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¹H-NMR spectra of CTA-PI-CTA 2 in deuterated chloroform a and PSt-PI-PSt 2 in deuterated acetone b

¹H-NMR spectra of CTA-PI-CTA 2 in deuterated chloroform a and PSt-PI-PSt 2 in deuterated acetone b

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In this study, two novel photoactive xanthates, which bear a photoinitiator (PI) group in the middle and an S-alkyl dithiocarbonate group (–O–C(S)–S–R) at each of the two ends of the molecule, were synthesized as chain transfer agents (CTA) to be used in reversible addition-fragmentation chain transfer/macromolecular design via the interchange of x...