Nerea González Gallardo

University of Alicante | UA · Organic Chemistry

Deep eutectic solvents (DESs) have been used for the first time as a sustainable medium in a ruthenium-catalyzed C-H activation reaction. This study describes an efficient, simple and straightfoward protocol...

A simple, fast, sensitive and green pretreatment method for determination of Cd, Co, Hg, Ni, Pb and V in oral and parenteral drug samples using inductively coupled plasma optical emission spectrometry (ICP OES) has been developed. According to United States Pharmacopoeia (USP), those metals must be reported in all pharmaceutical products for qualit...

This study describes, for the first time, the in situ generation of indium organometallic reagents in environmentally friendly deep eutectic solvents (DESs). The allylation process of different carbonyl compounds is achieved mediated by indium metal and using cheap allyl chloride derivatives. The unique DES properties allow to perform the reaction...

A strong σ-donor mesoionic carbene ligand has been synthesized and applied to four different palladium-catalyzed cross-coupling transformations, proving the catalyst/medium compatibility and the increased activity of this system over previous reports in Deep Eutectic Solvent medium. Some cross-coupling processes could be carried out at room tempera...

A versatile and DES‐compatible bipyridine palladium complex has been developed as a general pre‐catalyst for different cross‐coupling reactions (Hiyama, Suzuki‐Miyaura, Heck‐Mizoroki and Sonogashira) in deep eutectic solvents. Hydrogen bond capacity of the ligand allows to keep the excellent level of results previously obtained in classical organic...