Amenah I. A. Al-Nassiryكلية التربية للعلوم الصرفة جامعة تكريت · الكيمياء
Amenah I. A. Al-Nassiry
دكتوراه في الكيمياء اللاعضوية
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Introduction
Amenah l A Al-Nassiry
currently works at the الكيمياء, كلية التربية للعلوم الصرفة جامعة تكريت. امنه does research in Inorganic Chemistry.
Skills and Expertise
Publications
Publications (10)
We report reactions of Hg(II) ortho-cyano-aminothiophenolate coordination polymers, [HgfSC 6 H 3 XN(CN)g] n , with donor ligands. Addition of cyclic aromatic amines, such as pyridine (L), leads to breakdown of the polymeric structure to give mononuclear four-coordinate complexes, [Hgfj 2-SC 6 H 3 XN(CN)gL 2 ], while 2,2'-bipy and 1,10-phen (L 2) si...
Addition of 2-aminobenzothiazole (abt) and substituted derivatives to Hg(OAc)2 leads to the high yield formation of ortho-cyano-aminothiophenolate (ocap) complexes [Hg{SC6H3XN(C≡N)}]n (X = H, Me, Cl, Br, NO2) resulting from dehydrogenation...
Co( 2-Et 2 DT) 2 ] (1), [Cu( 2-Et 2 DT) 2 ] (2), [Co( 2-PyDT) 2 ] (3), [Cu( 2-PyDT) 2 ] (4), [Co( 2-PipDT) 2 ] (5) and [Cu( 2-PipDT) 2 ] (6) (Where Et 2 DT = diethyl dithiocarbamate; PyDT= pyrrolidine dithiocarbamate; PipDT = piperidine dithiocarbamate) were synthesized and characterized. The dithiocarbamate (DTC) behave as bidentate chelatin...
[Co(2-Et2DT)2] (1), [Cu(2-Et2DT)2] (2), [Co(2-PyDT)2] (3), [Cu(2-PyDT)2] (4), [Co(2-PipDT)2] (5) and [Cu(2-PipDT)2] (6) (Where Et2DT = diethyl dithiocarbamate; PyDT= pyrrolidine dithiocarbamate; PipDT = piperidine dithiocarbamate) were synthesized and characterized. The dithiocarbamate (DTC) behave as bidentate chelating ligands to afford tet...
Mixed ligand complexes of Zn (II) and Pd (II) have been prepared from piperidine
dithiocarbamate (PipDT) and amine ligand {2,20-bipyridine (Bipy),
1,10-phenanthroline (Phen), and 3-aminopyridine (3Apy)} to afford complexes
of the type [M(κ1-PipDT)(κ2-Bipy)] {MII Zn, Pd} (1,4), [M(κ1-PipDT)(κ2-Phen)]
(2,5), and [M(κ1-PipDT)(κ1-3Apy)2] (3,6). The rea...
New palladium(II) and platinum(II) 1,1'-bis(diphenylphosphino) ferrocene (dppf) complexes with heterocyclic N-acetamide co-ligands [Pt(1-O-amp)(1-N-amp)(2-dppf)], [M(2-dap)(2-dppf)], (M= Pd, Pt , ampH = N-(2-pyridyl-3-methyl)acetamide, dapyH2 = 2,6-diacetamidopyridine) have been prepared and characterized. The salts K2[PtCl2(sac)2] and Na2[PdC...
New series of phenyl mercury (II) complexes containing mixed ligands of 1,3-benzothiazole-2-thione (bztSH) and phosphine or amines as co-ligands were prepared. Treatment of bztSH with phenyl mercury (II) acetate in equivalent molar ratio afforded monounclear [ The prepared complexes were fully characterized by elemental analysis, molar conductivity...
A tetrahedral Hg(II) diethyl dithiocarbamate (Et2Dt) complex containing triphenylphosphine (PPh3) of the composition [HgCl(κ2‐Et2Dt)2(PPh3)] (1) is prepared. Furthermore, complex (1) is used as a synthone to prepare a novel series of complexes of the following composition [Hg(Et2Dt)L(PPh3)] {L = saccharinate (2), thiosaccharinate (3), benzisothiazo...
Room temperature addition of sodium saccharinate, Na(sac), to [MCl2(κ2-dppf)] (M = Pd, Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene) results in the formation of [MCl(sac)(κ2-dppf)] in which the sac ligand is coordinated in a monodentate fashion through nitrogen. All attempts to coordinate a second saccharinate ligand were unsuccessful. In contra...
