Figure 1 - uploaded by Anatoly Romanenko
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SEM images of polyaniline@MIL material (left) and free polyaniline (right), prepared in the similar reaction conditions. The octahedral shape of the crystal is similar to the MIL compound.
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We investigated current-voltage (I-V) characteristics of bulk polyaniline and aniline polymerized inside nanopores of chromium terephthalate dielectric matrix MIL-101. The temperature dependence of electrical conductivity σ(T) of these materials are described by the fluctuation-induced tunneling model (FIT), which means that the main contribution t...
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... scanning electron microscopy (SEM) images also confirm that polyaniline@MIL composite sample retain the crystalline morphology of MIL-101, unlike free polyaniline sample (Fig. 1). More importantly, no free amorphous polyaniline was found on the surface of MIL-101 crystals, which suggests that the polymerization of the aniline took place predominantly inside the MIL ...
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