efficiency, nutritional imbalance in crops, while raising economic and environmental con-
cerns. Innovative fertilizer formulations with balanced nutrient ratios customized to the crop requirements with temporal release
properties are needed to make sustainable agriculture practically possible. For an example, the demonstration of the advantages
of delayed differentiation, through reverse blending (RB) in small blending units at the end user level may be useful to increase
the sustainability of agriculture. This review discusses how to use innovative fertilizer procedures in the fertilizer supply chain
to optimize the supply of crop nutrition to boost crop production and safeguard the environment from the drawbacks of blanket
fertilizer applications. This review also aims to identify critical elements that influence fertilizer use efficiency and fertilizer cus-
tomization to improve fertilizer recommendations for future (precision) agriculture, and to assess the role and suitability of RB in
the production of customized fertilizers. We reviewed typical case studies and summarized the role of delayed differentiation in
the production of field fertilizers through RB. Customized fertilizers could be produced by using smallest sets of canonical basic
inputs (CBI). CBI acronym offers the smallest set of chemical composite materials that can be used as a blending input for the
production of customized fertilizers. Reverse blending (RB) accelerates the attainment of large flows by decreasing those flows to
discover chemically stable reactions for the creation of novel fertilizer formulations. RB drives the high flow massification to low
by managing the flow from 100 to 1.57%. RB requires a minimum of 10–15 CBIs (± 0.05%) to meet out nutritional requirements
of many crops. Delayed differentiation through RB will involve exploration of known percentage of CBI in terms of N, P, K, Zn,
B2O3, and filler to achieve a desirable fertilizer. The tailored fertilizers used for basal application must be granular, with at least
90% of the content ranging between 1 and 4-mm IS sieve, with no more than 5% lying below 1mm. Moisture content should not
be present at more than 1.5%. The paper demonstrates RB as a quadratic model approach where blending is based on geographical
area, enabling the crops to achieve target yields through customized fertilizer solution with higher agronomic (kg/ha of N, P, K,
Zn, B2O3) applicability. We understand that innovative fertilizer strategies must be developed to significantly reduce unforeseen
negative effects on the environment and human health caused by the improper use of fertilizers.
Keywords Fertilizer· Mass customization· Quadratic programming· Reverse blending· Target yield
1 Introduction
Global population is expected to reach approximately
roughly 9.7 billion people in the 2060s (Nations 2019; Bar-
rett 2021), an increase of one-quarter of today’s 7.8 billion
(Vollset etal. 2020; Randive etal. 2021). A golden revolu-
tion in agriculture is now required to feed the future popula-
tion and match the ever-expanding food demands (Evans and
Lawson 2020; Siddaramappa 2021). Global food production
has to expand by 70% from 2010 to 2060 with focus on
the doubling of production in developing countries (Ten-
korang 2006). It is well documented that huge gaps exist
between the potential productivity or productivity under
research trials compared to the productivity under farmer
fields; however, it is more severe under the developing
* Tahir Sheikh
tahirkmr@gmail.com
Extended author information available on the last page of the article
Journal of Soil Science and Plant Nutrition
1 3
countries (George 2014). A gap between prospective output
and farmers’ produce is caused by a set of several biotic
including all types of pests and/or abiotic factors which
could be listed edaphic, environmental, and management
categories (Fischer etal. 2014; Dehkordi etal. 2020; Fischer
etal. 2014; Ortiz-Bobea etal. 2020; Xiang etal. 2020; Srini-
vasarao 2021). Among the edaphic factors, crop nutrition is
the basis of agricultural production, effective fertilizer use
is essential to raising agricultural productivity and indis-
pensable in achieving global food security. Global demand
for primary nutrients is expected to reach 200.91 million
tonnes by 2022–2023 (Fig.1), implying a 0.7% average
annual growth rate, resulting in a greater reliance on ferti-
lizer inputs (Dawson and Hilton 2011; Randive etal. 2021).
Fertilizer statistic of 2020–2021 indicates that the global
consumption of nutrients has touched 104.87 million tonnes
(108.74 mt (N), 47.42 mt (P2O5), and 38.71 mt (K2O)) with
continuously increasing projections for future (Fig.2). The
global fertilizer market was worth $155.8 billion in 2019,
with a continuous annual growth rate of 3.8% predicted for
the forecast period of 2019–2024 (Williams 2019). To close
this gap between the nutrient supply from organic sources
and the nutrient demand for optimal crop development, fer-
tilizer must be available in sufficient quantities. A transition
from blanket fertilizers to customized fertilizers is needed
to boost crop yields by better synchronizing the supply
and uptake of nutrients (Vidyashree and Arthanari 2021).
Manycountriesareactivelyinvolvedinformulatingpoli-
ciestohelpthefertilizerindustryin ordertoachieveferti-
lizerself-sufficiency (Randive etal. 2021). Hundreds of dis-
tinct customized fertilizers, far more than what is currently
available, are required for efficient and sustainable farming
(Gennari etal. 2019; Qaim 2020). Bridging up a balance in
production and demand, fertilizer industry is facing severe
problem, making it unable to overcome its current produc-
tion processing technology (Evans and Lawson 2020; Mah-
mah and Amar 2021). Optimal soil nutrient concentrations
are required to boost the crop yields withmaximumnutrient
use efficiency. Such a wide range of nutrient inputs cannot be
generated satisfactorily using conventional fertilizer produc-
tion methods based on continuous pooling batches (Verma
and Singh 2019; Chaudhari etal. 2020). This demands the
use of customized fertilizers that adhere to formulas with
wide range of nutrients and quantities depending on the
pedological conditions of regional agricultural soils and
requirementsof the crop (Incrocci etal. 2017). Mass cus-
tomization has scope even under discreet production process
in assembly lines, allowing production of multiple products
in a row (Stewart and Roberts 2012; Fuglie etal. 2019; Papa-
dopoulos 2020; Sanchez 2020). The review proposes a new
technique of fertilizer production based on the chemical
identification of a small inputs. This method uses a delayed
differentiation approach, in which blending of inputs takes
place in small blending units but rather in the farmer’s area,
in order to simplify fertilizer production and distribution
(Benhamou etal. 2020). It is an innovative strategy where
fertilizer plants need to produce only few intermediate prod-
ucts instead of generating all the fertilizers required by the
farmers. These intermediated are then combined in small
processing units close to end users. This novel approach is
termed as reverse blending (RB), which uses parameterized
quadratic program to specify the ideal requirement of sev-
eral primary inputs that are attempted to keep at minimum
level. RB helps to produce range of fertilizers by blending
the minimum inputs. As a result, the goal of the RB is to
find out the best input composition to meet out the demand
of any crop. RB operates via a single-stage blending method
as opposed to the traditional multistage pooling process. The
Fig. 1 Global demand for nitrogen, phosphorus and potassium ferti-
lizer by nutrients (NPK), 2016–2017 to 2022–2023 (million metric
tons)
2021-22 2023-24
0
20
40
60
80
100
120
NK2OP2O5 TOTAL
)sennotcirtemnoilliM(muissatoP,negortiN
Phophorus, Total (Million metric tonnes)
0
50
100
150
200
Fig. 2 Global nitrogen, phosphorus, potassium, and total nutrient (N,
P2O5, K2O) consumption during 2021–2022 and projection for 2023–
2024
Journal of Soil Science and Plant Nutrition
1 3
aim of RB is to determine optimal quantities of nutritious
composite material (inputs) with known percentage in pursu-
ance of getting more formulations (outputs) (Srichaipanya
etal. 2014). These new blended products accredit the diverse
production of customized products. This section discusses
how to use innovative fertilizer procedures in fertilizer sup-
ply chain to optimize the supply of crop nutrition to boost
crop production and safeguard the environment from blan-
ket fertilizer applications. This review also aims to identify
critical elements that influence fertilizer-use efficiency and
fertilizer customization to improve fertilizer recommenda-
tions for future (precision) agriculture.
2 Fertilizer Use Eciency andCrop Yields
Excessive fertilizer inputs contribute little to increased
crop productivity (Mikula etal. 2020), but they can lead to
excessive water use, fertilizer pollution, and environmental
concerns (Wang etal. 2016; Ren etal. 2021). Long-term
excessive fertilizer application, particularly nitrogenous (N)
fertilizer, can have a considerable impact on the majority
of soil biology by altering soil pH (Ren Wang etal. 2020).
Currently, blanket recommendations are given throughout
agro-ecological regions, despite the fact that fertilizer usage
and nutrient response intensity by crop are spatially hetero-
geneous (Ichami etal. 2019). On an average blanket fertilizer
recommendations of 171kg NPK ha−1 (111kgN ha−1, 44kg
P2O5 ha−1, and 16kg K2O ha−1) for various field crops have
caused poor nutrient supply with low nutrient use efficiency,
leading to limited crop yield responses (Fig.3) (Choudhary
etal. 2020; Ritchie 2021), while increasing emission of
greenhouse gases from agriculture fields (Yao etal. 2012;
Zhong etal. 2016).
In the production of cereals as a whole, the partial factor
productivity of nitrogen (PFPN) has declined from 245kg
grain/kg N applied in 1961–1965 to 52kg/kg in 1981–85,
and is currently about 44kg/kg N (Panayotova and Kosta-
dinova 2015). Most agricultural crops recover 20 to 30% of
applied P during their growth under ideal conditions (Collins
etal. 2016). The most prevalent recovery efficiency of phos-
phorus (REP) values (which account for 50% of all data) fell
within the range of 0.10 to 0.35kg/kg, which is likely repre-
sentative of most agricultural land worldwide. The average
recovery efficiency of potassium (REK) varied between 0.4
and 0.5kg/kg K. REK occurs frequently in the field on soils
with poor K fixing potential, good management (high yield),
and relatively low K rates (Qiu etal. 2014).
Subsequently, excessive fertilizer application hinders the
sustainable use of fertilizer supplies and raises the vulner-
ability of environmental degradation, such as NO3 toxicity,
ammonia volatilization, leaching of N and P into groundwater,
and N2O emissions via microbial denitrification (Zhong etal.
2016; Lian etal. 2017). Nitrate–N can readily leach down
below the rhizosphere and readily reaches to ground water,
causing contamination of precious water resources. Glob-
ally croplands make 60% of the area with increased levels of
nitrate–N pollution. The injudicious application of fertilizers
may enhance pollution to ecosystem either by nitrate accumu-
lation in water bodies or nitrous oxide in atmosphere (Fig.4).
The theoretical link between nutrient supply and uptake
can be subdivided into three distinct regions (Fig.5). In the
first zone (I), the absorption of nutrients is linearly propor-
tional to nutrient supply. Increases in supply do not result in
increased nutrient uptake after nutrient supply levels have
reached a certain threshold (zone II). When the latter occurs,
the other nutrient may be the limiting factor in crop yield.
In the intermediate range of nutrient supply, a nonlinear
behavior is evident (zone III). For zone III, it is assumed
that the demand and supply curves (III) are parabolic (Sattari
etal. 2014). Excess fertilizers have low agronomic efficiency
(Salim and Raza 2020), while as higher environmental and
human health implications (Dimkpa etal. 2020). Optimizing
fertilizer recommendation for farmers is critical for boosting
food production in agricultural landscapes.
Fifty percent of nitrogenous fertilizers used by plants are
lost to evaporation (Wang etal. 2016), another 15 to 25%
react with organic compounds in clayey soil and interfere
with soil colloids and reach to ground water (Putra etal.
14
11
8
7
5.5
4.7
4
2.8
1980-85
1985-90
1990-95
1995-00
2000-05
2005-10
2010-15
2015-20
0
2
4
6
8
10
12
14
16
KPNgK/niarggK
Kg grain/ Kg NPK
Fig. 3 Relationship between the efficiency of nutrient input (NPK)
application and yield response in intensive agriculture, illustrat-
ing constrained crop development and productivity beyond the opti-
mum nutrient supply. Average blanket fertilizer recommendations of
171kg NPK ha−1 (111kg N ha−1, 44kg P2O5 ha−1, and 16kg K2O
ha−1) for various field crops have caused poor nutrient supply with
low nutrient use efficiency, leading to limited crop yield responses
Journal of Soil Science and Plant Nutrition
1 3
2020). Volatilization of NH3 is a potential side effect of
using ammonium fertilizers, and this leads to a wide range
of soil and environmental pollutions (Sigurdarson etal.
2018). Nitrogen fertilizer efficiency is only between 30 and
40% in rice and 50 and 60% in other cereal crops (Bijay
andSingh2017). Phosphorus (P) concentration ranges
from 0.1 in soil solution to 100mg P L−1 in xylem sap and
approximately 4000mg P kg−1 in seeds (Linhart etal. 2019;
Ojeda Rivera etal. 2022). More than half of the 33 million
metric tonnes P year−1 that is released into the oceans is
transported by rivers, while the remaining runoff comes from
the coasts (Nyffeler etal. 2018). In most crops, phosphorus
use efficiency ranges from 15 to 20% (Etesami 2020), while
potassium use efficiency ranges from 60 to 80% (Ichami
etal. 2019). Depletion of soil phosphorus (P) by agricultural
practices is a major constraint on future food and feed supply
(Nziguheba etal. 2016)). Total yearly phosphorus (P) losses
from arable soils due to water erosion are estimated to be 6.3
teragram (Tg), with 1.5 Tg being organic P and 4.8 Tg being
inorganic P (Alewell etal. 2020b). Agricultural soils loose
phosphorus between 4 and 19kg ha−1 year−1, with the great-
est losses occurring because of water erosion. Worldwide,
water erosion results in an annual loss of 5.9 ± 0.79kg of
phosphorus per hectare from the top 30cm of arable land
(Smil 2000; Alewell etal. 2020a). Predictions for the global
demand for phosphorus in 2050 range from 22 to 27 million
tons per year, with an additional need of 4 to 12 million
tons per year for grasslands (Mogollón etal. 2018). Low
use efficiency of water-soluble P fertilizers has detrimental
impacts on ecosystems and human health (Fig.6). However,
Fig. 4 Delayed differentiation through reverse blending for crop specific nutrients through customized fertilizers could increase nutrient use effi-
ciency with comparably minimum fertilizer pollution
Fig. 5 Actual nutrient (NPK) uptake versus supply sub-divided into
three zones (I, II, and III) for most of the crops at a various propor-
tions of N (138, 150, 196), P (26, 30, 20), and K (31,90, 40) kgha.−1
(A. Dobermann et al. 2002; Haefele et al. 2003; Wortmann et al.
2009)
Journal of Soil Science and Plant Nutrition
1 3
erosional P losses account for a far lesser share of all P
losses from agricultural systems in Europe (16%) and Aus-
tralia (19%), ranging from 30 to 85% (Belayneh etal. 2019).
South Africa, Madagascar, and Tanzania, as well as Bolivia
in South America, are predicted to experience a very high P
loss of 10–20 kgha−1 year−1, while as India, Angola, Zam-
bia, and Uruguay in Southern Africa are predicted to experi-
ence a P loss of 5 to 10kg ha−1 year−1 (Alewell etal. 2020b).
Phosphorus deficiency can be remedied by using fertilizer
high in phosphorus (Pi). Rock Pi is the primary source of
Pi, which can only be mined from a very few locations in
the world. Phosphorus is primarily a nonrenewable resource
and 85% of the world’s remaining supplies are held by just
one country, Morocco (Edixhoven etal. 2014; Kisinyo and
Opala 2020). Phosphate fertilizer accounts for over 80% of
the annual demand for phosphate rock (PR) ore. Exploitable
deposits of PR may last 300–400years or beyond at cur-
rent production level of 160–170 million tones year−1years
(Dawson and Hilton 2011; Jupp etal. 2021). Since, geo-
logical deposits of phosphorus cannot be increased and
phosphorus resourceswill become more scarce globally in
the future (Scholz and Wellmer 2013; Roberts and Johnston
2015). Field studies demonstrate that P recovery by the crop
during the same year of application seldom surpasses 25%
and more commonly is only between 10 and 15% of the
P applied (Fig.6), which has led to the widespread belief
that excess P fertilizer use is extremely wasteful (Syers etal.
2008; Roberts and Johnston 2015). Agronomic field trials
have revealed that the P not taken up by the crops (i.e., the
residual P) is not reversible deposit in the soil and remains
in an inaccessible form, challenging previous beliefs (Jupp
etal. 2021).
To measure the recovery efficiency of P by crop, the
below given formula is widely used to determine phosphorus
recovery efficiency (Cassman etal. 1998) as (1)
where UPU0 are the P taken up by a crop from soils
with (UP) and without (U0) added P and FP is the amount
of P applied through fertilizer, and the result expressed in
percentage.
Insufficient potassium (K) utilization in agricultural
production systems has reduced soil K storage (Philp etal.
2021). Nearly all of the world’s potash fertilizer comes
from MOP mined from sylvinite, carnallitite, or hartsalz
(Sweeting etal. 2020; Mikkelsen and Roberts 2021). K
fertilizers are applied to various crops at a far lower rate
than N and P fertilizers (Table1), and less than half of the
K lost by crops is typically restored annually (Majumdar
etal. 2021). The four forms of potassium found in soils
are unavailable K, accessible or fixed K, fast accessible or
exchangeable K, and water-soluble K (Berde etal. 2021).
The amount of potassium lost through leaching varies with
soil texture, pH, and the availability of potassium in the
soil (Sipert etal. 2020). K leaching from the soil system
does not have as severe an effect on the environment as of
N and P leaching, but it still can result in economic loss
and wasted agricultural inputs. Sustainable agriculture
requires a commitment to agricultural K-management that
can be sustained over time (Basak etal. 2022). Utilizing
slow-release K fertilizers, mineral adsorbents like clinop-
tilolite zeolite (CZ), or organic additives like composts
can all aid in K retention (Zargar Shooshtari etal. 2020;
Saleem etal. 2021; Sonali etal. 2022).
Precision fertilization, which accounts for soil condi-
tions affecting phosphate availability to plants and applies
fertilizer precisely when it is needed most through custom-
ized fertilizers (Raj etal. 2021). Customized fertilizers is a
(1)
Recovery ef f iciency%
(RE)=
U
p
U
0
F
p
Fig. 6 Relationship of high
phosphorus input with soil solu-
tion P, microbial P, and losses to
water bodies
Journal of Soil Science and Plant Nutrition
1 3
pre-eminent option to solve the problem of inefficient ferti-
lizer-use efficiencyand gratifies crop nutritional demands
specific to an area, soil, and growth stage of plant (Vid-
yashree and Arthanari 2021). In countries with no avail-
able specific fertilizer recommendations from the Interna-
tionalFertilizerAssociation (IFA) database (Ramankutty
etal. 2008; Potter Philip etal. 2021), a spatial pattern of
cropland maps is used by FAO to estimate the fertilizer
consumption by the following equation (Potter etal. 2010):
where F (i,j) is spatially precise fertility maps of N or P
(units = kg of N or P ha−1), FFAO(k) is total yearly national
consumption of N or P in country k (unit = kg of N or P).
Whereas AM3-cropland (ij) spatially explicit farmland data
(unit = crop land area in ha of grid cell area), and AM3-crop
plant (k) with total harvest area of nation estimated from the
M3 crop database (unit = crop area in ha).
Fertilizer response (FR) is an important indicator of
fertilizer recommendations and as cumulative increments
in crop yield due to fertilization irrespective of quantity
and type of fertilizer used (Ichami etal. 2019). It is calcu-
lated as ratio of mean crop yield of the fertilized (
x
t
in kg
ha−1) to the yield of unfertilized control plot’s (x¯c in kg
ha−1) (Hedges etal. 1999; Schut etal. 2018) and was com-
puted as a regression model to normalize the distribution
of data (Kihara etal. 2017). A normalized FR is required
to develop a multivariate regression in meta-regression
models. The lnFR was computed as
F
(i,j)=FFAO(k)
A
M3−Cropland
(i,j)
A
M
3
−Cropland
(k)
+ kgha1,i,j,𝜀
k
lnFR = ln(x
t
x
c)
FR is a useful concept to evaluate the response of a soil to
an applied fertilizer in a region (Njoroge etal. 2017). Soils
having FR greater than 1 were classified as responsive and
soils with FR less than or equal to 1 are designated as less
responsive (Vanlauwe etal. 2015; Ichami etal. 2019).
3 Customized Fertilizers
Customized fertilizers (CF) are multi-nutrient carriers
designed to contain macro, secondary, and/or micro nutri-
ents each from inorganic sources and/or organic sources
(Majumdar and Prakash 2018; Dasgupta etal. 2021). CF
developed through systematic scientific granulation process
is tailored to meet out regional crop-specific nutritional
needs (Vidyashree and Arthanari 2021). The target behind
the tailored fertilizer is to supply site-specific nutrient man-
agement (Bhattacharya etal. 2019) to achieving maximum
fertilizer use efficiency for the applied nutrient in a cost
effective manner (Argento etal. 2021). Customized fertiliz-
ers promote site-specific nutrient management with com-
plete variability of nutrients in right proportion for a selected
crop supported by soil testing and crop demand (Rakshit
etal. 2012; Choudhary etal. 2020; Deepranjan Sarkar etal.
2020). CF are in line with the site-specific nutrient man-
agement which ensures targeted application of major and
micronutrients at specific amount for every holding (Dipak
Sarkar etal. 2017; Kumar etal. 2020). Customized fertiliz-
ers focus on nutrient requirement of the crop in a particular
area through physically mixed and steam granulated technol-
ogy known as fusion blending (Yadav 2012; Kumar etal.
2020). To boost the crop production, an innovative product
such as customized fertilizers specific to an agro climatic
conditions might be supplied to farmers to mitigate nutrient
Table 1 Long-term experiments showing the agronomic value of potassium and recovery efficiency by various crops
* Grain yield of plot received K-fertilizer-control with no K-fertilizer/K-fertilizer input
** Grain yield/kgK uptake
Crop Rate of fertilizer application *Agronomy effi-
ciency of potassium
(%)
**Recovery effi-
ciency of potassium
(%)
Reference
Rice 10-year long-term experiment at 225 (kg K2O ha−1) 19.0, 26.0, 18.0 37.0, 61.0, 56.0 (Achim Dobermann
2007; Dhillon etal.
2019)
Wheat K rates at 51, 102, and 154 (kg K2O ha−1) 6.1, 5.9, 3, 0.1 23.7, 19.0, 13.3 (Zhan etal. 2016)
Maize 16-year experiment at 133 and 225 (kg K2O ha−1) 10.8, 4.9 37.3, 28.5 (Qiu etal. 2014)
Common bean 2years at 200 gm K kg−1 soil 22.5 - (Fageria etal. 2001)
Clitoria + pigeon pea
Acacia + pigeon pea
2years at 39 kgha−1 46.0 - (de Moura etal. 2010)
Sweet potato 22.8g of K2O kg−1 soil in a pot without K - 71.0 (Tang etal. 2015)
Journal of Soil Science and Plant Nutrition
1 3
deficiencies, particularly of secondary and micronutrients
(Haque and Haque 2016; Jeevika and Sreya 2016; Singh
etal. 2019). In this context, we understand that customized
fertilizers could be helpful to promote site-specific nutri-
ent management to maximize the nutrient-use efficiency of
applied nutrients in cost-effective manner (Table2).
4 Reverse Blending (RB) andDelayed
Dierential toAchieve Customized
Fertilizers
Delayed differentiation is one of the fundamental methods of
mass customization andhas proved to be high-performance
techniquein the industrial sector (Guo etal. 2018). However,
this is still underused in the process industry, particularly
when differentiation refers to product content rather than
design/production. Mass customization involves product
differentiation point (PDP) which refers to an action that
converts an input substrate into a unique product (Daaboul
and Cunha 2014; Kombaya etal. 2021). This concept can
be defined as the transformation of many more nutrients
into a customized fertilizer based on crop demand (Galizia
etal. 2020). Delayed differentiation addresses both fertilizers
and its packing and could be carried out in small capacity
blending units near to end users. Delayed differentiation of
fertilizer production through reverse blending (RB) comes
out to be an efficient technique of delivering customized/
miscible fertilizers that meet out precisely the needs of sus-
tainable agriculture while eliminating the production and
transportation concerns (Gao etal. 2019; Benhamou etal.
2020, 2022). However, this approach requires the design and
development of new chemical inputs which may need reen-
gineering the production and distribution processes (e.g., use
of new raw materials). For a fertilizer industry, this implies
developing a wide range of complex fertilizer, processed
through chemical reaction of raw material. The challenge,
therefore, is how to improve the performance of fertilizer
supply in terms of both efficiency (i.e., respond to sustain-
able agricultural needs) and effectiveness (reduce costs). For
this, we propose the RB solution as an approach introduced
by Benhamouet al. (2018) based on to finding out the new
chemical specifications using small inputs. RB is a one-stage
blending technique that is used to produce fertilizers, where
the attempt isto develop the set of “I” inputs which are
known as canonical basic inputs (CBIs). The composition
Table 2 Response of important crops to CF with increase in economic yield against standard check using customized fertilizers
s. no Customized fertilizer application Crop Grain
Yield (q
ha−1)
(%) increase
from control
Reference
Customized fertilizer @ 250kg/ha
(N-14:P2O5-21:K2O-8:Zn-0.5%)
Rice 50.98 39.44 (Dwivedi and Meshram 2014; Kumar etal.
2020)
70%- Farmers fertilizer practice through
customized fertilizer (FFP = N-120:P2O5-
60:K2O-40 kgha−1)
Rice 69.94 17.07 (Naveen etal. 2017)
Customized fertilizer@ 450kg ha−1
(N-14:P-17:K-17%)
Rice 47.88 43.7 (Nagabovanalli Basavarajappa etal. 2021)
Recommended dosage of fertilizer through
customized fertilizer (N-100:P2O5-
50:K2O-50 kgha−1 at 3 equal doses)
Onion 22.34 14.10 (Kamble and Kathmale 2015)
Customized fertilizer @ 250 kgha−1
(N-12:P2O5-26:K2O-18:S-5:Zn-0.5)
Wheat 50.40 16.07 (Tiwari etal. 2021)
Customized fertilizer@ 500kg ha−1 (N-7:P-
3:K-25:Mg-4:Zn-1.25:B-4%)
Elephant foot yam 67.5 23.55 (Anju etal. 2020)
Customized fertilizer (N-70–145:P2O5-
30–60:K2O-55–85 kgha−1)
Cassava 37.6 18.61 (Byju etal. 2016)
Customized fertilizer (N-11:P2O5- 27:
K2O-0:S-6.6:Zn-0.5%)
Chickpea 2.20 14.00 (Dwivedi etal. 2019)
Customized fertilizer @150kg ha−1
(N-14:P2O5-17:K2O-14:S-5:Zn-
0.2:B-0.2%)
Potato 134.32 35.00 (Mandal etal. 2020)
Customized fertilizer at recommended
dosage of 150 kgha−1 (N-56.25:P2O5-
63.75:K2O-41.25:Zn-1.50%)
Soybean 976.00 31.00 (Verma etal. 2015)
Customized fertilizer @562.50 kgha−1
(N-143.7:P2O5-79.7:K2O-51.6:S-
14.0:Zn-1.8%)
Fingermillet 32.79 75.00 (Goud etal. 2015)
Journal of Soil Science and Plant Nutrition
1 3
of CBIs is necessarily characterized by the nutrients N, P,
K, B2O3, and the filler which is later found in the output “j
fertilizer formula. In this approach, the objective is, in fact,
to start from the demands Dj of the outputs j to define the
characteristics (weight percentage of the component c in the
total weight of the CBIi) of the I CBIs (hence, the name of
the reverse blending) while keeping I (input) as small as
possible (Benhamou etal. 2020). Fertilizer producers who
wish to implement reverse blending must be therefore pre-
pared to redesign the supply chain to give a perfect nutri-
tional requirement of a particular crop. This approach drives
a high flow massification by managing the flow from 100 to
1.57% based on experimental findings to develop fertilizer
formulations.
Constraints related to respecting the requested quantity
Dj for each output j: simultaneously with the search for the
optimal composition of the CBIs, while RB aims at defin-
ing the optimal blending of selected CBIs taken in quanti-
ties ijx (decision variable) to obtain the quantity Dj which is
requested quantity for each output j as demonstrated through
models 1 and 2:
In this model, the nutritional demands (Dj) refer to the
potential demands that farmers would need if they would
want to apply custom fertilizers to accurately meet their
nutritional requirements of a crop. Constraints related to
meeting the nutritional requirements βcj (proportional wt.
of component “c” in wt. of output j). xij is quantity of inter-
mediate (i) used in j production.
The relative weight (∑i αci.xij/Dj) of component “c” in
output j (fertilizer) obtained by blending must be equal to
the requested nutritional specification (βcj. αci), which is
proportional weight of “c” component in the total weight
of intermediate (i):
(2)
i
Xij Dj,
j
(3)
ici.
X
ij
D
j
=𝛽cj,c,
j
5 Optimum CBI Composition toProduce
Customized Fertilizers
Canonical basis inputs (CBIs) are the smallest set of chemi-
cal composite materials that can be used as a blending input
for the production of customized fertilizers. These composite
materials may not have the fertilizer properties, but their
mixtures can fulfil the requirements (in terms of component
proportion) of any fertilizer, including the production of cus-
tomizable fertilizers. In manufacturing design process, bill
of materials (BOM) is used to represent the product struc-
ture. Here, BOM is made up of the blended mixtures of CBIs
that form a bill of materials, which is used to produce any
quantity of a desired fertilizer. CBI (composite materials)
must be chemically and physically compatible for hazardless
outcomes. For instance, it is not possible to combine two
CBIs that use urea and one that uses triple super phosphate
while making a fertilizer. CBIs can be created to blended
fertilizers, which are made by combining composite materi-
als that are chemically compatible.
RB not only identifies the CBIs, but it also shows how
much of every CBI unit is needed to make the exact volume
of each fertilizer with matching chemical composition. To
reach the necessary quantities, a filler (ineffective) must be
used in concert with the CBIs. It was discovered that RB
could be used to develop fertilizers for 28 different crops
and all of them could be created with only 8 CBIs (Table3).
Table3 summarizes each CBI’s chemical composition with
respect to N, P, K, Zn, B2O3, and filler (a non-effective com-
ponent added for chemical stabilization having no effect on
the nutritional structure). In contrast, when we evaluate the
impact of RB on the fertilizer plant’s production system,
the manufacturers focus on the volume of CBIs to be cre-
ated within its production unit, rather than how they will be
further used to downregulate the supply chain in blending
units. Table3 reveals how production could be obtained if
CBIs had been used on monthly basis. Comparative demon-
stration (Table4) reveals how only first four CBIs could sig-
nificantly simplify the production procedures using formulas
in every month, particularly the second CBIs account for
Table 3 Composition of
CBIs used in reverse blending
for production customized
fertilizers (Benhamou etal.
2018)
Canonical basic inputs (CBIs)
CBI-1 CBI-2 CBI-3 CBI-4 CBI-5 CBI-6 CBI-7 CBI-8 Filler
N (%) 46.00% 11.86% 12.70% 19.00% 0.00% 2.34% 2.14% 0.00% 0.00%
P (%) 0.00% 56.08% 16.11% 38.00% 0.00% 56.00% 56.00% 51.24% 0.00%
K (%) 0.00% 0.00% 16.11% 0.00% 63.60% 0.00% 0.00% 0.00% 0.00%
S (%) 0.00% 0.00% 0.00% 7.00% 25.27% 11.78% 7.06% 19.67% 0.00%
B2O3 (%) 0.00% 0.00% 0.00% 0.00% 6.13% 3.15% 0.00% 0.00% 0.00%
Zn (%) 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 7.79% 0.00%
Filler (%) 54.00% 32.06% 55.07% 36.00% 5.00% 26.72% 34.81% 21.30% 100.00%
Journal of Soil Science and Plant Nutrition
1 3
more than 90% of monthly production. The aforementioned
flow consolidation indicates the possibility of creating a new
MTS-based production system. Indeed, taking into consid-
eration the respective share of each CBI (Table2), we sug-
gest appropriate CBI allocation to simplify the production
lines with continuous and streamlined flow to the greater
possible extent (1 CBI per production line) and to reap the
benefits of cost-effective technology.
There are fertilizer formulas with known available nutri-
ent percentage available (N, P, K, Zn). These formulations
also include extra adjuvants known as fillers, which typically
have no effect on crop yields. One feature of the inputs used
to construct the optimum formula is the percent range of
nutritional values. Based on the parameters listed in Table3
and the statistical assumption or model, the appropriate for-
mulations can be calculated (Table4). According to research
done by Benhamou etal. (2019), the 8 CBIs generated by
Xpress solver programming commands can yield up to 700
fertilizer formulation for various crops. Similar studies have
shown that reverse blending could create 28 distinct fertilizer
solutions by using just 8 CBIs (Benhamou 2020).
6 Extended Reverse Blending (ERB)
The following algorithm may be applied to obtain the best solu-
tion to produce fertilizers using the adapted pooling problem
(APP) approach. The AAP is a parametric quadratic problem
used to find out the lowest value of I1 (a parametric feature) of
a canonical basis of I1 CBIs (a parametric feature) to get the
optimal fertilizer solution (the optimal size of I1 of CBIs and the
optimal fertilizer blends can be expressed as xij/Dj,
jϵΩ1, i=
I1).
ERB technique combines APP and a set of I1 of I1 CBIs to
create new composite materials and blending of which can gen-
erate an optimum set-1 of Ji fertilizer (Fig.7). Combining the
initial and new composite materials can generate the optimum
set Ω1 of J1 fertilizers, as shown in Fig.7. Afterward, running
of RBP will facilitate to find out the smallest set of I2 of new
inputs (composite material) that correspond to I2 of new CBIs.
Combining the initial I1 composite material of I1 CBI with I2 of
new CBI gives a blending solution for new (J2) fertilizer. At the
conclusion, all fertilizer standards (Ω = Ω1 U Ω2) are satisfied.
CBI technology is to be developed by mixing new compatible
composite materials by adopted pooling problem (AAP) leading
to substantial rise in I of CBIs (Fig.7). The number of required
CBIs grew from 7 to 12 while using the extended reverse blend-
ing (ERB) holistic model (possibly unfit for manufacturing).
ERB results can be achieved by using AAP followed
by RBP model from composite material of Table3 to
determine the optimum CBI which maximizes the set
of J1 fertilizer. This is followed by using RBP model to
define the reaming optimal set of CBI which can be com-
bined with the earlier CBI determined through AAP to
produce Ω2 of J2 fertilizer. Ferti-maps play a key role in
deciding the best possible operational solution to obtain
blended multi-nutrient fertilizers. Since fertilizers are
marketed in the form of percentage formulas, it is neces-
sary to convert the quantitative NPK requirements into
crop needs expressed in fertilizer formulas. For exam-
ple, to meet NPK requirement of 531.52kg/ha with for-
mula (%) 26.03 4.90 21.07. By multiplying these %
with the required quantity (531.52kg/ha), we can obtain
respective quantities of N, P, and K as 138.33, 26.06,
and 112kg/ha.
Table 4 Composition of inputs
(composite material) and
compatible matrix (Benhamou
etal. 2020)
Composite material (k)
Filler Urea TSP KCl MAP DAP Potas-
sium
nitrates
k = 1 k = 2 k = 3 k = 4 k = 5 k = 6 k = 7
Composition of the composite materials (γck)
Component c%N c = 1 0 46 0 0 11.2 18.3 13.0
%P c = 2 0 0 46 0 55.0 46.4 0
%K c = 3 0 0 0 60 0 0 46.0
% Filler c = 4 100.0 54.0 54.0 40.0 33.8 35.3 41.0
Matrix of the composite materials in compatibilities (ξkk)
Composite material (k) Filler k = 1 0 0 0 0 0 0 0
Urea k = 2 0 0 1 1 0 0 0
TSP k = 3 0 1 0 0 0 0 0
KCl k = 0 1 0 0 0 0 0
MoP k = 5 0 0 0 0 0 0 0
DAP k = 6 0 0 0 0 0 0 0
Posam nitrate k = 7 0 0 0 0 0 0 0
Journal of Soil Science and Plant Nutrition
1 3
7 Fertilizer Customization andEcosystem
The judicious application of synthetic fertilizers is cru-
cial for improving ecological integrity in any food pro-
duction system while minimizing detrimental effects on
the environment (Nyamangara etal. 2020). Ecosystem
services include both tangible and intangible benefits to
millions of people (Müller and Burkhard 2012; La Notte
etal. 2017). Blanket fertilizer recommendations have a
negative impact on the environment (Rahman and Zhang
2018), apart from using nutrients in excess of quantity,
the another key cause is low fertilizer-use efficiency
(Nagabovanalli Basavarajappa etal. 2021). To achieve
supply–demand synchronization, fertilizer management
strategies must account for temporal fluctuations in crop
nutrient requirements (Ram etal. 2012). When fertilizer
treatments are not synchronized with crop needs, there
are significant nutrient losses from the soil–plant sys-
tem, resulting in low fertilizer usage efficiency (Nagabo-
vanalli Basavarajappa etal. 2021). Customized fertilizers
may be proved beneficial in maintaining food security
and conserving the environment (Barman etal. 2020).
Therefore, major steps need to be taken to boost agricul-
tural output by the application of customizedfertilizers
developed through innovative, climate-smart technology
like reverse blending.
8 Conclusion
Global agriculture production is built on the foundation of
crop nutrition and proper fertilizer use to address agrarian
productivity. Improving the efficiency and effectiveness
of fertilizers can potentially reduce the over-exploitation
of non-renewable fertilizer sources. Developing innova-
tive fertilizer formulas has significant potential to address
serious challenges of rationalized fertilization. Delayed
differentiation of fertilizer production through RB comes
out to be an efficient technique of delivering customized/
miscible fertilizers that meet out precisely the needs of
sustainable agriculture while eliminating the produc-
tion and transportation concerns. Delayed differentiation
addressesboth fertilizers and their packaging, which can
be carried out in small capacity blending units near to end
users. RB uses a set of optimum “I” inputs, called canoni-
cal basic inputs (CBIs) with known chemical composition
with respect to N, P, K, Zn, B2O3, and filler. In addition,
RB determines the CBIs for a particular crop and eco-
system to produce an appropriate amount of each ferti-
lizer with the desired chemical nature. Customized fer-
tilizers promote site-specific nutrient management with
complete variability of nutrients in right proportion for a
selected crop supported by soil testing and crop demand.
There are many potential opportunities through cutting-
edge technologies in fertilizer customization to increase
crop-nutrient use efficiency in different ecologies. Gaps
in scientific understanding on the production of tailored
fertilizers will require collaborative attention of agrono-
mist, soil scientists, fertilizer industry, and environment
authorities for long-term interests of human population.
Acknowledgements This study was supported by G.B. Pant National
Institute of Himalayan Environment—Almora (Ministry of Envi-
ronment and Climate Change, Govt. of India—New Delhi) [Ref no.
NMHS/SG-2016/018; Date: March 31, 2016].
Declarations
Conflict of Interest The authors declare no competing interests.
Fig. 7 A Illustration showing
mass customization by extended
reverse blending approach in
comparison with pooling. The
approach combines AAP at
J1 set solution from existing
composite material of I1 CBIs.
Blending produces largest set of
Ω1 of J1 fertilizer. B RB exploits
smallest set J2 from a CBI
composite material correspond-
ing to I2, combining set of initial
input gives blending formula of
fertilizer J2
Journal of Soil Science and Plant Nutrition
1 3
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Authors and Aliations
TahirSheikh1 · ZahoorBaba2· ZahoorA.Ganie3· BasharatHamid2· AliMohdYatoo4· AnsarulHaq5· SadafIqbal1·
FehimJ.Wani6· SivagamyKannan7· RoheelaAhmad8
Zahoor Baba
baba.zahoor@gmail.com
1 Division ofAgronomy, FoA, Sher-E-Kashmir University
ofAgricultural Sciences andTechnology Kashmir-Wadura,
Sopore, India193201
2 Division ofBasic Science, FoA, Sher-E-Kashmir University
ofAgricultural Sciences andTechnology Kashmir-Wadura,
Sopore, India193201
3 Stine Research Center, FMC Corporation, Newark, DE, USA
4 Department ofEnvironmental Sciences, University
ofKashmir, Kashmir, India190001
5 Division ofAgronomy, Sher-E-Kashmir University
ofAgricultural Sciences andTechnology Kashmir-Wadura,
Sopore, India193201
6 Division ofAgricultural Economics & Statistics, FoA,
Sher-E-Kashmir University ofAgricultural Sciences
andTechnology Kashmir-Wadura, Sopore, India193201
7 ICAR KVK, Tirur, Tamil Nadu Agricultural University,
Coimbatore, India641001
8 Division ofSoil Science & Agricultural Chemistry, FoA,
Sher-E-Kashmir University ofAgricultural Sciences
andTechnology Kashmir-Wadura, Sopore, India193201
... These ingredients are common components that must be mixed (in different ways reflecting thousands of mixing recipes) to satisfy thousands of customized fertilizers. Published research on RB (Benhamou et al., 2020;Sheikh et al., 2022) mainly gave the definition of this approach, its originality compared to the existing blending problems, its quadratic optimization models and its application on a real sample of 700 requirements in N, P and K calculated with FERTIMAP. This product design is the first step. ...
Chapter
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The science, art and practice of growing plants are called agriculture. The history of agriculture began thousands of years ago. It began independently in various parts of the world depending on climatic conditions and terrains. Agriculture enabled the human population to expand several times beyond what could be supported by hunting and gathering. From the twentieth century, precision farming in contemporary agriculture increased productivity. Precision farming is a technology-enabled approach to farming that measures, observes and analyses individual fields and crops' needs. This type of farming's main aim compared with traditional farming is where inputs are utilized in precise amounts to increase crop yields and profitability. The present work detailed about advancement and role of the Artificial Intelligence (AI) and Internet of Things (IoT) used in precision farming. The AI and IoT play a vital role in our modern day-today applications. The advantages and advancements of AI and IoT are applied in modern agriculture. This makes modern agriculture more precise and profitable. Some of the contemporary applications using AI and IoT in smart precision farming are discussed. In addition to that, important tools and techniques deployed in precision farming are also explained. The crucial benefits and the real-time devices used in the precision farming are also discussed in detail.
Conference Paper
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With increasing consumer demand for a greater variety of products in changing and unpredictable quantities. Manufacturing different products tailored to the needs of their clients is a real challenge that industries face today. Today's consumers are looking for products that carry part of their identity and allow them to stand out from the crowd. In this context many indicators have been proposed to evaluate the reactivity and flexibility of a production system; such as customization, scalability and convertibility of the system. Customization is one aspect of flexibility; it expresses a system's ability to produce customized products with customized functionality. This document develops a measure of customization of reconfigurable production systems. These measures do not only impact the production system but also the product design and the process design, which can therefore serve as a guide for the customization of manufactured products. A case study is presented to show the use of the proposed approach.
Article
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La révolution industrielle 4.0 a connu d’importants succès en production discrète (objets…), en retardant la personnalisation dans des unités de production ou d’assemblage. La production continue (granules, liquides…) est l’oubliée de cette révolution, en raison d’une organisation productive en séquence de lots qui rend difficile la production efficiente d’une grande variété de produits. En réponse à ce défi, une nouvelle approche de conception et de fabrication de produits, appelée Reverse Blending et détaillée dans un article d’IJPE, permet de retarder la personnalisation des engrais, dans de petites unités de mélange implémentées à proximité du client final. Elle se fonde sur la recherche de la composition chimique optimale d'un nombre réduit de produits semi-finis dont les combinaisons possibles permettent de satisfaire une très grande diversité de produits finis personnalisés. L’intérêt de cette approche de Chaîne Logistique Intelligente, à la production continue, est montré à travers quatre études.
Preprint
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Due to the importance of Phosphorus (P) on plant development and reproduction, global P security has emerged as a key factor towards global food security. Together with multiple agrochemicals, P-based fertilizers have become the pillars that sustain our food production systems. Therefore, improving the genetics and biology of key crops such as maize, rice, wheat and soybean to develop varieties better adapted to thrive under environments that present low phosphate (Pi) availability and that possess higher Pi-fertilizer use efficiency is imperative. In this review, we summarize the current understanding of Pi nutrition in plants, with particular focus on crops, and provide new perspectives on how to harness the ample repertoire of genetic mechanisms behind plant low-Pi adaptive responses that can be utilized to design smart low-Pi tolerant plants. We discuss on the potential of implementing more integrative, versatile and effective strategies by incorporating genome editing and synthetic biology approaches to reduce Pi-fertilizer input and enable global food security in a more sustainable way.
Article
A field experiment was conducted during the winter (rabi) seasons of 201011 and 201112 at Raipur, Chhattisgarh, to study the effect of customized fertilizer (11 : 27 : 0 : 6.6 : 0.5% of NPKS and Zn) on performance of chickpea (Cicer arietinum L.). Different doses of customized fertilizer were used in the study. The customized fertilizer (CF)combination of N, P, K, S and Zn mixturesignificantly influenced yield attributes, seed yield and nu- trient uptake. The highest seed yield (2.2 t/ha), stover yield (2.7 t/ha) and the highest net returns ( 42,883/ha) were obtained with the application of 150% CF dose. The uptake of N P K and Zn was also higher under this treat- ment. However, in terms of benefit: cost (B:C) ratio, application of 100% CF and 150% CF resulted in equal value, i.e. 2.9. Hence application of 100% CF dose can be considered as optimum, as it gave higher B:C ratio.
Chapter
The science, art and practice of growing plants are called agriculture. The history of agriculture began thousands of years ago. It began independently in various parts of the world depending on climatic conditions and terrains. Agriculture enabled the human population to expand several times beyond what could be supported by hunting and gathering. From the twentieth century, precision farming in contemporary agriculture increased productivity. Precision farming is a technology-enabled approach to farming that measures, observes and analyses individual fields and crops’ needs. This type of farming's main aim compared with traditional farming is where inputs are utilized in precise amounts to increase crop yields and profitability. The present work detailed about advancement and role of the Artificial Intelligence (AI) and Internet of Things (IoT) used in precision farming. The AI and IoT play a vital role in our modern day-to-day applications. The advantages and advancements of AI and IoT are applied in modern agriculture. This makes modern agriculture more precise and profitable. Some of the contemporary applications using AI and IoT in smart precision farming are discussed. In addition to that, important tools and techniques deployed in precision farming are also explained. The crucial benefits and the real-time devices used in the precision farming are also discussed in detail.
Article
Chemical fertilizers are used in modern agricultural practice to increase plant output. They possess anthropogenic compounds which are hazardous, result in poor soil quality, poor crop nutrition and pollutes the water table. Currently, food crops that lack in micro-nutrients (Zn, silicates and Se) can be enriched with micronutrients by use of fertilizers. Eco-friendly bio-fertilizers have been proved to provide a known population of microorganisms that create a mutual benefit to the plants & the rhizosphere soil. Nanomaterials are often used in plant fertilizer formulation, allowing for controlled release and targeted delivery of beneficial nanoscale components, as well as to boost plant production and reduce environmental pollutants. In the present study we identified a multipotent micronutrient solubilizing bacterium (MSB) - Pseudomonas gessardi and Pseudomonas azotoformans as a bio-fertiliser. Comparative study of the formulated MSB, with nanocomposite prepared with the soya chunks as natural carrier material and chemically synthesized cerium oxide was performed on the growth of fenugreek for its effectiveness. The SEM images of nanocomposite showed the non-uniform distribution of CeO2 in bio-inoculant with an average size of 25.24 nm. The current study deals with increase in the shoot and root length of the fenugreek plant with only 75 ppm of CeO2 in nanocomposite, thereby preventing bioaccumulation of Ce in soil. This work gives a potential use of CeO2 nanocomposite with MSB bio-inoculants which could be applied to soil deficient with the micronutrients that can enhance the crop yield.