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The heat evolution rate (a–c) and cumulative heat (d) of OPC (1), OPC-CAH1 (2), and OPC-CAH2 (3) samples during the early stage of hydration.
Source publication
The effect of synthetic CAH (130°C; 8 h; CaO/(SiO 2 + Al 2 O 3 ) = 0.55; Al 2 O 3 /(SiO 2 + Al 2 O 3 ) = 0.1, 0.15) with different crystallinity on the hydration kinetics of OPC at early stages of hydration was investigated. Also, the formation mechanism of compounds during OPC hydration was highlighted. It was determined that the synthetic CAH acc...
Citations
... The formation of CSH products with different C/S ratios gave peaks at different temperatures. According to [27], calcium aluminate hydrates (CAH) significantly affect the specimens' early strength development and setting. On the other hand, increasing the temperature of the endothermic peaks from 70 to 100 °C with increasing the curing age is indicative of the removal of the adsorbed water in the calcium silicate and alumina gel, which is masked by the peak of removal of the hygroscopic water. ...
... This marks the dissolution of the added slag and its reactivity in the alkaline medium. Hence, when lime-rich material is added, the alkaline media releases Ca 2+ and Al (OH) 4− ions from the slag [27]. Within the same temperature range, it is partly possible to interface between the loss of the structural (OH − ) and the final stage of dehydration of CSH and hydrated aluminate phases. ...
Background
The goal of this study is to develop a feasible and sustainable solution to manage the use of industrial wastes of ground granulated blast-furnace steel slag (GGBS) activated by cement kiln dust (CKD) and quicklime (QL). Using activated GGBS in the manufacture of stabilized green bricks is still uncommon in Egypt in such applications. Five clay-based mixtures, each with varying replacement ratios (5–10, wt.%) of CKD and QL, were studied. Laboratory tests were conducted on cylindrical specimens made from these mixtures, which were left to cure for periods of up to 60 days. The raw materials and lab-made specimens were analyzed using particle size analysis, differential thermal analysis, X-ray fluorescence, and X-ray diffraction techniques. The physical and mechanical properties of the cured specimens were also determined and evaluated according to standard specifications. Furthermore, the durability of the cured specimens was evaluated against collapsibility in water.
ResuIts
It has been observed that adding QL and CKD to the stabilized green specimens of different mixes can enhance their engineering properties with curing age increasing. This is due to the pozzolanic reaction, which fills the pore structure with calcium silicate hydrates and calcium aluminate hydrates gel. The ratio of QL and CKD used significantly affected the engineering properties of the specimens. The study found that using 20% GGBS and 5% QL led to an increase in compressive strength (266 kg/cm ² ) at the density of (2.15 g/cm ³ ), while also water absorption was reduced (8%) to give superior results. When GGBS and CKD were combined, a higher content of CKD (10 wt.%) gave better results compared to (5 wt.%) CKD. Furthermore, the physical and mechanical properties of the tested specimens (MD 1, MD II, MD III and MD IV) met the acceptable limits of dry compressive strength (30–70 kg/cm ² ), water absorption (8–15%), and density (1.7–2 gm/cm ³ ), as specified by the Egyptian standard specifications for buildings used compressed earth blocks.
Conclusion
The CKD and QL act as alkali activators for GGBS and can be utilized in masonry construction.
... Throughout the hydration dynamic, the reaction between silicon and calcium ions results in the formation of calcium silicate hydrates (CSH), where this CSH could increase the compressive strength. 30,31 Here, the Al 3+ freely goes into the calcium silicate hydrate of the cement, where this replacement has a significant influence on different characteristics of the chemical performance of the cement. 32−36 2.2. ...
Throughout the life of a well, the cement sheath is exposed to several loadings, which can harm its key properties and impede its functions. These loadings become more significant at the early age of forming the cement sheath in which the properties of the cement are not completely developed. In this study, 10 cement samples with and without laponite particles were prepared and cured for five different periods (6, 12, 24, 48, and 72 h). The failure properties, petrophysical parameters, elastic properties, and density variation along the samples were examined. All of the samples were characterized by nuclear magnetic resonance and X-ray diffraction to understand the influence of the curing times on the cement properties. The results showed that the compressive and tensile strengths of both cement systems increased with the curing time and the incorporation of the laponite particle increased the strength of the cement. The permeability of both cement samples decreased with curing time, and the addition of laponite also decreased the permeability of the cement samples because of the presence of laponite-clay particles. The addition of laponite particles also increased the elasticity of the cement as indicated by the decrease in Young's modulus and the increase in Poisson's ratio. Logarithmic relationships were established to represent the changes in porosity, compressive strength, and tensile strength, while the changes in the other properties of permeability, Poisson's ratio, Young's modulus, and density variation were represented accurately with power-law equations.
... Nevertheless, these minerals can be prepared using calcium, alumina and silica sources. For example, Doneliene et al. [12] investigate the effect of synthetic hydrated calcium aluminate as an additive on the hydration properties of Ordinary Portland Cement. Qin et al. [13] prepared calcium aluminate hydrate in an autoclave. ...
The main goal of this study is to investigate the effects of the calcium aluminate hydrate (CA04) and the mixture of calcium aluminate and silicate hydrates (CA04 + CS04) on the compressive strengths and the microstructure of metakaolin-based geopolymer cements. Bauxite, rice husk and eggshells were calcined and mixed in proper amounts to prepare CA04 and CS04. Metakaolin has been substituted by 0, 5, 10, 15 and 20 wt% of CA04, 10 and 20 wt% of (CA04 + CS04) in the formulation of geopolymer cements. The clay-like solid materials were characterized by measuring their compressive strengths, the crystalline and amorphous phases were monitored using the X-ray diffractometry analysis, their microstructures were investigated using the scanning electron microscope and mercury intrusion porosimetry and the functional groups were studied using the infrared spectroscopy. The compressive strengths of geopolymer cements containing 0, 5, 10, 15 and 20 wt% of CA04 are 49.50, 57.17, 63.59, 38.79 and 35.05 MPa, respectively. Those containing 10 and 20 wt% of (CA04 + CS04) are 40.59 and 51.19 MPa, respectively. The average pore diameters of geopolymer cements containing 0, 10 and 20 wt% of CA04 are 11.80, 10.10, 12.20 nm, respectively. Whereas the one containing 20 wt% of (CA04 + CS04) is 10.80 nm. It appears that geopolymer cement with 10 wt% of CA04 and 20 wt% of (CA04 + CS04) have higher compressive strengths and lower average pore diameters. It was found that 10 and 20 wt% of CA04 and (CA04 + CS04), respectively, could be used as additives for the preparation of geopolymer cements with higher strength development.
... In addition, an increase in CBR values resulted in increasing BA content, with the optimum value being 60% BA content. This increase could be due to an adequate amount of calcium required for the formation of calcium silicate hydrate and calcium aluminate hydrate, which are the major compounds responsible for strength gain (Doneliene et al. 2016). The soaked CBR values were consistent with previous reports on biomass ashes, such as olive biomass bottom ash and rice husk ash, as additives for construction materials, in which the soaked CBR value first increased with the content of ash, but at excessive contents of ash, the soaked CBR decreased (Basha et al. 2005;Cabrera et al. 2018). ...
Physico-chemical properties and the environmental impacts were studied relative to the leaching of rubber fly ash and bottom ash. The pozzolanic properties of fly ash and bottom ash were confirmed by the chemical composition, including silicon oxides, calcium oxides, and aluminum oxides. The geo-technical characteristics of rubber wood fly ash and bottom ash, i.e., modified compaction, plasticity, and the soaked California Bearing Ratio, were evaluated to assess the feasibility of fly ash or bottom ash mixed with lateritic soil as aggregate materials for the subbase in road construction in order to optimize the replacement of lateritic soil by fly ash or bottom ash. The leachates from rubber fly ash and bottom ash did not exceed standard thresholds. The measured characteristics of fly ash or bottom ash mixed with lateritic soil were in good alignment with the effective engineering thresholds. Recommendations were developed for safe reuse of byproducts from rubber renewable power plant in subbase road construction.
... During the hydration process, the interaction between silica, alumina, and calcium ions produces various types of hydrates such as calcium silicate hydrates (CSH), calcium aluminate hydrates, and calcium aluminum silicate hydrates. 53 The reaction between cement and granite waste results in producing calcium silicate hydrate (CSH) crystals that contribute to the high compressive strength. 54 Where the aluminum readily enters the CSH of the cement, and this substitution has an important effect in several aspects of the chemical behavior of the cement. ...
Silica flour is one of the most commonly used material in cementing oil wells at high-temperature conditions of above 230°F to prevent the deterioration in the strength of the cement. In this study, replacement of the silica flour with the granite waste material at which an inexpensive and readily available material in cementing oil-wells is evaluated. Four cement samples with various amounts of silica flour and granite powder were prepared in this work. The effect of including the granite waste instead of silica flour in the cement elastic, failure, and petrophysical properties after curing the samples at 292°F and 3000 psi was examined. The results revealed that replacement of the silica flour with 40% by weight of cement (BWOC) optimized the cement performance and confirmed that this concentration of granite could be used as an alternative to the silica flour in oil-well cementing. This concertation of granite slightly improved the elastic properties of the cement. It also improved the cement compressive and tensile strengths by 5.7 and 39.3%, respectively, compared to when silica flour is used. Replacement of the silica flour with 40% BWOC of granite waste also reduced the cement permeability by 64.7% and porosity by 17.9%.
When the cement paste is subjected to stresses, the cement matrix and its characteristics are dramatically influenced, especially in the early ages of cement hydration when the cement properties have not yet settled. Nanoclay, which is made up of very small particles, was used to improve the properties of cement. In this study, the early-age performance of cement made with nanoclay powder for use in oil wells is assessed. Ten cement samples were made and cured at varying times (6, 12, 24, 48, and 72 hours), wherein 1% by weight of cement of nanoclay was used in five samples, and in the other five samples, there was no nanoclay present in the cement. Failure properties, petrophysical parameters, and elastic properties were studied for all the cement samples. Nuclear magnetic resonance (NMR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) were all used to describe the cement samples and determine how different curing times affected the cement’s mineralogical and microstructural features. The results displayed that compressive and tensile strengths were shown to increase with curing time for both the base (control) and nanoclay cement samples; however, the compressive and tensile strengths of the nanoclay cement samples were found to be greater than the base sample by 20.2% and 17.9%, respectively. This is due to the presence of more calcium silicate hydrate in these samples. Nanoclay cement had 76.9% lower permeability than control cement, which can be related to the capacity of the nanoclay particles to fill the microstructure dominating the base samples as curing time increased. Young’s modulus of the cement was lowered by 1.8%, while Poisson’s ratio was increased by 2.7% when nanoclay was incorporated. Nanoclay cement has a 29.2% smaller porosity than regular cement, and this porosity increases as the cement cures. The novelty of this work is that several properties of the class G cement were evaluated at the early stage of hydration, where the nanoclay particles were used to improve these properties.
