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Taxonomic relation of known non-toxic cereals, minor cereals, pseudocereals and other cereals [modified from Moreno et al. (2014)].

Taxonomic relation of known non-toxic cereals, minor cereals, pseudocereals and other cereals [modified from Moreno et al. (2014)].

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Amaranth (Amaranthus caudatus), quinoa (Chenopodium quinoa) and kañiwa (Chenopodium pallidicaule) have been cultivated in the Andean region of South America since Pre-Hispanic times. They are regarded as formidable nutritious alternatives due their high content of protein (rich in lysine), dietary fibre and bioactive compounds such as tocopherols,...

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Context 1
... (Amaranthus caudatus), quinoa (Chenopodium quinoa) and kañiwa (Chenopodium pallidicaule) do not belong to the same family (Poaceae or Graminea) as well-known cereals grains like wheat, oat or barley (Figure 1). Yet they can be ground and used as conventional cereals; there comes the name 'pseudo cereal'. ...
Context 2
... might shed some light on why corn starch with higher content of amylose leads to greater sectional expansion and lower shrinking at die point. Chinnaswamy and Hanna (1988) studied the effect of various contents of amylose in blends (10, 25, 50 and 65% amylose resulting from blending native starches with various contents of amylose), pure native starches (0, 25, 50 and 70% amylose) and amylose/amylopectin mixes on the sectional expansion ratio of extrudates (barrel temperature, 140 °C; screw speed, 160 rpm; feed rate, 60 g/min) (Figure 10). In general, the authors found that blends containing 50% amylose had greater sectional expansion than at lower or higher amylose contents. ...
Context 3
... general, the authors found that blends containing 50% amylose had greater sectional expansion than at lower or higher amylose contents. Chinnaswamy and Hanna (1988) also found that those blends with higher proportion of native starches, high in amylose (I<II<III<IV; Figure 10), had in average higher sectional expansion. Also, pure native starches showed the highest sectional expansion at 50% amylose, and among the lowest at 75% amylose. ...
Context 4
... pure native starches showed the highest sectional expansion at 50% amylose, and among the lowest at 75% amylose. The amylose/amylopectin mixes confirmed the previous results as it showed a sectional expansion peak at 50% amylose, and the lowest expansion of all at 0% and 100% amylose (Figure 10). Figure 10. ...
Context 5
... porous structure of extruded snacks results from the fast escape of water vapour (conventional extrusion) or carbon dioxide (supercritical fluid extrusion), imbedded in a starch-based molten fluid (or melt), at die point. The dynamic of nuclei formation, bubble growth and contraction has been modelled by Schwartzberg et al. (1995), Alavi et al. (2003aAlavi et al. ( , 2003b and Nowjee (2004) (Figure 11). Schwartzberg et al. (1995) explains that starch granules contain, naturally, microscopic pores thereby providing nuclei at which expansion of vapour bubbles start; this is the case of popcorn. ...
Context 6
... et al. (1995) explains that starch granules contain, naturally, microscopic pores thereby providing nuclei at which expansion of vapour bubbles start; this is the case of popcorn. However, starch granules and nuclei are inevitably destroyed during extrusion, and so few nuclei are present at die point resulting in large bubbles prone to coalesce (Figure 11B). In order to form bubbles, the pressure exerted by vapour in the pore () has to be sufficient to exceed the pressure at the outer surface of the domain ( ) (Figure 11B). ...
Context 7
... starch granules and nuclei are inevitably destroyed during extrusion, and so few nuclei are present at die point resulting in large bubbles prone to coalesce (Figure 11B). In order to form bubbles, the pressure exerted by vapour in the pore () has to be sufficient to exceed the pressure at the outer surface of the domain ( ) (Figure 11B). A detailed mathematical description of the necessary pressure to overcome the flow yield stress (∆ ), elastic stresses ( ) and surface tension (2/) is shown below : ...
Context 8
... interesting aspect is the time it takes before quasi- exponential bubble growth. According to Schwartzberg et al. (1995), it takes around 17 ms of very slow growth before rapid bubble expansion during the vapour-induced puffing of grains (Figure 12). There is, in fact, a critical ∆ at which expansion starts to occur. ...
Context 9
... slices should cover the entire cylindrical volume of the sample after reconstruction. Figure 13 shows what images look like at the different stages of processing: (1) raw images, (2) representative slice after reconstruction and (3) slices corresponding to particular volumes of interest (VOI). As explained by Trater et al. (2005), measurements may be very time-consuming, thus a certain number of VOI containing the entire sample cross-section must be chosen. ...
Context 10
... effect of WPC on the microstructure of the extrudates seemed dependent on the water content of mixture. For instance, an increase of WPC in extrudates at 26% water content of melt caused an increase of mean cell diameter and reduction in cell density while an equivalent increase of WPM in extrudates at 34% water content of melt led substantial decrease in mean cell diameter, wall thickness and increase in cell density (Figure 14). This shows the potential of this technique in order to conduct microstructure analysis in extruded snacks ( Babin et al., 2007;Parada et al., 2011). ...
Context 11
... (2009) used online monitoring setup of a Raman spectrometer and non-destructive ultrasound device during the extrusion (temperature profile: 90/90/90/90/100/110/120/90,100,110 °C) of flour blends containing chickpea, corn, oat, corn starch, tomato powder and ground raw hazelnuts. The author found that increasing temperature during extrusion produced various structural changes in the melt (Figure 15). When the temperature in section C rose above 90 °C, C-O-H bending of starch and C-O vibration of hydrocarbons chains band at 1125 cm -1 disappeared from the spectra as shown in Figure 15. ...
Context 12
... author found that increasing temperature during extrusion produced various structural changes in the melt (Figure 15). When the temperature in section C rose above 90 °C, C-O-H bending of starch and C-O vibration of hydrocarbons chains band at 1125 cm -1 disappeared from the spectra as shown in Figure 15. Ester groups, CH2 of lipids and primary, secondary and tertiary amide appeared to have gone through severe breakdown as temperature increased. ...
Context 13
... focused on the detection of few underlying or latent factors that explain most of the variation in the response variables thereby postulating models with high predicting abilities. As shown in the Figure 16, the overall goal of PLSR is to predict response variables, indirectly, by extracting latent variables T (X-scores) and U (Y-scores) from predictors and response variables, respectively. T is then used to predict U, and this predicted U is used to construct predictions for response variables. ...
Context 14
... though X- and Z-variables share no physical matrix size-dimension and, therefore, cannot be correlated directly to each other, they are connected via Y. The schematic construction of L-PLSR is shown in Figure 17. The L-PLSR may reveal patterns in Y that correspond to patterns in both X and Z thereby acting as a filter against noise in Y. Should X/Y/Z patterns be found, they could be used to predict Y from information easy to obtain (i.e., X and Z). ...
Context 15
... was defined as the slope of force- distance curve when compression was perpendicularly enforced under three-point bending. The universal testing machine (Instron 4465, Instron Ltd., High Wycombe, UK) was equipped with a loading cell (100 N) and a flat rectangular-shaped aluminium probe (Figure 18). Samples were positioned perpendicularly over a sample holder. ...
Context 16
... calculated contents of four chemical constituents in the dry flour blend [protein content of blend; ash content of blend; dietary fibre content of blend; sum content of main fatty acids of blend, FA (palmitic, oleic, linoleic and linolenic acid)] were also included as predictors in matrix X (II, III). After that, a two-block PLSR model (see Figure 16) was computed from the data now consisting of nine predictors and six response variables (SEI, stiffness, WCE, torque, pressure and total SME). The significances of the regression coefficients B in t-test were computed using the jack- knife technique (Martens and Martens 2000). ...
Context 17
... three-block PLSR (i.e., L-PLSR) model was computed using a different combination of predictors and response variables compared with those in the two-block model (see Figure 17). The predictors in the matrix X were content of amaranth or quinoa of solids, temperature of die, protein content of blend, ash content of blend, fibre content of blend and FA. ...
Context 18
... increased at increasing SS and decreasing WCM, while stiffness increased at decreasing SS and increasing WCM ( Table 14). Chemical constituents of the blend such as protein, ash, fibre and sum content of fatty acids seemed to have an overall inverse effect on SEI and proportional effect on stiffness (Table 14; Figure 19). Temperature of die was the process parameter with the lowest effect on SEI and stiffness (Table 14; Figure 19) (II, III). ...
Context 19
... constituents of the blend such as protein, ash, fibre and sum content of fatty acids seemed to have an overall inverse effect on SEI and proportional effect on stiffness (Table 14; Figure 19). Temperature of die was the process parameter with the lowest effect on SEI and stiffness (Table 14; Figure 19) (II, III). Total SME presented a strong positive and negative correlation with SEI and stiffness, respectively (II, III). ...
Context 20
... it comes to the most expanded extrudates containing kañiwa, stiffness was remarkably stable regardless of the content of kañiwa but SEI reduced considerably (Figure 20). For the most expanded extrudates containing Figure 19. Four-dimensional contour plots for sectional expansion index (SEI) and stiffness (STF) for extrudates containing amaranth (A), quinoa (Q), kañiwa (K) and lupine (L) as a function of screw speed (SS), water content of mixture (WCM) and contents of amaranth or quinoa of solids (CoF). ...
Context 21
... extrudates presented very stable porosity regardless of the content of amaranth, quinoa or kañiwa (Figure 21). Extrudates containing 50% kañiwa were the only ones showing a substantial reduction in porosity; this accounted for 73% compared to 82 and 85% porosity exhibited by extrudates containing amaranth and quinoa, respectively. ...
Context 22
... (Amaranthus caudatus), quinoa (Chenopodium quinoa) and kañiwa (Chenopodium pallidicaule) do not belong to the same family (Poaceae or Graminea) as well-known cereals grains like wheat, oat or barley (Figure 1). Yet they can be ground and used as conventional cereals; there comes the name 'pseudo cereal'. ...
Context 23
... might shed some light on why corn starch with higher content of amylose leads to greater sectional expansion and lower shrinking at die point. Chinnaswamy and Hanna (1988) studied the effect of various contents of amylose in blends (10, 25, 50 and 65% amylose resulting from blending native starches with various contents of amylose), pure native starches (0, 25, 50 and 70% amylose) and amylose/amylopectin mixes on the sectional expansion ratio of extrudates (barrel temperature, 140 °C; screw speed, 160 rpm; feed rate, 60 g/min) (Figure 10). In general, the authors found that blends containing 50% amylose had greater sectional expansion than at lower or higher amylose contents. ...
Context 24
... general, the authors found that blends containing 50% amylose had greater sectional expansion than at lower or higher amylose contents. Chinnaswamy and Hanna (1988) also found that those blends with higher proportion of native starches, high in amylose (I<II<III<IV; Figure 10), had in average higher sectional expansion. Also, pure native starches showed the highest sectional expansion at 50% amylose, and among the lowest at 75% amylose. ...
Context 25
... pure native starches showed the highest sectional expansion at 50% amylose, and among the lowest at 75% amylose. The amylose/amylopectin mixes confirmed the previous results as it showed a sectional expansion peak at 50% amylose, and the lowest expansion of all at 0% and 100% amylose (Figure 10). Figure 10. ...
Context 26
... porous structure of extruded snacks results from the fast escape of water vapour (conventional extrusion) or carbon dioxide (supercritical fluid extrusion), imbedded in a starch-based molten fluid (or melt), at die point. The dynamic of nuclei formation, bubble growth and contraction has been modelled by Schwartzberg et al. (1995), Alavi et al. (2003aAlavi et al. ( , 2003b and Nowjee (2004) (Figure 11). Schwartzberg et al. (1995) explains that starch granules contain, naturally, microscopic pores thereby providing nuclei at which expansion of vapour bubbles start; this is the case of popcorn. ...
Context 27
... et al. (1995) explains that starch granules contain, naturally, microscopic pores thereby providing nuclei at which expansion of vapour bubbles start; this is the case of popcorn. However, starch granules and nuclei are inevitably destroyed during extrusion, and so few nuclei are present at die point resulting in large bubbles prone to coalesce (Figure 11B). In order to form bubbles, the pressure exerted by vapour in the pore () has to be sufficient to exceed the pressure at the outer surface of the domain ( ) (Figure 11B). ...
Context 28
... starch granules and nuclei are inevitably destroyed during extrusion, and so few nuclei are present at die point resulting in large bubbles prone to coalesce (Figure 11B). In order to form bubbles, the pressure exerted by vapour in the pore () has to be sufficient to exceed the pressure at the outer surface of the domain ( ) (Figure 11B). A detailed mathematical description of the necessary pressure to overcome the flow yield stress (∆ ), elastic stresses ( ) and surface tension (2/) is shown below : ...
Context 29
... interesting aspect is the time it takes before quasiexponential bubble growth. According to Schwartzberg et al. (1995), it takes around 17 ms of very slow growth before rapid bubble expansion during the vapour-induced puffing of grains (Figure 12). There is, in fact, a critical ∆ at which expansion starts to occur. ...
Context 30
... slices should cover the entire cylindrical volume of the sample after reconstruction. Figure 13 shows what images look like at the different stages of processing: (1) raw images, (2) representative slice after reconstruction and (3) slices corresponding to particular volumes of interest (VOI). As explained by Trater et al. (2005), measurements may be very time-consuming, thus a certain number of VOI containing the entire sample cross-section must be chosen. ...
Context 31
... effect of WPC on the microstructure of the extrudates seemed dependent on the water content of mixture. For instance, an increase of WPC in extrudates at 26% water content of melt caused an increase of mean cell diameter and reduction in cell density while an equivalent increase of WPM in extrudates at 34% water content of melt led substantial decrease in mean cell diameter, wall thickness and increase in cell density (Figure 14). This shows the potential of this technique in order to conduct microstructure analysis in extruded snacks ( Babin et al., 2007;Parada et al., 2011). ...
Context 32
... (2009) used online monitoring setup of a Raman spectrometer and non-destructive ultrasound device during the extrusion (temperature profile: 90/90/90/90/100/110/120/90,100,110 °C) of flour blends containing chickpea, corn, oat, corn starch, tomato powder and ground raw hazelnuts. The author found that increasing temperature during extrusion produced various structural changes in the melt (Figure 15). When the temperature in section C rose above 90 °C, C-O-H bending of starch and C-O vibration of hydrocarbons chains band at 1125 cm -1 disappeared from the spectra as shown in Figure 15. ...
Context 33
... author found that increasing temperature during extrusion produced various structural changes in the melt (Figure 15). When the temperature in section C rose above 90 °C, C-O-H bending of starch and C-O vibration of hydrocarbons chains band at 1125 cm -1 disappeared from the spectra as shown in Figure 15. Ester groups, CH2 of lipids and primary, secondary and tertiary amide appeared to have gone through severe breakdown as temperature increased. ...
Context 34
... focused on the detection of few underlying or latent factors that explain most of the variation in the response variables thereby postulating models with high predicting abilities. As shown in the Figure 16, the overall goal of PLSR is to predict response variables, indirectly, by extracting latent variables T (X-scores) and U (Y-scores) from predictors and response variables, respectively. T is then used to predict U, and this predicted U is used to construct predictions for response variables. ...
Context 35
... though Xand Z-variables share no physical matrix size-dimension and, therefore, cannot be correlated directly to each other, they are connected via Y. The schematic construction of L-PLSR is shown in Figure 17. The L-PLSR may reveal patterns in Y that correspond to patterns in both X and Z thereby acting as a filter against noise in Y. Should X/Y/Z patterns be found, they could be used to predict Y from information easy to obtain (i.e., X and Z). ...
Context 36
... was defined as the slope of forcedistance curve when compression was perpendicularly enforced under three-point bending. The universal testing machine (Instron 4465, Instron Ltd., High Wycombe, UK) was equipped with a loading cell (100 N) and a flat rectangular-shaped aluminium probe (Figure 18). Samples were positioned perpendicularly over a sample holder. ...
Context 37
... calculated contents of four chemical constituents in the dry flour blend [protein content of blend; ash content of blend; dietary fibre content of blend; sum content of main fatty acids of blend, FA (palmitic, oleic, linoleic and linolenic acid)] were also included as predictors in matrix X (II, III). After that, a two-block PLSR model (see Figure 16) was computed from the data now consisting of nine predictors and six response variables (SEI, stiffness, WCE, torque, pressure and total SME). The significances of the regression coefficients B in t-test were computed using the jackknife technique (Martens and Martens 2000). ...
Context 38
... three-block PLSR (i.e., L-PLSR) model was computed using a different combination of predictors and response variables compared with those in the two-block model (see Figure 17). The predictors in the matrix X were content of amaranth or quinoa of solids, temperature of die, protein content of blend, ash content of blend, fibre content of blend and FA. ...
Context 39
... increased at increasing SS and decreasing WCM, while stiffness increased at decreasing SS and increasing WCM ( Table 14). Chemical constituents of the blend such as protein, ash, fibre and sum content of fatty acids seemed to have an overall inverse effect on SEI and proportional effect on stiffness (Table 14; Figure 19). Temperature of die was the process parameter with the lowest effect on SEI and stiffness (Table 14; Figure 19) (II, III). ...
Context 40
... constituents of the blend such as protein, ash, fibre and sum content of fatty acids seemed to have an overall inverse effect on SEI and proportional effect on stiffness (Table 14; Figure 19). Temperature of die was the process parameter with the lowest effect on SEI and stiffness (Table 14; Figure 19) (II, III). Total SME presented a strong positive and negative correlation with SEI and stiffness, respectively (II, III). ...
Context 41
... it comes to the most expanded extrudates containing kañiwa, stiffness was remarkably stable regardless of the content of kañiwa but SEI reduced considerably (Figure 20). For the most expanded extrudates containing Figure 19. Four-dimensional contour plots for sectional expansion index (SEI) and stiffness (STF) for extrudates containing amaranth (A), quinoa (Q), kañiwa (K) and lupine (L) as a function of screw speed (SS), water content of mixture (WCM) and contents of amaranth or quinoa of solids (CoF). ...
Context 42
... extrudates presented very stable porosity regardless of the content of amaranth, quinoa or kañiwa (Figure 21). Extrudates containing 50% kañiwa were the only ones showing a substantial reduction in porosity; this accounted for 73% compared to 82 and 85% porosity exhibited by extrudates containing amaranth and quinoa, respectively. ...

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