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Heat release of biomass and blended biomass 

Heat release of biomass and blended biomass 

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Background: Blended biomass, a new feedstock for pellets production potentially be viable to support the demand for wood pellets at present and in the future. Combustion behavior and characteristics tests were carried out in thermogravimetry (TG) analyzer with an air flow rate of 100 ml/min and heating rate of 20 °C/min. Heat flow and heat required...

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... released during the combustion of biomass samples at heating rate of 20 °C/min was calculated based on the area under DSC curve as presented in Figure 1 and Figure 3b. The low heat release (4.5 – 6.7 kJ/kg) in agricultural biomass might be due to breaking of low volatile chemical bound. Similar results were found by by Kok and Özgür [13] for rice husk and miscanthus biomass. In woody biomass the chemical bonds are not easily broken and this might result in the release of higher amount of heat (10 -12 kJ/kg) than agricultural biomass. The heat released due to combustion of individual agricultural and woody biomass as well as their blends is shown in Figure 5. Blending of agricultural with woody biomass improved the release of energy. Several reason could be behind such result. For instance, increase in carbon and hydrogen content, and contribution of lignin from woody biomass in the blend. As presented in Figure 5, the energy released from the blend biomass was in the range of 7.0 to 10 kJ/kg. Combustion behavior and thermal analysis of selected agricultural and woody biomass and their blend was investigated in this study. The differences in thermal behavior of agricultural and woody biomass were analyzed and the following conclusions were derived:  The reactivity, combustion behavior and degradation rate peak of the agricultural biomass changed after blending them with woody biomass.  Typically, agricultural biomass contains higher amount of inorganic minerals which can result in higher emissions and problem during combustion process. Blending agricultural residues with forestry biomass helped to reduce the sulfur, copper, chlorine and ash content that can possibly meet the standard limit of biomass fuel.  There was some improvement in heat released (6.94 to 9.26 kJ/kg) during combustion for blended biomass as compared to individual agricultural biomass (reed canary grass - 5.4 kJ/kg, timothy hay- 6.78 kJ/kg, and switchgrass - 4.59 kJ/kg). Overall, blending of agricultural biomass with woody biomass can be considered as one of the alternative options to increase the biomass fuel feedstock such as pellet production to meet the future demand. Future works will be proposed to study the biomass availability in Malaysia for industrial application and meeting pellets demand of neighbourhood country. The authors appreciate the financial assistance from New Brunswick Department of Agriculture, Aquaculture and Fishries; New Brunswick Soil and Crop Improvement Association; New Brunswick Agricultural Council; Agriculture and Agri-Food Canada; New Brunswick Innovation Foundation; and Universiti Teknologi PETRONAS, ...
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... released during the combustion of biomass samples at heating rate of 20 °C/min was calculated based on the area under DSC curve as presented in Figure 1 and Figure 3b. The low heat release (4.5 – 6.7 kJ/kg) in agricultural biomass might be due to breaking of low volatile chemical bound. Similar results were found by by Kok and Özgür [13] for rice husk and miscanthus biomass. In woody biomass the chemical bonds are not easily broken and this might result in the release of higher amount of heat (10 -12 kJ/kg) than agricultural biomass. The heat released due to combustion of individual agricultural and woody biomass as well as their blends is shown in Figure 5. Blending of agricultural with woody biomass improved the release of energy. Several reason could be behind such result. For instance, increase in carbon and hydrogen content, and contribution of lignin from woody biomass in the blend. As presented in Figure 5, the energy released from the blend biomass was in the range of 7.0 to 10 kJ/kg. Combustion behavior and thermal analysis of selected agricultural and woody biomass and their blend was investigated in this study. The differences in thermal behavior of agricultural and woody biomass were analyzed and the following conclusions were derived:  The reactivity, combustion behavior and degradation rate peak of the agricultural biomass changed after blending them with woody biomass.  Typically, agricultural biomass contains higher amount of inorganic minerals which can result in higher emissions and problem during combustion process. Blending agricultural residues with forestry biomass helped to reduce the sulfur, copper, chlorine and ash content that can possibly meet the standard limit of biomass fuel.  There was some improvement in heat released (6.94 to 9.26 kJ/kg) during combustion for blended biomass as compared to individual agricultural biomass (reed canary grass - 5.4 kJ/kg, timothy hay- 6.78 kJ/kg, and switchgrass - 4.59 kJ/kg). Overall, blending of agricultural biomass with woody biomass can be considered as one of the alternative options to increase the biomass fuel feedstock such as pellet production to meet the future demand. Future works will be proposed to study the biomass availability in Malaysia for industrial application and meeting pellets demand of neighbourhood country. The authors appreciate the financial assistance from New Brunswick Department of Agriculture, Aquaculture and Fishries; New Brunswick Soil and Crop Improvement Association; New Brunswick Agricultural Council; Agriculture and Agri-Food Canada; New Brunswick Innovation Foundation; and Universiti Teknologi PETRONAS, ...

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