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Major and trace elements v. Mg no. plot for the Neoproterozoic mafic rocks from western Hunan. 

Major and trace elements v. Mg no. plot for the Neoproterozoic mafic rocks from western Hunan. 

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The Neoproterozoic mafic rocks in western Hunan, South China, form a NNE-striking mafic rock belt for which outcrops are found predominantly in Guzhang, Qianyang and Tongdao. Samples from Qianyang and Tongdao yielded ion microprobe U–Pb zircon ages of 747±18 Ma and 772±11 Ma, respectively. The mafic rocks are geochemically divided into two subtypes...

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... mafic rocks from Qianyang and Guzhang have Mg no. ranging from 65 to 25, suggesting that fractional crystallization is an important factor in the evolution of the mafic magmas in the area. Moreover, the Zr/Nb-Zr plot (Fig. 4) implies that the slight chemical differences between samples would reflect variations in the degree of fractional crystallization rather than partial melting. The effects of fractional crystallization for the mafic rocks from western Hunan are indicated by the compositional variations of both major and trace elements with respect to Mg no. as fractionation index (Fig. 7). CaO, CaO/Al 2 O 3 and CaO/TiO 2 increase with the increased Mg no. (Fig. 7), which indicates the crystallization of clinopyroxene (Class et al. 1994). It should be pointed out that two types of correlations with Mg no. have been shown by some elements and element ratios (Fig. 7). Under Mg no. ≥ 45 (predominantly including the ultramafic and mafic rocks), negative correlations are revealed by TiO 2 , Al 2 O 3 , Na 2 O+K 2 O and V versus Mg no., whereas positive correlations exist between Al 2 O 3 /TiO 2 and Mg no., implying the fractional crystallizations of olivine and clinopyroxene. Under Mg no. < 45, however, there are positive correlations of TiO 2 and V versus Mg no., relatively constant Na 2 O + K 2 O and Al 2 O 3 versus Mg no., and negative correlation of Al 2 O 3 /TiO 2 versus Mg no., probably indicating the fractionation of Fe-Ti oxides. Incompatible trace elements (e.g. Zr, Nb and Y) show negative correlations with Mg no., while the compatible trace elements (e.g. Ni and Cr) have positive correlations with Mg no., supporting the fractionation of olivine and pyroxene. Furthermore, a Eu anomaly is lacking in most mafic samples (Fig. 5), indicating that plagioclase fractionation was not important in the mafic magma ...
Context 2
... mafic rocks from Qianyang and Guzhang have Mg no. ranging from 65 to 25, suggesting that fractional crystallization is an important factor in the evolution of the mafic magmas in the area. Moreover, the Zr/Nb-Zr plot (Fig. 4) implies that the slight chemical differences between samples would reflect variations in the degree of fractional crystallization rather than partial melting. The effects of fractional crystallization for the mafic rocks from western Hunan are indicated by the compositional variations of both major and trace elements with respect to Mg no. as fractionation index (Fig. 7). CaO, CaO/Al 2 O 3 and CaO/TiO 2 increase with the increased Mg no. (Fig. 7), which indicates the crystallization of clinopyroxene (Class et al. 1994). It should be pointed out that two types of correlations with Mg no. have been shown by some elements and element ratios (Fig. 7). Under Mg no. ≥ 45 (predominantly including the ultramafic and mafic rocks), negative correlations are revealed by TiO 2 , Al 2 O 3 , Na 2 O+K 2 O and V versus Mg no., whereas positive correlations exist between Al 2 O 3 /TiO 2 and Mg no., implying the fractional crystallizations of olivine and clinopyroxene. Under Mg no. < 45, however, there are positive correlations of TiO 2 and V versus Mg no., relatively constant Na 2 O + K 2 O and Al 2 O 3 versus Mg no., and negative correlation of Al 2 O 3 /TiO 2 versus Mg no., probably indicating the fractionation of Fe-Ti oxides. Incompatible trace elements (e.g. Zr, Nb and Y) show negative correlations with Mg no., while the compatible trace elements (e.g. Ni and Cr) have positive correlations with Mg no., supporting the fractionation of olivine and pyroxene. Furthermore, a Eu anomaly is lacking in most mafic samples (Fig. 5), indicating that plagioclase fractionation was not important in the mafic magma ...
Context 3
... mafic rocks from Qianyang and Guzhang have Mg no. ranging from 65 to 25, suggesting that fractional crystallization is an important factor in the evolution of the mafic magmas in the area. Moreover, the Zr/Nb-Zr plot (Fig. 4) implies that the slight chemical differences between samples would reflect variations in the degree of fractional crystallization rather than partial melting. The effects of fractional crystallization for the mafic rocks from western Hunan are indicated by the compositional variations of both major and trace elements with respect to Mg no. as fractionation index (Fig. 7). CaO, CaO/Al 2 O 3 and CaO/TiO 2 increase with the increased Mg no. (Fig. 7), which indicates the crystallization of clinopyroxene (Class et al. 1994). It should be pointed out that two types of correlations with Mg no. have been shown by some elements and element ratios (Fig. 7). Under Mg no. ≥ 45 (predominantly including the ultramafic and mafic rocks), negative correlations are revealed by TiO 2 , Al 2 O 3 , Na 2 O+K 2 O and V versus Mg no., whereas positive correlations exist between Al 2 O 3 /TiO 2 and Mg no., implying the fractional crystallizations of olivine and clinopyroxene. Under Mg no. < 45, however, there are positive correlations of TiO 2 and V versus Mg no., relatively constant Na 2 O + K 2 O and Al 2 O 3 versus Mg no., and negative correlation of Al 2 O 3 /TiO 2 versus Mg no., probably indicating the fractionation of Fe-Ti oxides. Incompatible trace elements (e.g. Zr, Nb and Y) show negative correlations with Mg no., while the compatible trace elements (e.g. Ni and Cr) have positive correlations with Mg no., supporting the fractionation of olivine and pyroxene. Furthermore, a Eu anomaly is lacking in most mafic samples (Fig. 5), indicating that plagioclase fractionation was not important in the mafic magma ...

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Citations

... Data for primitive mantle, N-MORB, OIB and E-MORB are from Sun and McDonough (1989). Kay (1978); Hart (1984Hart ( , 1988; Zindler and Hart (1986); Burton-Johnson et al. (2020) and Wang et al. (2008Wang et al. ( , 2018Wang et al. ( , 2020aWang et al. ( ,b, 2021a at $185-145 Ma, $136-112 Ma and $95-85 Ma, respectively. The presence of xenocrystic grains among these rocks potentially indicates crustal contamination en route. ...
... Multi-stage folds and faults were formed during the Wuling, Caledonian, Hercynian and Indosinian-Yanshanian orogenic episodes and are broadly distributed in the WHEGMB (Fig. 1c;Li et al., 2014). Regional magmatism occurred in the Neoproterozoic era, but it was minor (840-503 Ma; Zhang et al., 2014;Wang et al., 2008) and unrelated to Zn-Pb mineralization (Yang and Lao, 2007). ...
... There have been many studies on these rocks in the Jiangnan Orogen (eg. Chen et al., 2018;Ge et al., 2001;Li et al., 1999;Wang et al., 2007;Yao et al., 2019;Zhao et al., 2018). The results indicate that these rocks consist of two groups with distinct ages and tectonomagmatic affinities, separated by an unconformity that marks the ca. ...
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... The South China Block (SCB) comprises the Yangtze Block to the north-west and the Cathaysia Block to the south-east (Figure 1a), and the final amalgamation of the two blocks formed the Jiangnan Orogen Li et al., 2013aLi et al., , 2016Shu et al., 2015Shu et al., , 2021Wang et al., 2004Wang et al., , 2006Wang et al., , 2008Wang, Shu, et al., 2012;Yao et al., 2017;Zhao, 2015;Zheng et al., 2007Zheng et al., , 2008, followed by post-collision collapse or orogenic extension along the orogenic belt (Li et al., 1995;Wang, Shu, et al., 2012). Although this orogen is now widely accepted to have formed during the early middle Neoproterozoic (Han et al., 2020;Li et al., 2016;Wang et al., 2007;Wang et al., 2013;Wei & Zhao, 2020;Zhang et al., 2013Zhang et al., , 2020Zhao & Cawood, 2012;Zheng et al., 2007Zheng et al., , 2008), the precise time of assembly and the evolution history of the Jiangnan Orogen still remain controversial (Sun et al., 2018). ...
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... Numerous ca. 770 Ma mafic dykes and sills in the SCC have been reported over the last two decades (Ge et al., 2001;Kou et al., 2018;Liu et al., 2020Liu et al., , 2021Wang et al., 2008Wang et al., , 2009Zhou et al., 2007). They are widely distributed in the Yangtze block, intruding the Banxi Group and its equivalents (Figure 1; HNBGMR , 1988). ...
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... Zhao 2015). After the collision, the detachment and sinking of oceanic crust, coupled with asthenospheric upwelling, led to post-orogenic extension at c. 815-750 Ma, responsible for the formation of c. 760 Ma OIB-like mafic rocks in western Hunan Province (Wang et al. 2008). Therefore, it is reasonable to conclude that the metasomatites formed during the post-orogenic stage (c. ...
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... Metamorphism is a material accumulation and texture alteration phenomenon that happens as a result of physiological symptoms in hard rock caused by events such as crust movement, magma activity, or changes in the earth's thermal fluid. An acute anticline physically separates the Neoproterozoic metamorphosed strata of the Jiangnan Orogenic Belt into two low-grade mutated phases (BGMRHN 1988;BGMRJX 1984;BGMRGX 1985;BGMRZJ 1989;Guo et al. 1980;Zhou and Zhu 1993;Charvet et al. 1996;Wang et al. 2007Wang et al. , 2008aWang et al. , 2008bZhao 2015). A metamorphic facies series is a series of metamorphic zones, and the Barrovian is the most common. ...
... Volcaniclastics are sedimentary rocks that occur when lava erupts into the air. Despite being previously assumed to be Recent zircon U-Pb age analyses in the Mesoproterozoic have demonstrated that these groups arose during the early Neoproterozoic (850-820 Ma) (Yang et al. 1994;Wang et al. 2007Wang et al. , 2008aWang et al. , 2008bGao et al., 2008Gao et al., , 2010aGao et al., , 2011aZhou et al. 2009;Wang et al. 2010Wang et al. , 2012b. They have similar deformation and structural properties, with high-angle tight linear and isoclinal overturned folds being the most prevalent. ...
... They have similar deformation and structural properties, with high-angle tight linear and isoclinal overturned folds being the most prevalent. ((BGMRZJ 1989;BGMRJX 1984;BGMRHN 1988;BGMRGX 1985;Zhou et al. 2004;Wang et al. 2007Wang et al. , 2008aWang et al. , 2008bZhao and Cawood 2012). However, The Danzhou Group in north Guangxi Province, the Xiajiang Group in northeast Guizhou Province, the Banxi Group in Hunan Province, the Dengshan Group in Jiangxi Province, and the Likou Group/Jingtan Formation in south Anhui Province and the Heshangzhen Goup in northwest Zhejiang Province are among the metamorphic sequences above the unconformity and are only deformed into relatively simple, nearby vertical and open folds (BGMRJX 1984;BGMRHN 1988;BGMRGX 1985;Zhou et al. 2004;Wang et al. 2007Wang et al. , 2008aWang et al. , 2008bZhao and Cawood 2012) (Fig. 1). ...
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... In addition, abundant basic and bimodal volcanic rocks of late Yanshanian ages (ca. 136-83 Ma) also occur in this area (Jia et al., 2003;Wang et al., 2008). These S-type granitoids and mafic rocks have been interpreted to be formed in an extensional tectonic setting (Jia et al., 2003;Li et al., 2009;Li and Li, 2007;Wang et al., 2008Wang et al., , 2014Xu et al., 2009). ...
... 136-83 Ma) also occur in this area (Jia et al., 2003;Wang et al., 2008). These S-type granitoids and mafic rocks have been interpreted to be formed in an extensional tectonic setting (Jia et al., 2003;Li et al., 2009;Li and Li, 2007;Wang et al., 2008Wang et al., , 2014Xu et al., 2009). ...
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Hydrothermal alteration commonly occurs in lode gold deposits, and contributes to metal precipitation through water–rock interactions. In the Wangu gold deposit in northeastern Hunan, South China, bleaching of slates enclosing auriferous quartz veins widespreadly occur, with the colour transformed from dark-grey into pale yellow-grey. The bleaching has been used to guide gold exploration, but its nature and genesis, as well as the relationship with gold mineralization, remains unclear. Field and petrographic work, combined with Tescan Integrated Mineral Analyzer (TIMA), demonstrates that the bleaching is mainly caused by the combination of sericitization and carbonatization. Combined with fluid inclusion studies, it is inferred that bleaching is caused by the pre-ore hydrothermal event characterized with CO2-bearing fluids. Large amounts of siderite are distributed within the bleaching zones, and they are locally crosscut by sulfides, suggesting that the bleaching happened before gold mineralization. Mass balance calculation and μ-XRF analysis indicate that despite the abundance of siderite, Fe is not gained during alteration. Geochemical path modeling further suggests that siderite is efficient in precipitating Au by decreasing S contents in fluids and destroying Au-bearing complexes. In addition, the siderite contents in altered slates and Au contents in sulfides suggest that the chemical interaction between siderite and ore fluids can produce ores with economic significance. The siderite developed during the pre-mineralization alteration, provided ideal chemical traps and prepared the ground for gold mineralization. When the gold-bearing fluids overprinted the altered rocks, sulfides formed through reaction with siderite. It is concluded that the sulfidation, which resulted in the destruction of Au-S complexes, is the major mechanism for gold mineralization within the bleached slates.
... The Neoproterozoic igneous rocks have been studied for decades and received great attention in recent years due to the absence of diagnostic features of regional deformation and metamorphism in the orogenic belt Li et al., 2016b;Wang et al., 2012b;Wang et al., 2013a;Zheng et al., 2008b;Zhao and Cawood, 2012;Zhang et al., 2013a). One hotly debated issue is the exact time of the collision between the Yangtze and Cathaysia blocks, with one group suggesting that the collision occurred at some time between 900 Ma and 860 Ma Wang and Li, 2003;Wang et al., 2011a;Wang et al., 2011b), accompanied with extensive and intensive arc-related magmatism (Kou et al., 2018;Zheng et al., 2008a), while some authors considered that it might have happened during the interval between 870 Ma and 830 Ma Zhao and Cawood, 1999;Wang et al., 2008;Zhao et al., 2011). Recent geochemical and geochronological studies on the volcanic-sedimentary sequences in this orogenic belt conducted by argue against the two hypothesis and proposed a time of the collision should not be earlier than 830 Ma, accounting for the metamorphism and deformation of older successions, as well as the generation of ~835-815 Ma granitic rocks in the Jiangnan orogen. ...
... The overlying early Neoproterozoic sedimentary sequences in the western Jiangnan orogen are dominated by sandstone, siltstone, slate and phyllite, represented by the Sibao Group (local stratigraphic equivalents include the Fanjingshan Group in northeast Guizhou Province, the Lengjiaxi Group in central Hunan Province, the Shuangqiaoshan Group in northwest Jiangxi Province), corresponding to the Shangxi Group in south Anhui Province and the Shuangxiwu Group in west Zhejiang Province in the eastern Jiangnan orogen (for province locations see Fig. 3) (Zhao and Cawood, 2012). These early Neoproterozoic sedimentary rocks are commonly deformed into high-angle tight linear and isoclinal overturned folds (Hunan BGMR, 1988;Wang et al., 2007a;Wang et al., 2008;Wang et al., 2017a). The Sibao Group and its equivalents were traditionally considered as Mesoproterozoic in age, but new sedimentological and geochronological evidence indicates that they are Neoproterozoic with an upper age limit of ~820 Ma (Wang et al., 2017a). ...
... The north and south tectonic boundaries of the eastern Jiangnan orogen were previously thought to be along the Shitai-Jiujiang fault and Shaoxing-Jiangshan-Pingxiang fault (also called the Jiang-Shao fault), respectively ( Fig. 1) (Guo and Gao, 2018). Note that the Jiang-Shao fault is considered as the suture zone between the Cathaysia and Yangtze blocks in the Neoproterozoic (860-820 Ma) (Fig. 1, Cawood et al., 2013;Wang et al., 2008;Yao et al., 2014;Yao et al., 2017;Zhao and Cawood, 2012), but the southwestern extension of the boundary is unknown due to poor exposure and thermo-tectonic modification (Li et al., 2010c;Ren, 1991). ...
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