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Single crystal density and elastic constants in eclogite a)

Single crystal density and elastic constants in eclogite a)

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Ultrahigh-pressure (UHP) eclogites often show strong plastic deformation and anisotropy of seismic properties. We report in this paper the seismic velocity and anisotropy of eclogite calculated from the crystallographic preferred orientations (CPOs) of constituent minerals (garnet, omphacite, quartz and rutile) and single crystal elastic properties...

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... are the best approximation to the chemical compo- sitions of garnet and omphacite in the experimentally deformed eclogites (GB244 & GB320) and the naturally deformed eclogites (D95-21 & MB98-08). The elastic constants are estimated to be the average of the elastic constants of their end members, assuming that the sec- ond-order elastic constants C ij are related linearly to the molar fraction of constituent end-members (Table 2) [34] . The seismic properties of garnet single crystal show that the directions of fast P-wave velocity (9.15 km/s) corre- spond to the <100> directions of garnet while the direc- tions of slow P-wave velocity (9.00 km/s) are the <111> directions (Figure 2a). ...

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... Amphibole exists in subducting slabs under lower-pressure and lower-temperature conditions than eclogite stability conditions, and in the middle to lower crust [33], whereas the LPO development of amphibole is known to produce a strong seismic anisotropy [18,[34][35][36]. Therefore, deformed retrograded eclogites may represent seismic velocity and anisotropy in relatively shallow subducting slabs [5,6,20,31,[37][38][39][40][41][42][43][44][45][46][47][48][49]. Measuring the LPOs of omphacite, amphibole, and garnet in retrograded eclogites can therefore be useful in understanding the seismic velocity and anisotropy of subducting slabs in subduction zones. ...
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Various rock phases, including those in subducting slabs, impact seismic anisotropy in subduction zones. The seismic velocity and anisotropy of rocks are strongly affected by the lattice-preferred orientation (LPO) of minerals; this was measured in retrograded eclogites from Xitieshan, northwest China, to understand the seismic velocity, anisotropy, and seismic reflectance of the upper part of the subducting slab. For omphacite, an S-type LPO was observed in three samples. For amphibole, the <001> axes were aligned subparallel to the lineation, and the (010) poles were aligned subnormal to foliation. The LPOs of amphibole and omphacite were similar in most samples. The misorientation angle between amphibole and neighboring omphacite was small, and a lack of intracrystalline deformation features was observed in the amphibole. This indicates that the LPO of amphibole was formed by the topotactic growth of amphibole during retrogression of eclogites. The P-wave anisotropy of amphibole in retrograded eclogites was large (approximately 3.7–7.3%). The seismic properties of retrograded eclogites and amphibole were similar, indicating that the seismic properties of retrograded eclogites are strongly affected by the amphibole LPO. The contact boundary between serpentinized peridotites and retrograded eclogites showed a high reflection coefficient, indicating that a reflected seismic wave can be easily detected at this boundary.
... AVs = 0.60%), which is similar to other dry (i.e. mostly Grt and Omp) eclogite (e.g., Abalos et al., 2011;Bascou et al., 2001;Kim et al., 2018;Llana-Funez and Brown, 2012;Sun et al., 2012a;Wang et al., 2009;Wang et al., 2005b;Zhang et al., 2008). The second least anisotropic sample is P1502-5 (AVp = 2.45%, max. ...
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... Investigating the seismic properties (i.e., P-and S-wave velocities and their anisotropies) of eclogite is crucial for constraining the presence of eclogite in the deep crust and upper mantle, which has profound implications for interpreting the composition, density, and thermal and mechanical structures of the subducted crust, continental lithosphere, and upper mantle, as well as for reconstructing the geodynamic evolutions of the subduction and collision zones [9][10][11][12][13][14][15][16][17][18][19]. For this purpose, numerous previous studies have addressed the seismic properties of dry eclogite (i.e., bi-mineralic eclogite), e.g., [20][21][22][23][24][25][26][27]; retrograded eclogite (i.e., amphibolized eclogite), e.g., [16,19,23,[28][29][30][31]; epidote/glaucophane eclogite [12,14,28]; lawsonite eclogite [13,32]. However, because of the sample rarity, the seismic properties of the olivine and orthopyroxene rich eclogite have not been studied yet. ...
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... The single-crystal seismic anisotropy of garnet (< 1%) is weaker than that of omphacite (up to ~20% for P-wave seismic anisotropy and ~15% for S-wave seismic anisotropy: Bascou et al., 2001). The seismic anisotropy of eclogite is generally reported to be less than ~5%, which can be ascribed predominantly to the properties http://www.springer.com/journal/12303 of omphacite ( Bascou et al., 2001Bascou et al., , 2002Zhang et al., 2008;Ábalos et al., 2011;Cao et al., 2013;Worthington et al., 2013). Here we report the microstructures of a pristine eclogite that contains alternating garnet-and omphacite-rich layers from northern Victoria Land (NVL) in Antarctica. ...
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... [3] Previous studies on seismic properties of blueschist and eclogite mainly focused on the seismic velocities and anisotropies of these rocks, and most of these investigations were concentrated on medium-and high-temperature eclogites, which are simply composed of a bi-mineralic assemblage of garnet and omphacite [e.g., Abalos et al., 2011;Bascou et al., 2001;Christensen and Mooney, 1995;Fountain et al., 1994;Kern et al., 1999Kern et al., , 2002Llana-Fúnez and Brown, 2012;Mauler et al., 2000;Rudnick and Fountain, 1995;Sun et al., 2012;Wang et al., 2005Wang et al., , 2009Warner et al., 1996;Zhang et al., 2008]; only a few recent studies focused on blueschist [Bezacier et al., 2010;Fujimoto et al., 2010;Kim et al., 2013;Mookherjee and Bezacier, 2012]. Based on these studies, some general conclusions have been reached: (1) eclogite commonly shows very high P-wave (8.0-8.6 km/s) and S-wave velocities (4.5-4.9 km/s) comparable to those of mantle peridotite [Rudnick and Fountain, 1995], which are significantly higher than those of blueschist (V p = 7.3-7.6 ...
... We used the elastic stiffnesses from Bezacier et al. [2010] for glaucophane, Ryzhova et al. [1966] for epidote, Vaughan and Guggenheim [1986] for phengite, and McSkimin et al. [1965] for quartz. To obtain the appropriate single-crystal elastic properties for omphacite (Di 0.5 ,Jd 0.4 ,Ae 0.1 ) and garnet (Grs 0.25 ,Pyr 0.20 ,(Alm,Spss) 0.55 in eclogite) (Grs 0.35 ,Pyr 0.05 , (Alm,Spss) 0.60 in blueschist), an average of the elastic stiffness of the end-members was used, assuming that the elastic stiffnesses C ij were linearly related to the molar fraction of constituent end-members [Collins and Brown, 1998;Zhang et al., 2008]. The elastic constants for end-members of omphacite and garnet were from Aleksandrov et al. [1964]; Bass [1989]; Kandelin and Weidner [1988]; Levien et al. [1979]; O'Neill et al. [1991]; Wang and Simmons [1974]. ...
... [32] The patterns of P-wave anisotropy in omphacite aggregate resemble those of glaucophane and epidote, which show the fastest and slowest P-wave velocities parallel to the lineation and normal to the foliation, respectively (Figures 11 and S6). These results are consistent with those of most previous calculations and laboratory observations of deformed eclogites [Abalos et al., 2011;Bascou et al., 2001;Mauler et al., 2000;Zhang et al., 2008]. The patterns of S-wave polarization anisotropy (AVs) are more complicated, and the polarization direction of the fast shear wave is mostly sub-parallel to lineation for a foliation-normal incident seismic ray, except for the sample 08BSY-38. ...
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... They provide a unique opportunity for studying the seismic anisotropy of subduction zone under HP/UHP conditions. Great efforts and progress have been made on documenting the seismic properties of eclogites from the continental collision zones in the past (e.g., Zhang et al., 2008;Wang et al., 2005a, b;Ji et al., 2003;Kern et al., 2002;Bascou et al., 2001). However, there are rare studies integrating both results from laboratory measurements and theoretical calculations Zhang et al., 2008). ...
... Great efforts and progress have been made on documenting the seismic properties of eclogites from the continental collision zones in the past (e.g., Zhang et al., 2008;Wang et al., 2005a, b;Ji et al., 2003;Kern et al., 2002;Bascou et al., 2001). However, there are rare studies integrating both results from laboratory measurements and theoretical calculations Zhang et al., 2008). Combination of laboratory measurement and theoretical calculation of seismic properties will enhance our understanding of the earth's seismic anisotropy and provide reasonable interpretation of field observations. ...
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Rheology of rocks controls the deformation of the Earth at various space-time scales, which is crucial to understand the tectonic evolution of continental lithosphere. Researches of rock rheology are mainly conducted via high-pressure and high-temperature rheological experiments and multi-scale observations and measurements of naturally deformed rocks. At present, a large amount of data from such kinds of studies have been accumulated. This paper first provides an up-to-date comprehensive review of the rheological mechanisms, fabric types and seismic properties of the main rock-forming minerals at different depths of continental lithosphere, including olivine, orthopyroxene, clinopyroxene, amphibole, plagioclase, quartz and mica. Then, progress in high-pressure and high-temperature experiments and natural deformation observations is introduced, mainly regarding the rheological strength and behavior, seismic velocity and anisotropy of lithospheric mantle peridotite, eclogite, mafic granulite, amphibolite and felsic rocks. Finally, by taking the Tibetan Plateau as an example, the application of rock rheology for quantitative interpretation of seismic anisotropy data is discussed. The combination of mineral deformation fabrics and seismic anisotropy is expected to make an important breakthrough in understanding the rheological properties and structure of continental lithosphere.
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The upper crust within collisional orogens is very heterogeneous both in composition and grade of deformation, leading to very variable physical properties at small scales. This yields difficulties for seismic investigations of tectonic structures at depth since local changes in elastic anisotropy cannot be detected. In this study, we show elastic anisotropies of the range of typical lithologies within deformed upper crustal rocks in the Alps. Furthermore, we aim to model average elastic anisotropies for these rocks and their changes with increasing depth due to the closure of microcracks. We therefore sampled rocks in the Adula Nappe of the central Alps, which is typical for upper crust in collisional orogens. The two major rock types found are orthogneisses and paragneisses, however, small lenses of metabasites and marbles also occur. Crystallographic preferred orientations (CPOs) and volume fractions of minerals in the samples were measured using time-of-flight neutron diffraction. Combined with single crystal elastic anisotropies these were used to model seismic properties of the rocks. The sample set shows a wide range of different seismic velocity patterns even within the same lithology, due to the heterogeneity of deformed upper crust. To approximate an average for these upper crustal units, we picked common CPO types of rock forming minerals within the gneiss samples, which represent the most common lithology. These data were used to determine an average elastic anisotropy of a typical upper crustal rock within the Alps. Average mineral volume percentages within the gneiss samples were used for the calculation. In addition, ultrasonic measurements of elastic anisotropies of the samples at increasing pressures were performed. These measurements, as well as the microcrack pattern determined in thin sections of the samples were used to model the closure of microcracks in the average sample at increasing depth. At ≈740 MPa microcracks are assumed to be closed yielding average elastic anisotropies of 4 % for the average gneiss. This value is an approximation, which can be helpful for seismic models at a lithospheric scale. At a crustal or smaller scale, however, it is an oversimplification and local lithological as well as deformational changes shown by the range of elastic anisotropies within the sample set have to be considered.