Figure - available from: Applied Organometallic Chemistry
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¹H nuclear magnetic resonance (NMR) spectra of dimethyl acetylenedicarboxylate (DMAD), Cu‐N3 and Cu‐N3 + DMAD (300 MHz, CDCl3, 298 K). *Methyl groups in DMAD. Methyl groups of CNXyl ligand in Cu‐N3 complex. Methyl groups in the formed Cu(I) triazole complex.
Source publication
Three neutral Cu(I) complexes bearing 2,6‐dimethylphenyl isocyanide (CNXyl) and different triatomic pseudohalogens (SCN⁻, OCN⁻ and N3⁻) as ligands were efficiently synthesized and characterized. The solid‐state structures were unambiguously determined through single‐crystal X‐ray diffraction, revealing unexpected bridging coordination modes in the...
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