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Dyeing mechanism of Disperse Dye. 

Dyeing mechanism of Disperse Dye. 

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Article
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This study highlighted the influence of change in material to liquor ratio on the colorfastness properties of Synolon Yellow EXW fluorescent disperse dye applied on knitted polyester fabric in exhaust dyeing method. Three different liquor ratios (1:6, 1:8 and 1:10) were used and dye shade percentages were 0.5%, 1.0% and 1.5%. The results showed tha...

Context in source publication

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... dye of hydrophobic nature has extremely poor solubility in water (Trotman, 1984) [1]; for this reason dispersing agent is added to the dye bath to maintain dispersion stability, especially in the case of high temperature dyeing (Bukinshaw, 1995) [2]. In dye bath, the dye transfer to fiber from the micelles aggregate of surfactant molecules dispersed in a liquid colloid. As micelles empty their dye, they reform and dissolve more dye from the solid particles [3]. In presence of dispersing agents, the following equilibrium situation is set up (fig 1) [4]. Satisfactory fastness to light, washing, rubbing, sublimation and burnt gas fumes, is particularly significant for disperse dyes [5]. The dyeing of artificially made fibres with disperse dyes generally have good fastness properties [6]. After the applications of fluorescent azo disperse dyes on polyester fiber, it has been found that it enhances various fastness properties [7]. Experiment showed the increase of photo physical properties after application of fluorescent acid azo dyes on wool, silk and nylon [8]. Fluorescent disperse dyes have the unique property of absorbing in the UV range and emitting in the visible region of the electromagnetic spectrum and which owe their potential application to their intense fluorescence properties [9]. The application of fluorescent dyes are associated with their ability to attract attention, because of the remarkable vivid brilliance of the color and dyes are associated with their ability to attract attention, because of the remarkable vivid brilliance of the colors [10] Synolon EXW dyes are state-of-the-art disperse dyes with the highest wash fastness. They meet the requirements of the major retailers and even the most severe fastness tests [11]. They are highly recommended for Polyester/Elastin blends, especially for sportswear [12]. At 120°C temperature the dye exhaustion of Synolon Yellow EXW fluorescent disperse dye was found 30% and this increased to 60% when the temperature raised to 130°C. After 40 minutes of run time the exhaustion% increased to 70% [13]. Fluorescent dyes can be applied in various differentiated fields. But one of the leading application fields where fluorescent dyes have long been used is for the dyeing of flat materials, especially textiles. The application of fluorescent dyes results a significant increase in color brightness, which makes the dyed materials more easily perceptible. The materials dyed with fluorescent dyes render a unique advantage for manufacturing sports clothing and clothing for special services, such as fire brigades and the police because of the intensified perceptibility [14]. Recently, the application of fluorescent dyes in medical diagnostic and biochemical investigations has developed extremely dynamically [15].In comparison of disperse dyes of different auxiliary groups, dyes containing benzothiazolyl residue have better fastness properties than that of the azo disperse dyes based on 2-naphthol ...

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Citations

... By applying the fluorescent marker at a temperature lower than the temperature of the glass transition of the polyester, the polyester chains are quite rigid, which makes diffusion difficult. Therefore, by increasing the temperature up to 100 °C, the development of amorphous zones in the fibrous structure is favored which facilitates the penetration of dye inside the textile and thus increases fluorescence [37]. A temperature of 130 °C and 140 °C can decrease the fluorescence intensity, the quenching phenomenon is observed. ...
... However, the transmission decreases to nearly zero around 300 nm wavelength. A reason might be the aromatic structure of polyester that offers certain UV-protection [37]. Further, all samples finished with the UV-absorber Tanuval, no matter which finishing process is applied, show a decreasing transmission in the range of wavelength from 400 to 350 nm, to nearly zero at 350 nm. ...
Article
Full-text available
The article presented concerns the application of fluorescein as a fluorescent material for anti-counterfeiting technology which will allow the labeling and identification of legitimate articles in the textile field. Fluorescein has been applied to polyester fabrics by microwave irradiation technique in the presence of a UV absorber. Thus, its presence in the textile substrate is detectable following an excitation at a specific wavelength belonging to the Ultra-violet zone, which makes this material very effective for tracking and detecting counterfeit articles. Fluorescent samples are characterized morphologically by scanning electron microscopy (SEM) and quantitatively by optical spectroscopy such as reflectance and transmission measurements. The treated samples show under UV light a yellowish green emission with a slight yellow coloration of the polyester fiber. The UV absorber applied to the fluorescent solution improves the light resistance of the treated samples by 25%. Their addition to the bath can also ensure the production of a protective fabric against UV.
... By applying the uorescent marker at a temperature lower than the temperature of the glass transition of the polyester, the polyester chains are quite rigid, which makes diffusion di cult. Therefore, by increasing the temperature up to 100°C, the development of amorphous zones in the brous structure is favored which facilitates the penetration of dye inside the textile and thus increases uorescence [36]. A temperature of 130 °C and 140 °C can decrease the uorescence intensity, the quenching phenomenon is observed ( gure 5). ...
... However, the transmission decreases to nearly zero around 300 nm wavelength. A reason might be the aromatic structure of polyester that offers certain UV-protection [36]. Further, all samples nished with the UV-absorber Tanuval, no matter which nishing process is applied, show a decreasing transmission in the range of wavelength from 400 nm to 350 nm, to nearly zero at 350 nm. ...
Preprint
Full-text available
The article presented concerns the application of fluorescein as a fluorescent material for anti-counterfeiting technology which will allow the labeling and identification of legitimate articles in the textile field. Fluorescein has been applied to polyester fabrics by microwave irradiation technique in the presence of a UV absorber. Thus, its presence in the textile substrate is detectable following an excitation at a specific wavelength belonging to the Ultra-violet zone, which makes this material very effective for tracking and detecting counterfeit articles. Fluorescent samples are characterized morphologically by scanning electron microscopy (SEM) and quantitatively by optical spectroscopy such as reflectance and transmission measurements. The treated samples show under UV light a yellowish green emission with a slight yellow coloration of the polyester fiber. The UV absorber applied to the fluorescent solution improves the light resistance of the treated samples by 25%. Their addition to the bath can also ensure the production of a protective fabric against UV.
Chapter
This study examined the effects of dyeing polyester fabrics with a fluorescent dye under different conditions (temperature, pH and fluorophore concentration) on the color intensity and fluorescence quality of the dyed fabrics. Exhaustion dyeing method was applied in this experiment for textile fiber. The dependence of fluorescein on pH has been studied, and a bathochromic and hyperchromic effect of the absorption spectra of its fluorescent solution by going to higher pHs has been shown. In addition, images taken under UV excitation at 365 nm gave different emissions from the treated polyester at different pH values.