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![(Solid line) TL and (dash line) PL spectra of the ground [Ru(bpy)3]Cl2. Reprinted from: Sharipov G.L.; Tukhbatullin A.A.; Triboluminescence of tris(2,2′-bipyridyl)ruthenium(II) dichloride hexahydrate. Jour. of Lum. 2019, 215, 116691. Reprinted with permission from Elsevier [38].](profile/Julia-Goszyk/publication/356645630/figure/fig2/AS:1097406624075777@1638653536235/Solid-line-TL-and-dash-line-PL-spectra-of-the-ground-Rubpy3Cl2-Reprinted-from.png)
(Solid line) TL and (dash line) PL spectra of the ground [Ru(bpy)3]Cl2. Reprinted from: Sharipov G.L.; Tukhbatullin A.A.; Triboluminescence of tris(2,2′-bipyridyl)ruthenium(II) dichloride hexahydrate. Jour. of Lum. 2019, 215, 116691. Reprinted with permission from Elsevier [38].
Source publication
![Figure 22. Triboluminescence spectra of Mn(Ph3PO)2Br2 [41].](profile/Julia-Goszyk/publication/356645630/figure/fig3/AS:1097406624079872@1638653536306/Triboluminescence-spectra-of-MnPh3PO2Br2-41_Q320.jpg)
![Figure 22. Triboluminescence spectra of Mn(Ph 3 PO) 2 Br 2 [41].](profile/Julia-Goszyk/publication/356645630/figure/fig4/AS:1097406624088064@1638653536356/Triboluminescence-spectra-of-MnPh-3-PO-2-Br-2-41_Q320.jpg)
![Geometry of the [Cu(NCS)(py)2(PPh3)] molecule [10].](profile/Julia-Goszyk/publication/356645630/figure/tbl1/AS:1097406624088066@1638653536403/Geometry-of-the-CuNCSpy2PPh3-molecule-10_Q320.jpg)
Triboluminescence (TL) is a phenomenon of light emission resulting from the mechanical force applied to a substance. Although TL has been observed for many ages, the radiation mechanism is still under investigation. One of the exemplary compounds which possesses triboluminescent properties are copper(I) thiocyanate bipyridine triphenylphosphine com...
Citations
Research on luminescent tetrakis coordination compounds containing trivalent lanthanide ions (Ln 3+) has greatly increased in the last two decades owing to their unique spectroscopic properties and advantages over traditional tris compounds. In this review, we target the synthesis, crystal structure, and luminescence properties of Ln 3+ tetrakis coordination compounds Q[Ln(L) 4 ] as molecular light emitters with various classes of ligands (L: β-diketonates, carbacylamidophosphonates, sulfonylamidophosphonates, alkyldithiocarbamate and carboxylates) and different counterions (Q +). Moreover, we describe their special photophysical features and the potential of lanthanide tetrakis complexes in molecular design to obtain efficient luminescent materials. It is also discussed the relationship between structural data and experimental-theoretical approaches for the modeling of luminescence properties of this class of compounds. Additionally, we highlight some potential applications of Ln 3+ tetrakis coordination compounds as efficient luminescent materials.
A series of Pt(II) complexes bearing N-heterocyclic carbenes, [Pt(CN) 2 (Rim-Mepy)] (Rim-MepyH ⁺ = 3-alkyl-1-(4-methyl-(2-pyridinyl))-1H-imidazolium, R = Me, Et, i Pr, or t Bu), exhibits triboluminescence in the visible range from blue to red, as...
