Figure 5 - uploaded by Francoise M. Amombo Noa
Content may be subject to copyright.
![Cyclic voltammetry of the Ce(IV)/Ce(III) redox couple in CTH-15 Cyclic voltammogram of CTH-15 in carbon paste, 0.1 M phosphate buffer, pH = 7 and sweep rate 10 mVs À1 showing that the redox potential of Ce(IV)/Ce(III) in [Ce 3 (btec)(Hbtec)(OAc)(HCO 2 )] CTH-15 is about 0.2 V versus Ag/AgCl, a remarkable stabilization of Ce(IV) compared with the aqueous solution chemistry. For other cyclic voltammograms, see Figures S27 and S28.](profile/Francoise-Amombo-Noa/publication/348514639/figure/fig5/AS:1057360579665930@1629105815920/Cyclic-voltammetry-of-the-CeIV-CeIII-redox-couple-in-CTH-15-Cyclic-voltammogram-of.png)
Cyclic voltammetry of the Ce(IV)/Ce(III) redox couple in CTH-15 Cyclic voltammogram of CTH-15 in carbon paste, 0.1 M phosphate buffer, pH = 7 and sweep rate 10 mVs À1 showing that the redox potential of Ce(IV)/Ce(III) in [Ce 3 (btec)(Hbtec)(OAc)(HCO 2 )] CTH-15 is about 0.2 V versus Ag/AgCl, a remarkable stabilization of Ce(IV) compared with the aqueous solution chemistry. For other cyclic voltammograms, see Figures S27 and S28.
Context in source publication
Context 1
... CTH-15, the voltammogram shows a quasi-reversible electron transfer reaction, probably related to the Ce(IV)/Ce(III) redox couple in the MOF structure, see Figure 5 (as no corresponding couple was shown for CTH-16 with the non-redox active Gd 3+ ). The electron transfer kinetics is slow as expected for a carbon paste electrode. ...
