Figure - available from: Applied Organometallic Chemistry
This content is subject to copyright. Terms and conditions apply.
Perspective view of compound Cu‐N3 showing the atom numbering. Selected bond distances (Å) and angles (°): Cu(1)‐N(1), 2.089(2); Cu(1)‐N(2), 2.132(2); Cu(2)‐N(1), 2.068(2); Cu(2)‐N(2), 1.980(2); Cu(1)‐Cu(2), 3.146; N(1)‐Cu(1)‐N(2), 90.78(2); N(1)‐Cu(2)‐N(2), 96.70(2).
Source publication
Three neutral Cu(I) complexes bearing 2,6‐dimethylphenyl isocyanide (CNXyl) and different triatomic pseudohalogens (SCN⁻, OCN⁻ and N3⁻) as ligands were efficiently synthesized and characterized. The solid‐state structures were unambiguously determined through single‐crystal X‐ray diffraction, revealing unexpected bridging coordination modes in the...
Similar publications
The title compound, [Co(C3H4N2)(C30H30N10)](BF4)2, is a five-coordinate CoII complex based on the neutral ligands tris[(1-benzyltriazol-4-yl)methyl]amine (tbta) and imidazole. It exhibits a distorted trigonal bipyramidal geometry in which the equatorial positions are occupied by the three N-atom donors from the triazole rings of the tripodal tbt...
