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Structural map of Sicily with location of the studied areas; the dark grey polygons represent volcanic areas. 

Structural map of Sicily with location of the studied areas; the dark grey polygons represent volcanic areas. 

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Article
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Small endhoreic (topografically closed) lakes represent a little percentage of continental waters but, in arid or sub-arid regions, they develop special ecosystems potentially prone to ecological involution due to climatic changes. The mandatory use of light, non-invasive field techniques is often required, especially in protected areas. In the pre...

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... Earth surface is covered by the hydrosphere for about 2/3, distributed between oceans and marine waters, representing 98% of the total water; the remaining 2% is arranged in continental ice, snow, lakes, rivers and ground waters. Only 0.4% of the total continental waters are stored in lakes, of which 80% is accumulated in the 40 largest lakes of the Earth (Encyclopaedia Britannica on line). Although small endhoreic (topographically closed) lakes represent a minor proportion of total continental waters, they constitute noteworthy appealing geoniches of great scientific and environmental interest. Most of little endhoreic lakes originated through processes which are very fast on a geological time scale, like meteoric impacts, volcanic phenomena, landslides, sink-holes or biotic activities such as plant accumulations and/or animal fabrics; due to their fast genesis these lakes often suffer metastable hydrological and morphological equilibria, easily altered by climatic and environmental changes. Differently with respect to lakes resulting from the "normal" hydro-geologic evolution of the landscape, they are abruptly inserted into independently- evolving catchment basins and their surface and underground drainage systems are not able to supply the amount of water needed to compensate the evaporation losses from the lake surfaces, eventually causing a complete desiccation during pro- longed drought periods. In arid or sub-arid regions endhoreic lakes allow the development of special ecosystems inserted in a dry landscape, characterized by a fragile hydrologic re- silience, seriously affected by climatic changes and anthropic activity [Nicholson 1998, Coe and Foley 2001, Jones et al. 2001, Roshier et al. 2001, Shi et al. 2002, Demlie et al. 2007]. The study of the hydro-morphological evolution of endhoreic lakes may give interesting insights in the preser- vation of geo-biodiversity and, more in general, of the natural landscape. A critical issue can arise while studying small lacustrine features (i.e. with areal extensions even minor than 1,000 m 2 ): the obligation of using light field techniques. This topic be- comes particularly relevant in the study of small lakes protected as nature reserves, where the very restrictive rules, often imposed by the local legislation for the protection of these environments, normally permit only field activities based on non-invasive techniques, like basic echo-sounder (fish-finders) and GPS mounted on small non-motorized vessels and/or underwater visual/photographic surveys carried out without any breathing apparatus. Lake Specchio di Venere and Lake Sfondato, both nature reserves located in South Italy, represent two paradigmatic ex- amples of small endhoreic lakes quickly formed and inserted in highly significant natural contexts, potentially prone to ecological involutions driven by environmental changes. Lake Specchio di Venere is a volcanic lake located on Pantelleria Island (Sicily Channel, Mediterranean Sea), Lake Sfondato a sink-hole lake formed at the beginning of 20 th century in Central Sicily [Madonia et al. 2006, and references therein]. Our work describes the morphological and bathymetric characteristics of the two lakes inferred from field analy- ses based on low environmental impact techniques, with a special attention to the influence of the survey methodolo- gies on the interpretative results. Bathymetric surveys and direct measurements of changes in lake surface elevations have been applied, in the Lake Sfondato case, to check the reliability of different hydrological balance hypotheses and to evaluate the role potentially played by environmental and climatic changes on the chances of survival of this lacustrine ecosystem. Sicily is located in the Central Mediterranean, along the main Eurasia-Nubia convergent plate boundary [Dewey et al. 1989, Serpelloni et al. 2007, Catalano et al. 2009], where three main elements mark both the collisional complex of Sicily and its offshore continuation (Figure 1): (i) the Hyblean Foreland outcropping in southeastern Sicily; (ii) the Caltanissetta Basin, a dynamic foredeep basin from the Late Miocene to the Quaternary; (iii) a complex chain, thrust towards the east and southeast, consisting of the Calabrian Arc and the Maghrebian thrust belt [Vallone et al. 2008 and references therein]. A powerful evaporitic succession, the Ges- soso-Solfifera Formation was deposited in the Caltanissetta Basin during the Messinian (Upper Miocene) salinity crisis in the Mediterranean Sea; from bottom to top, it consists of bedded diatomites (Tripoli Formation), limestones (some- times evaporitic), gypsum deposits interbedded with clay levels and Na-K salts [Mezzadri 1989]. Lake Specchio di Venere is located on Pantelleria Island (South Mediterranean Sea; Figure 2a), a Pleistocene strato- volcano whose subaerial portion is mainly composed of ex- plosive volcanic products ranging from trachytes to peralkaline rhyolites [Civetta et al. 1984]. Each major erup- tion results in the formation of calderas, the most recent ones are the "La Vecchia" and the "Monastero" calderas (known as "Cinque Denti"), whose formation is dated at 45- 50 ky [Rotolo et al. 2007, and references therein], in which Lake Specchio di Venere is located. The lake water is hyper- alkaline (pH ca. 9), showing a chloride-alkaline composition, with the dominance of Na and Cl ions typical of most thermal waters of Pantelleria, primarily determined by the mixing of marine, hydrothermal and meteoric waters [Parello et al. 2000]. This particular environment allows the growth of unusual mixed siliceous and carbonate microbialites, recently described by Cangemi et al. [2010]. Lake Sfondato (Figure 2b), located close to the city of Caltanissetta (Sicily, Italy), is a sink-hole lake formed at the beginning of 20 th century [Madonia et al. 2006, and references therein], in gypsum terrains pertaining to the Gessoso- Solfifera evaporitic formation. Its genesis was due to the dissolution of a salt diapir in the underground and the sub- sequent collapse of the overlying terrains. Topographic data were derived from the Sections no. 626910 (Lake Specchio di Venere) and 630040 (Lake Sfondato) of the Sicilian regional technical cartography (Car- tografia Tecnica Regionale, C.T.R.) at a scale of 1:10,000, and converted from the original Gauss-Boaga system to UTM WGS84 format. To compare hand-drafted bathymetric maps based on non−GPS surveys reported in the scientific litera- ture with more recent products derived from gridding and contouring software the former, available as image raster files, were transformed into geo-TIFF using the roto-trans- lational geo-referencing algorithm implemented in Quantum GIS software (release 1.0.2). Metric coordinates (UTM WGS84) for each of the depth measurement points recorded in the maps were read on the geo-TIFF, associating each point with the corresponding depth value. The obtained cartesian coordinate triplets (Easting, Northing, Depth) were elaborated with a kriging algorithm using Golden Software Surfer (release 8). A total of 6 differential GPS surveys ( 2 at Lake Specchio di Venere and 4 at Lake Sfondato) were carried out between October 2006 and May 2009 (Table 1), using a pair of Thales Magellan single frequency GPS units; the position data acquired were post-processed using Thales Mo- bile Mapper software. Depths were measured with a Garmin echosounder coupled to the antenna of the GPS rover re- ceiver rigidly mounted on a kayak (Figure 3). Errors were <0.5 m for position, 10 cm for depths in the range 0−10 m and 1 m for the depths >10 m. Depth measurements were randomly performed to avoid the generation of pseudo-ba- thymetric features due to alignments. During the May 2009 field campaign a video-photographic, free-diving survey of Lake Specchio di Venere bottom was performed using a wa- terproof digital camera. Lake level excursions were measured at Lake Sfondato using a fixed control point made of an iron nail plunged into outcropping bedrocks over the lake surface; meteorological data for hydrological calculations were taken from the database of the Agro-Meteorological Informative Service of the Regional Sicilian Government (SIAS) and were collected in the nearest available station (Caltanissetta). Prior to the advent of GPS techniques two bathymetric surveys were carried out at Lake Specchio di Venere. Both focused on the recognition of the general morphology of the lake floor for volcanological researches [Bocchi et al. 1988, Aiuppa et al. 2007]. Positioning of the measurement points were obtained using topographic instruments and a metric rope strung between the opposite shores of the lake. In recent years two more GPS−based surveys (in 2007 and 2009), gave new insights into lake bottom morphology, changing the focus from a volcanological to a sedimentary point of view. The latter was an extension of the 2007 survey, aimed to detail the southern shallow sector of the lake ...

Citations

... Until now, one of the most relevant features of this lake, i.e. the carbonate bank running all around its shoreline (Cangemi et al., 2010;Madonia et al., 2013), has been poorly studied. ...
... 450 m long and ca. 350 m wide, with a maximum depth of 12.5 m (Bocchi et al., 1988;Madonia et al., 2013) and steepest slopes on its northeastern side (Fig. 1 c-d). The surface area of the lake, extending up to ca 200.000 m 2 , is strongly controlled by water input by rainfall, runoff, and a contribution from the thermal aquifer and water output through seepage to groundwater (Aiuppa et al., 2007). ...
... The bank emerges as a white, interdigitated platform (Fig. 1e), ranging in thickness from ca 2 to ca 30 cm (Fig. 1i). It gently dips into the lake, forming a series of degrading terraces to a depth of 2 m, beyond which a steep scarp leads to the maximum depth of ca. 12 m (Madonia et al., 2013). ...
Article
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Specchio di Venere is a peculiar, ambient temperature, geothermal, alkaline lake, with lake water oversaturated in carbonate phase where siliceous stromatolites actively grow despite the undersaturation of silica phases. The most of the main sedimentary structures of this lake have been investigated in recent years, with the exception of the carbonate bank running along the south- western margin of the lake, which is the object of this study. Here we report on the mineralogical and geochemical characterisation of the carbonate bank, based on the study of two cores taken in the area mostly affected by the circulation of fluids of different origin. The ultimate results of our study suggest that silica gel deposits form inside the carbonate bank, following an Alkali-Silica Reaction. These new findings complete the general overview on the sedimentary processes acting in a Lake Specchio di Venere, whose origin is sometimes chemico-physical and sometimes strongly conditioned by microbial activity.
... The Specchio di Venere, also called Bagno dell' Acqua, is an alkaline, saline endorheic lake located at the northern rim of Cinque Denti caldera. According to Madonia et al. (2013), its morphology is a result of the accumulation of meteoric water into an endorheic depression formed as a result of volcanism sea level changes and ground deformation. The SV Lake is approximately 450 m by 350 m; its floor is divided into two distinct sectors: the southwestern one formed by an apparently flat submerged platform, (depth <1 m), and the northeastern one reaching a maximum depth of 12.5 m (Bocchi et al. 1988). ...
... In May 1996, the surface area of the lake was 200,000 m 2 and the volume was 925,000 m 3 (Aiuppa et al. 2007). Madonia et al. (2013) reported a surface area of 210,000 m 2 in 2007-2009. According to Aiuppa et al. (2007), seasonal factors can change the surface area and volume by about 15 and 7 %, respectively. ...
... To estimate the total volume of the SV Lake, a direct measurement with GPS of the perimeter of the lake was made. Then, re-drawing the bathymetric map of SV Lake performed by Madonia et al. (2013) and using Globbal Mapper 9.0® and Google Earth Pro® (2013), a total surface of 210,000 m 2 and a volume of 580,116 m 3 were calculated for SV Lake. Aiuppa et al. (2007) reported a larger volume for the lake (925,000 m 3 ), with a similar estimation for the lake surface (200,000 m 2 ). ...
Article
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We have mapped the diffuse CO2 efflux from the Specchio di Venere Lake area using the accumulation chamber method. We calculated a CO2 emission of 43 ± 5 t day−1 for the area studied, accounting for both diffuse degassing from soil and bubbling through the lake. We also present data on the water composition of Specchio di Venere Lake, the Polla 3 spring, and Liuzza well. On the basis of water chemistry, two physical-chemical processes, evaporation and mineral precipitation of carbonate species, are invoked to explain the CO2 degassing for the lake area.
... Presently, Pantelleria shows diffuse hydrothermal activity characterised by low temperature fumarole vents and hydrothermal springs. Lake Specchio di Venere is located inside the calderic depression of Caldera Cinque Denti in the north-eastern part of the island and shows a subecircular shape ca 450 m long and ca 350 m wide, with a maximum depth of 12.5 m (Madonia et al., 2013). The endorheic lake is located a few hundred of meters from the coast. ...
Article
Alkaline lakes like the hydrothermally affected lake Specchio di Venere (Pantelleria Island, Central Mediterranean) are typical geological settings harbouring calcified microbial mats. The present work is focused on the discrimination between biotic and abiotic processes driving carbonate precipitation in this lake, using hydrochemical, mineralogical and isotopic data.Hydrochemical analyses demonstrate that the lake is nearly 10−fold supersaturated with regard to aragonite and seasonally reaches hydromagnesite supersaturation. Microscopic observations depict organosedimentary laminated structures consisting of microbial communities and aragonitic precipitates, which are rather disseminated in pores than directly linked to microorganisms. Oxygen isotopic data indicate that authigenic carbonate crystallisation from evaporating water is the dominant precipitation process, further suggested by the absence of textural evidence of diagenetic processes. Conversely, the observed δ13C values reflect an influence of extracellular polymeric substances (EPS) on carbon fractionation during the precipitation process, due to the selective sequestration of 12C in the biomass. The above considerations suggest that at lake Specchio di Venere the carbonate precipitation is mainly of inorganic nature, but a minor role played by biologically influenced processes in microbial mats is not excluded.
... In the vicinity of both lakes there are thermal grounds with steam vents and hot springs and a high CO 2 soil flux. The SV lake has high alkalinity (~70 meq/L), whereas the EC lake is characterized by high concentration of dissolved CO 2 [Taran et al. 1998;Favara et al. 2001;Aiuppa et al. 2007;Mazot & Taran, 2009;Mazot et al. 2011;Madonia et al. 2013]. ...
... In the vicinity of both lakes there are thermal grounds with steam vents and hot springs and a high CO 2 soil flux. The SV lake has high alkalinity (~70 meq/L), whereas the EC lake is characterized by high concentration of dissolved CO 2 [Taran et al. 1998;Favara et al. 2001;Aiuppa et al. 2007;Mazot & Taran, 2009;Mazot et al. 2011;Madonia et al. 2013]. ...
... In the vicinity of both lakes there are thermal grounds with steam vents and hot springs and a high CO 2 soil flux. The SV lake has high alkalinity (~70 meq/L), whereas the EC lake is characterized by high concentration of dissolved CO 2 [Taran et al. 1998;Favara et al. 2001;Aiuppa et al. 2007;Mazot & Taran, 2009;Mazot et al. 2011;Madonia et al. 2013]. ...
Conference Paper
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The marine sector of the Campi Flegrei caldera has started to be monitored over the long-term with a seafloor equipment deployed in the Gulf of Pozzuoli from 2008. The equipment includes a set of geophysical, oceanographic and environmental sensors integrated in a marine platform that was specifically designed for real-time monitoring. This platform, named CUMAS (Cabled Underwater Multidisciplinary Acquisition System), was installed in the center of the Gulf at about 2.5 km south of Pozzuoli where the sea depth is about 100 m [Iannaccone et al., 2010]. The CUMAS system consists of a seafloor module connected by cable to a buoy (elastic beacon type) equipped with autonomous power supply systems, real-time datatransmission devices and a weather station. The core of CUMAS is the seafloor module that contains geophysical and oceanographic sensors, in particular, a three-component broadband seismometer, a best in class three axis MEMS accelerometer, a low-frequency hydrophone and a high-resolution sea bottom pressure recorder. A single-point acoustic, three-component, water-current meter and a water-temperature sensor were also installed to monitor some water local physical parameters. A set of status sensors, which also included a digital compass and a two-component digital tilt-meter, were added to track the attitude of the module over the course of the experiment. The marine monitoring system transmits the data in real-time and is integrated into the Monitoring Center in Naples managed by INGV-Osservatorio Vesuviano. A continuous GPS station has been installed since the end of 2011 on the top of the buoy. The elastic beacon buoy forms a structure which is rigidly connected by a mechanical cable to the ballast on the sea bottom, a submerged float at the base of the buoy maintains tension on the cable and ensure the overall buoyancy of the system. In this way, any vertical movement of the seafloor propagates rigidly to the emerged part of the buoy itself, allowing measurement of the vertical movement of the sea floor by the GPS station. The analysis of about 17 months of continuous GPS data, from January 2012 to May 2013, revealed an overall uplift of about 3-4 cm allowing a first measurement of vertical seafloor displacement in the Campi Flegrei caldera [De Martino et al., 2014]. A new opportunity to enhance the deployed system was given by a national project, EMSO-MedIT, which is providing the necessary resources to expand the data acquisition to other areas of the Gulf of Pozzuoli. New improved systems similar to CUMAS are going to be deployed in three additional marine sites of the Gulf of Pozzuoli and the existing tide gauges network will be renewed with state-of-art sensors. The overall new monitoring infrastructure will allow to extensively map the seafloor vertical displacement and to improve the interpretative models of the bradyseism phenomenon including a more accurate location of earthquakes in the marine areas and extending to lower magnitude values the detection of the seismic activity.
Article
Full-text available
Hydrothermal lakes are a very common feature in volcanic environments, and among these lake Specchio di Venere (Pantelleria island, Italy) has attracted the interest of several researchers due to its peculiar characteristics. With the aim of improving the knowledge of its mineralogy, our work pointed out the characterisation of the bottom lake sediments. We collected and analysed 5 sediments cores around the shoreline, determining the mineralogical phases, concentration of major, minor, and trace elements, and the isotopic composition of carbon and oxygen in the carbonate phases. Our findings remarked a general compositional homogeneity in both the vertical and horizontal distribution of mineral phases, with the exception of peculiar geological niches connoted by biological and hydrothermal activities. We wish to dedicate this paper to the memory of our colleague and friend Nancy Romengo, who shared with us the passion for the magic Pantelleria island