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Locality map of coring sites. Bathymetric contours are at 500 m intervals.

Locality map of coring sites. Bathymetric contours are at 500 m intervals.

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A rock magnetic study was performed on sediment cores from four sites in the South Atlantic off the western coast of Africa, which were taken during the Ocean Drilling Program Leg 175 (Sites 1078, 1082, 1084, and 1085). The sites are within the Angola-Namibia upwelling system, and the sediments have a high total-organic-carbon content. Concentratio...

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... ODP Leg 175, sediment cores were taken at thir- teen sites off the western coast of Africa between 5 • and 32 • S ( Wefer et al., 1998). The main purpose of the leg was to investigate the paleoceanography of the Angola-Benguela currents. Sediments from four sites out of thirteen, Sites 1078, 1082, 1084, and 1085 ( Fig. 1), were used in this study. This area contains one of the major upwelling regions in the world, and is characterized by organic-rich greenish sedi- ments with intense diagenetic activity. Site 1078 is in the Mid-Angola Basin off Lobito, and its water depth is 427 m. The site is between the high- productivity regions to both the north and ...
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... 8(a)). This supports the inference that the low-field magnetic susceptibility of these sites is dominated by paramagnetic minerals. After subtracting the high-field slope (paramagnetic behavior), we could determine the hys- teresis parameters of the ferrimagnetic fraction of the sedi- ments (Fig. 8(b)). Magnetic domain state was estimated from Fig. 10(a)). Results of sample 1082A-6H3-135 are displayed. Irreversibility of cooling and warming curves above about 100 K is indicative of magnetite. The difference in the two curves before sediments were thawed (thin black curves) is larger than that a few months after thawing (thicker gray ...
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... origin contribute more to the sediments from the Congo Basin and the Angola Basin than to the sediments off the African coast at and to the south of the Walvis Ridge, where biogenic magnetites of single domain size dominate. Remanent magnetization in a temperature range between 6 and 250 K or 300 K was measured on frozen and unfrozen samples (Fig. 10). Changes of remanent magnetization were obscured by a strong magnetic moment at low temperature from the dominant paramagnetic component, which was in- duced by a small residual field in the sample space of the low-T susceptometer (∼0.05 mT, varies with temperature and varies each time after generating a strong field) and by the ...
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... and varies each time after generating a strong field) and by the remanent magnetization of blocked paramagnetic materials at low temperature. None the less, the presence of magnetites in both frozen and unfrozen samples can be concluded from the irreversibility of magnetization curves during zero-field low-temperature cycling of 250 K IRM (Fig. 10(b)). Magne- tization during cooling down was slightly larger than during warming up above about 100 K. The loss of remanent mag- netization during the low-temperature cycle is most likely caused by passing through the magnetic isotropic point of magnetite (T I ) and the Verwey transition. The temperature of T I is at about 130 K for pure ...
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... loss of remanent mag- netization during the low-temperature cycle is most likely caused by passing through the magnetic isotropic point of magnetite (T I ) and the Verwey transition. The temperature of T I is at about 130 K for pure magnetite, and lowered by substitution of Ti 4+ (Dunlop and¨Ozdemirand¨ and¨Ozdemir, 1997). The Ver-wey transition is a crystallographic phase transition known to occur at 110-120 K for pure magnetite (Verwey, 1939). ...
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... 1939). The magnetization loss of frozen samples during the low- temperature cycle was significantly larger than that of the thawed samples. Another sign of the presence of magnetite is a slight increase of the slope of the thermal demagnetization curves around 100 K, which was detected as a small increase in the derivative (−M/T ) (an arrow in Fig. 10(a)). This could be a manifestation of the Verwey transition. Pyrrhotite cannot be expected here because magnetic transition at 30 to 34 K, indicative of pyrrhotite ( Rochette et al., 1990), was not ...

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... Rapid loss of magnetization during storage has been reported for organic-rich lake sediment cores (Oldfield et al. 1992) and for anoxic marine sediments Roberts et al. 1999;Yamazaki et al. 2000). Such modifications of magnetic properties are known as "storage diagenesis" (Oldfield et al. 1992). ...
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