Lotus leaf: (a) Magnification of one. From website [14]; (b) Three different magnification of SEM images showing morphological micro-and nanostructures. From Koch et al. [13].

Lotus leaf: (a) Magnification of one. From website [14]; (b) Three different magnification of SEM images showing morphological micro-and nanostructures. From Koch et al. [13].

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In this review we discuss the current state of the art in evaluating the fabrication and performance of biomimetic superhydrophobic materials and their applications in engineering sciences. Superhydrophobicity, often referred to as the lotus effect, could be utilized to design surfaces with minimal skin-friction drag for applications such as self-c...

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... characteristics of 200 species. They demonstrated that the epidermal (i.e. outermost) cells of the lotus leaves form papillae, which act as microstructure roughness. The papillae are superimposed by a very dense layer of epicuticular waxes (wax crystals), also referred to as hair-like structures [12] or nanostructure roughness [13]. Fig. 1 shows different degrees of magnification of lotus leaves using SEM images from one to 10 6 times. Epicuticular waxes themselves have hydrophobic properties, which together with micro-and nanostructure roughness, result in reduced contact area between water droplets and the leaf's surface. This combination results in static contact ...
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... structure is studied by Choi and Kim [42]. These authors present slip length of their surface in comparison to that of a smooth one. Lee and Kim [4] demonstrated that the slip length can be maximized by superimposing a nanostructure onto a microfabricated structure, similar to the case of wax crystals on papillae of the lotus leaves as shown in Fig. 10. These authors demonstrated that the contact angle for their surfaces can approach 180 • . In addition, they showed that the slip length can be increased up to 400 ...
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... are limitations for commercializing microfabricated surfaces such as those shown in Figs. 8-10. Production cost is probably the most prohibitive issue with microfabricated surfaces. Recent studies, however, have shown that there are alternative methods for engineering superhydrophobic surfaces more cost-effectively. As discussed by Emami et al. [5], one can produce a superhydrophobic surface by randomly depositing hydrophobic ...
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... issue with microfabricated surfaces. Recent studies, however, have shown that there are alternative methods for engineering superhydrophobic surfaces more cost-effectively. As discussed by Emami et al. [5], one can produce a superhydrophobic surface by randomly depositing hydrophobic particles (e.g. aerogel) on a substrate (see also [6,7]). Fig. 11(a) shows an SEM image of aerogel powders synthesized using sodium silicate and deposited on a substrate. The static contact angle is measured for a coated surface with aerogel powders to show its superhydrophobicity. Fig. 11(b) shows that the contact angle for such a surface is 150 • ...
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... a superhydrophobic surface by randomly depositing hydrophobic particles (e.g. aerogel) on a substrate (see also [6,7]). Fig. 11(a) shows an SEM image of aerogel powders synthesized using sodium silicate and deposited on a substrate. The static contact angle is measured for a coated surface with aerogel powders to show its superhydrophobicity. Fig. 11(b) shows that the contact angle for such a surface is 150 • ...
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... roughness (posts or particles) and compare their results with those of surfaces manufactured via microfabrication. Their numerical simulations indicated that the gas fraction has a significant impact on the characteristics of a superhydrophobic surface, as it affects the slip length and therefore the skin-friction coefficient. As can be seen in Fig. 12, the friction coefficient decreases with increasing gas fraction for surfaces with staggered posts and randomly distributed posts. In addition, the difference between the skin-friction coefficient of the random posts and that of the staggered posts increases by increasing the gas fraction. Thus, the surface with randomly distributed ...
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... orientation of the fibers is the result of the inherent electrostatic instability of the charged jet as it travels from the spinneret to the collector. This instability can be reduced by using a DC-biased AC potential that induces short segments of alternating polarity, thereby reducing the magnitude of the destabilizing force on the fiber (see Fig. 14(a)) [43]. Fig. 14 shows SEM images of fiber mats produced via DC-electrospinning and DC-biased AC-electrospinning. As shown in Fig. 14, DC-biased AC-electrospinning provides a better control over the microstructure of deposited fibrous mats. The insert in Fig. 14(b) shows a water droplet on the coating with a static contact angle of 157 ...
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... fibers is the result of the inherent electrostatic instability of the charged jet as it travels from the spinneret to the collector. This instability can be reduced by using a DC-biased AC potential that induces short segments of alternating polarity, thereby reducing the magnitude of the destabilizing force on the fiber (see Fig. 14(a)) [43]. Fig. 14 shows SEM images of fiber mats produced via DC-electrospinning and DC-biased AC-electrospinning. As shown in Fig. 14, DC-biased AC-electrospinning provides a better control over the microstructure of deposited fibrous mats. The insert in Fig. 14(b) shows a water droplet on the coating with a static contact angle of 157 degrees, proving ...
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... to the collector. This instability can be reduced by using a DC-biased AC potential that induces short segments of alternating polarity, thereby reducing the magnitude of the destabilizing force on the fiber (see Fig. 14(a)) [43]. Fig. 14 shows SEM images of fiber mats produced via DC-electrospinning and DC-biased AC-electrospinning. As shown in Fig. 14, DC-biased AC-electrospinning provides a better control over the microstructure of deposited fibrous mats. The insert in Fig. 14(b) shows a water droplet on the coating with a static contact angle of 157 degrees, proving superhydrophobicity even in the case of random fiber deposit [11]. This is because, similar to the case of ...
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... thereby reducing the magnitude of the destabilizing force on the fiber (see Fig. 14(a)) [43]. Fig. 14 shows SEM images of fiber mats produced via DC-electrospinning and DC-biased AC-electrospinning. As shown in Fig. 14, DC-biased AC-electrospinning provides a better control over the microstructure of deposited fibrous mats. The insert in Fig. 14(b) shows a water droplet on the coating with a static contact angle of 157 degrees, proving superhydrophobicity even in the case of random fiber deposit [11]. This is because, similar to the case of microfabricated surfaces, such superhydrophobic fibrous coatings can provide the porosity that is necessary to entrap air when the surface is ...
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... the slip length results attained using this fabrication approach are comparable to those obtained using ordered micro/nanostructure surfaces [4]. It is worth mentioning that the morphology of the fibers influences the hydrophobicity of the surface. For example, fiber diameter can affect the static contact angle of the coating, as shown in Fig. 15. This figure shows that contact angle decreases with increasing fiber diameter. However, one should note that since other microstructural parameters of the surfaces reported in this figure were not kept constant while fiber diameter was varied, changes in the fiber diameter could have affected the porosity of the mat. Therefore, in the ...
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... striders, Gerris remigis, possess a very rare trait that allows them to walk on water. Water striders owe this ability to the hydrophobic waxy microhairs covering their legs, microsetae, which are superimposed with nanogrooves [2] as shown in Fig. ...
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... the volume of the displaced water caused by immersing a single leg is 300 times that of the leg itself. Feng et al. [45] have modeled the ultra-hydrophobicity of a water strider's leg by providing a theoretical analysis, coupled with experimental measurements, to determine how deep the leg can reach before piercing the water surface as shown in Fig. 17. They demonstrated that the maximum depth, h max , depends on the diameter, D, and the contact angle of the leg, φ leg . Their results are shown in Fig. 18. It can be seen that for the actual diameter range (140-180 μm) and for the measured maximum depth (h max = 4.38 ± 0.02 mm), the contact angle should be at least 168 • , i.e. highly ...
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... of a water strider's leg by providing a theoretical analysis, coupled with experimental measurements, to determine how deep the leg can reach before piercing the water surface as shown in Fig. 17. They demonstrated that the maximum depth, h max , depends on the diameter, D, and the contact angle of the leg, φ leg . Their results are shown in Fig. 18. It can be seen that for the actual diameter range (140-180 μm) and for the measured maximum depth (h max = 4.38 ± 0.02 mm), the contact angle should be at least 168 • , i.e. highly water-repellent. Such a high contact angle allows water striders to stand on water, even in the presence of rain or water ...
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... and the maximum pitch for superhydrophobic surfaces made up of randomly distributed posts. This information is used in Eq. (2) to determine the maximum allowable hydrostatic pressure, which corresponds to the post that has the maximum local gas fraction. In a Voronoi diagram, the superhydrophobic surface is divided into cells, as shown in Fig. 19. Each post has a single surrounding Voronoi cell consisting of all points on the surface that are closer to that post than to any other post. The sides of a Voronoi cell are the locations of the points on the surface that are equidistant from the two nearest posts. The Voronoi nodes are the points equidistant from three (or more) ...
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... Fig. 20. It can be seen that the maximum allowable pressure decreases dramatically when the posts are arranged randomly. The results of this figure indicate that superhydrophobic surfaces with random roughness are more susceptible to failure under hydrostatic pressures. Therefore, although random posts can result in a better drag reduction (see Fig. 12), they are more likely to fail under elevated ...
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... particles in comparison to the ordered distributed ones. These authors also conducted a series of 3-D full-morphology (FM) numerical simulations and analytical expressions to predict the critical pressure (pressure beyond which the surface departs from the Cassie state) against solid volume fraction of their granular porous coatings, as shown in Fig. 21. This figure shows that the air-water interface can sustain more pressure as the solid volume fraction increases. Moreover, the surface with random particles is more susceptible to failure under hydrostatic pressure, as ...

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... This is due to surface tension, which keeps a tiny layer of air between the solid surface and the liquid. As water droplets roll off these surfaces, they carry away dirt, and this is known as the lotus effect, or self-cleaning [6][7][8]. Numerous studies have been carried out over the last few decades to look at the concepts, architectures, and workings of these self-cleaning surfaces [9,10]. The waxy substance or chemicals and the tiny bumps on the surface of the lotus leaf make it extremely hydrophobic. ...
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Η περί τη βιομιμητική (Biomimetic) έρευνα αντλεί έμπνευση από ιδιότητες ζωντανών οργανισμών που υπάρχουν στη φύση και ζουν σε διαφορετικούς βιοτόπους και διακριτά ενδιαιτήματα. Η βιομιμητική βασίζεται στη μελέτη, την ανάδειξη, την αντιγραφή και την προσομοίωση ιδιοτήτων και δομικών χαρακτηριστικών έμβιων οργανισμών που έχουν αποδεδειγμένα αντέξει περιβαλλοντικές καταπονήσεις. Έτσι, δομές και ιδιότητες ζωντανών οργανισμών (υδρόφοβες, οπτικές και άλλες ιδιότητες) που αποκαλύπτονται με τη βασική έρευνα χρησιμοποιούνται από την τεχνολογία δημιουργώντας ανταλλακτικές αξίες, θέσεις εργασίας, χρηστικά και πρωτοποριακά προϊόντα. Η βιομίμηση (Biomimicry) έχει σχέση με την απατηλή μίμηση χαρακτηριστικών ενός οργανισμού από έναν άλλο οργανισμό για ξεγέλασμα, για προσέλκυση ή άμυνα. Για παράδειγμα, τα άνθη ορισμένων φυτών όπως οι ορχιδέες μιμούνται, καθώς ανοίγουν και επιδεικνύουν τον φαινότυπό τους (χρώματα, σχήματα και συμμετρίες) όσον αφορά τη μορφολογία, ορισμένα έντομα για να τα προσελκύσουν. Επίσης, πεταλούδες και έντομα μιμούνται το φύλλωμα δέντρων και θάμνων για να μην γίνουν αντιληπτές/αντιληπτά από θηρευτές. Τόσο η βιομιμητική όσο και η βιομίμηση σχετίζονται με την αποκάλυψη χαρακτηριστικών ιδιοτήτων της ύλης της φύσης από την ερευνητική δραστηριότητα των ανθρώπων. Ωστόσο, η ανάπτυξη των ηλεκτρονικών μικροσκοπίων ήταν μια κομβική υποδομή αναφοράς για τη βασική έρευνα που πυροδότησε πολλές από τις ιδέες της βιοέμπνευσης και των μετέπειτα εφαρμογών. Κατά συνέπεια, στη βιομιμητική τεχνική καθρεφτίζονται επιλεκτικά ιδιότητες της ύλης της φύσης που προβάλλονται με προσομοίωση σε τεχνητές, ανθρώπινες κατασκευές. Η πρωταρχική προσέγγιση θεμάτων βιομιμητικής (Biomimetics) συνδέεται με την άποψη ότι οργανισμοί που ζουν σε βιοτόπους έχουν ήδη αποκριθεί με επιτυχία σε περιβαλλοντικές καταπονήσεις, με την πάροδο του χρόνου και πρόκειται για εκατομμύρια χρόνια εξέλιξης και προσαρμογής. Δηλαδή, η επιβίωση και η ανάπτυξή τους έχει αποδεδειγμένα δοκιμαστεί και βασίζεται στις προσαρμογές τους στο φυσικό τους περιβάλλον. Η βιομιμητική μελετά και αναζητά τις επιτυχημένες αποκρίσεις στο περιβάλλον από τους ζωντανούς οργανισμούς, με απώτερο στόχο να προτείνει λύσεις, έτσι ώστε επιλεγμένα αντικείμενα, υλικά και δομές που θα βοηθήσουν την ανθρώπινη και ανθρωποκεντρική δραστηριότητα να βρίσκονται σε δυναμική ισορροπία με το περιβάλλον του πλανήτη μας. Στις μέρες μας είναι γεγονός ότι από επίμονες, επίπονες και μακρόχρονες μελέτες φυσικής ιστορίας, οραματισμό και έμπνευση προκύπτουν σύγχρονες τεχνολογικές εφαρμογές και νέα προϊόντα με ποικίλες εφαρμογές. Η ανάδειξη της σημασίας της βιομιμητικής, της βιομίμησης, της βιομιμητικότητας ή του βιομιμητισμού σχετίζεται με τη συμβολή την οποία μπορεί να προσφέρει η ενσωμάτωση “πληροφορίας” που προϋπήρχε και προϋπάρχει στη φύση σε καινοτομίες και ανθρωπογενείς επεμβάσεις στο περιβάλλον, με στόχο τη βιώσιμη ανάπτυξη. Στο πλαίσιο αυτό ενθαρρύνεται η διεπιστημονικότητα, η αλληλεπίδραση ιδεών και καινοτόμων απόψεων. Πρόκειται για ταχύτατα αναπτυσσόμενες διεργασίες διεθνώς, σε πανεπιστήμια και ερευνητικές δομές. Με εφόδιο το έργο που διεξάγεται και δημοσιοποιείται, θετικές επιστήμες, κοσμετολογία, αθλητισμός, φαρμακευτική, γεωπονία, αρχιτεκτονική, αρχαιολογία, καλές τέχνες, επιστήμες υλικών, κατασκευών, υφασμάτων, υγείας, περιβάλλοντος και διαστήματος, επιστήμες αγωγής και φυσικής αγωγής αποβλέπουν σε ανάλογα αποτελέσματα. Η έμβια ύλη της φύσης, η οποία αποτελεί “καλούπι” για την τεχνολογία. Επίσης, προσεγγίζονται με παιδεία νέες πτυχές έρευνας και τεχνολογικών δυνατοτήτων. προκλήσεων και προοπτικών για τις επερχόμενες γενιές. Εννοείται ότι τα κεφάλαια του παρόντος συγγράμματος δεν καλύπτουν όλη την έκταση της βιομιμητικής και της βιομίμησης, αλλά είναι ένα πρώτο, σημαντικό βήμα για την ανάδειξη του θέματος και της έμπνευσης καθώς και την προώθηση των ερεθισμάτων ή των παρατηρήσεων από την έμβια ύλη της φύσης.