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The use of terephthalate ligands with CnH2n+1NH-chains (n≥6) led to the isolation of the first examples of Zr4+-terephthalate MOFs with 6-connected frameworks. The material with hexyl-amino functional groups has been...
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... In our group, several ammonium-functionalized Zr 4+ MOFs have been reported and widely used as sorbents for the removal of various anionic species [12,[20][21][22][23][24][25]. However, these MOFs could not be applied in solutions containing cationic pollutants without the previous deprotonation of the amine group [26], which means that the material could not further uptake anions. ...
Environmental pollution has been a reality for many decades, with its contamination intensifying daily due to rapid urbanization and the ever-increasing world population. Dyes, and especially synthetic ones, constitute a category of pollutants that not only affect the quality of water but also exhibit high toxicity toward living organisms. This study was thoroughly planned to explore the removal of two toxic dyes, namely the methylene blue (MB) and methyl orange (MO) compounds from contaminated aqueous media. For this purpose, we designed and synthesized two new composite materials based on ammonium-functionalized Zr4+ MOF (MOR-1 or UiO-66-NH3+) and naturally occurring sorbents, such as bentonite and clinoptilolite. The composite materials displayed exceptional sorption capability toward both MB+ and MO− ions. A key finding of this study was the high efficiency of the composite materials to simultaneously remove MB+ and MO− under continuous flow conditions, also showing regeneration capability and reusability, thus providing an alternative to well-known mixed bed resins.
The increasing utilization of hydrazine and its derivatives across diverse sectors highlights the pressing need for efficient detection methods to safeguard human health and the environment. Likewise, nicardipine, a widely...
The incorporation of superhydrophobic properties into metal organic framework (MOF) materials is highly desirable to enhance their hydrolytic stability, gas capture selectivity in the presence of humidity and efficiency in oil–water separations, among others. The existing strategies for inducing superhydrophobicity into MOFs have several weaknesses, such as increased cost, utilization of toxic reagents and solvents, applicability for limited MOFs, etc. Here, we report the simplest, most eco-friendly, and cost-effective process to impart superhydrophobicity to MOFs, involving a rapid (90 min) treatment of MOF materials with solutions of sodium oleate, a main component of soap. The method can be applied to both hydrolytically stable and unstable MOFs, with the porosity of modified MOFs approaching, in most cases, that of the pristine materials. Interestingly, this approach was used to isolate superhydrophobic magnetic MOF composites, and one of these materials formed stable liquid marbles, whose motion could be easily guided using an external magnetic field. We also successfully fabricated superhydrophobic MOF-coated cotton fabric and fiber composites. These composites exhibited exceptional oil sorption properties achieving rapid removal of floating crude oil from water, as well as efficient purification of oil-in-water emulsions. They are also regenerable and reusable for multiple sorption processes. Overall, the results described here pave the way for an unprecedented expansion of the family of MOF-based superhydrophobic materials, as virtually any MOF could be converted into a superhydrophobic compound by applying the new synthetic approach.
The efficient removal of arsenite (As(III)) poses a significant challenge to traditional water treatment technologies due to its high toxicity and mobility. In this work, multifunctional Zirconium-Ferrocene Metal Organic Framework (ZrFc-MOF) fabricated with redox-active 1,1-ferrocene dicarboxylic acid ligands and Zr4+ precursors were elaborated to achieve remarkably enhanced As(III) removal via activation by peroxymonosulfate (PMS). The adsorption affinity coefficient increased from 0.097 to 2.035 L mg-1 and the maximum adsorption capacity increased from 59.79 to 111.34 mg g-1 compared with that without PMS. Besides the conventional homogeneous PMS oxidation and the following adsorption through Zr-O clusters of ZrFc-MOFs, the enhanced As(III) removal synergistic combines the oxidation mechanism of As(III) by reactive oxygen species (•OH, SO4•-, O2•- and 1O2) formed in Ferrocene (Fc) activating PMS process with the simultaneous formed extra adsorption sites of Ferrocenium (Fc+). PMS also help ZrFc-MOF to avoid destruction in harsh alkaline condition, making the effluent in this advanced treatment meet the World Health Organization (WHO) threshold of 10 μg L-1 over a wide range of initial pH (2-11) with high selectivity and durability. These results indicate that this novel Fc-based MOFs activating PMS system has potential applicability for As(III) in oxidation and selectively capturing in the water environment.
Environmental pollution and the shortage of drinking water are the challenges that mankind is facing. Solar interface evaporation technology has been demonstrated as an important method for producing clean water, but its application to sewage still faces problems, mainly manifested in solubility and oily pollutants. Therefore, an evaporator device contains a superhydrophobic Bi2WO6 felt floating layer, a filter paper hydrophilic layer, and a copper foam/CuO photothermal layer, of which the water contact angle of the superhydrophobic felt can reach 159°. The floating layer not only has the ability to adsorb n-hexane but the Rh B degradation can also be realized under indoor/outdoor light conditions. The carrier life of Bi2WO6 is 28.8 ns. A copper foam/CuO photothermal layer prepared through a low-temperature treatment is combined with the floating and hydrophilic layer to obtain an evaporation rate of 1.53 kg m-2 h-1.
