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a Static oil contact angle and water contact angle of nine different membrane materials, b three different ratios of oil contact angles for PS and CA. c Oil contact angle of membranes prepared with different PVDF concentrations
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The preparation of composite nanofibers often can make up for the shortage of single materials in the field of oil–water separation, including separation efficiency, mechanical properties and fine flexibility. The film materials prepared by doping inorganic nanoparticles have defects of poor stability and uneven dispersion of the fiber surface. In...
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Gap electrospinning is a facile technique to produce aligned nanofibers useful for many applications, but its potential has not yet been fully exploited in nature, leading to the fiber length still limited to several tens of centimeters at present. In this work, we report a breakthrough in the production of well-aligned nanofibers with record lengt...
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Citations
... To determine the oil adsorption capacity of the PDMS-pCA@CNWF, 10 g solvents (THF, DMF, chloroform, and hexane) and 150 mL water were added to a 200 mL beaker, and then 0.05 g of the PDMS-pCA@CNWF was placed in the mixture. After 5 min, the film was taken out [32]. The droplets suspended outside the adsorbent were air-dried. ...
Oil separation is crucial for avoiding environmental pollution originating from industrial wastewater and oil spillage; therefore, it is essential to develop techniques for oil separation. Herein, a new membrane with superhydrophilicity was synthesized by a facile, green, and low-cost method. First, cellulose non-woven fabric (CNWF) was modified by poly (catechin) (pCA), which has good antioxidant and antibacterial activities, to make it unaffected by ultraviolet light and to improve the stability of the structure. Then, hydrolyzed polydimethylsiloxane (PDMS) was coated on the pCA@CNWF surface via chemical bonding to make the composite hydrophobic. This durable superhydrophobic fabric can be used to separate various oil/water mixtures by gravity-driven forces with high separation efficiency (over 98.9%). Additionally, the PDMS-pCA@CNWF possesses the advantages of flexibility, high efficiency, and an outstanding self-cleaning performance, and demonstrates significant potential for applications in various environments, even under various harsh conditions, which make it very promising for the treatment of oil pollution in practical applications.
The rising widespread oil-impacted wastewater warrants an urgent call for innovative approaches to the handling of oily wastewater. A variety of techniques has been investigated to treat oil-impacted water, and they are found to be inefficient. Electrospun nanofibers emerge as the viable technique to treat oily wastewater precisely owing to their high specific surface areas and interconnected nanoscale pore structures. In this review, a brief background on the study is provided followed by the environmental pollution by the oily wastewater. Subsequent to that, the polyvinylidene fluoride (PVDF) modification methods are also presented followed by the physicochemical properties of both the electrospun PVDF blends and the PVDF-based composites. Furthermore, the performances of the PVDF-based composites in oil/water separation are described. It is concluded with the future prospects for using PVDF-based composites for oil/water separation.
Highly efficient oil/water separation ability is a prerequisite for the actual application of the membranes in oily sewage treatment, which is closely related to the surface feature and the porous structure of the membranes. In this work, the electrospun poly(vinylidene fluoride) (PVDF) porous fibers were firstly fabricated through blend-electrospinning with poly(vinyl pyrrolidone) (PVP) and then treating in distilled water. The results showed that the fibers exhibited the sponge-like porous structure, and a few PVP was reserved in the fibers due to the relatively good interaction between PVDF and PVP. The fibrous membrane exhibited high porosity, super-wettability with freely switchable super-lipophilicity and super-hydrophilicity. The oil adsorption capacities as well as the oil and water fluxes were measured, and the oil adsorption capacities were varied in the range of 22.7–76.0 g/g, and oil and water fluxes were 54,737.3 and 56,869.9 L/(m²h), respectively. Specifically, the PVDF porous fibrous membranes showed excellent separation abilities and they could highly efficiently separate oil from oil-in-water emulsions or separate water from water-in-oil emulsions, accompanied with the extremely high water or oil flux. This work confirms that the PVDF membranes composed of the porous fibers can be used in wastewater treatment.
